wikipedia: In organic chemistry, the polydispersity index (PDI), is a measure of the distribution of molecular mass in a given polymer sample. The PDI calculated is the weight average molecular weight divided by the number average molecular weight. It indicates the distribution of individual molecular masses in a batch of polymers. The PDI has a value equal to or greater than 1, but as the polymer chains approach uniform chain length, the PDI approaches unity (1).
wikipedia: In organic chemistry, the polydispersity index (PDI), is a measure of the distribution of molecular mass in a given polymer sample. The PDI calculated is the weight average molecular weight divided by the number average molecular weight. It indicates the distribution of individual molecular masses in a batch of polymers. The PDI has a value equal to or greater than 1, but as the polymer chains approach uniform chain length, the PDI approaches unity (1).
从数学角度看大于等于1.
聚合物,用凝胶色谱测PDI,就是分子量分布情况,当然越低越好啦!也就是说越接近1越好!如果用DLS(动态光散射)的粒经分布,应该也是越小越好,不过这个值都是小于1的。
PDI肯定是大于1的,即使是GPC标样,PDI也不过是小于1.1。
凝胶色谱就好了,没有问题了。
动态光散射结果是接近零最好,一般都小于0.1
是不是说,DLS给出的pdi就不是“重均/数均”了?那DLS给出的是什么值呢?这个值是如何得到的呢?再帮帮忙吧~
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DLS测的不是分子量,它测得是粒子的大小也就是粒径。