24小时热门版块排行榜    

查看: 400  |  回复: 1

yanfangwuy

新虫 (正式写手)

[求助] 求翻译一段文献, 自己翻译的是在是不通 已有1人参与

Dynamic combinatorial chemistry is a novel aspect of supramolecular chemistry dealing with the generation of dynamic libraries resulting from all the possible combinations of fragments of the constituents (keys). The receptors (locks) favour the expression of the keys that bind best to it (thermodynamic selection) or that form fastest within it (kinetic selection). The already mentioned in situ rich chemistry of the organosulfur ligands makes this system suitable for developing supramolecular dynamic combinatorial aspects under solvothermal conditions.Moreover, these kinds of organosulphur ligands seem to be especially suitable to form metal–sulphur–organic networks with promising electronic properties.The incorporation of thiolate-S as a single atom bridge between adjacent transition metal sites could allow higher spin density delocalization towards the bridging atom and contribute to strong super-exchange interactions when the selected metal orbital energies are better matched for the sulphur atom. In principle, this beneficial feature is highly desirable in terms of magnetic, conductive and luminescent properties of the resulting materials.
回复此楼

» 猜你喜欢

» 本主题相关价值贴推荐,对您同样有帮助:

已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

see_NEW

木虫 (著名写手)

【答案】应助回帖

★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与,应助指数 +1
yanfangwuy: 金币+10, 有帮助 2015-01-23 20:57:37
动力组合化学是超分子化学的一个新型学科, 目的在于通过化学成分碎片(钥匙)的所有可能组合方式建立动态文库. 受体(锁)倾向于接受最合适的钥匙构象,这种钥匙或者是最易结合(热力动力学选择)的构象,或为最易形成的构象(运动学选择)。 热溶剂条件下,有机硫配体原位富集化学与这门超分子动态组合学科的开发需求极度契合。这种有机硫配体似乎特别倾向形成具有理想电荷的有机铁硫网。相邻过渡态铁原子以硫醇S单原子相连,可以保证连接原子更高的旋转密度分布,以便使目标金属原子的旋转能与硫原子通过强大的超交换作用达到更高的匹配。原则上,最终产物在磁学,电导学,发光特性方面都具有高度倾向性的特点。
Forfree
2楼2015-01-23 16:57:00
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖
相关版块跳转 我要订阅楼主 yanfangwuy 的主题更新
最具人气热帖推荐 [查看全部] 作者 回/看 最后发表
[考研] 26考研-291分-厦门大学(085601)-柔性电子学院材料工程专业求调剂 +3 min3 2026-03-24 4/200 2026-03-25 18:22 by xcjcqu
[考研] 考研一志愿苏州大学初始315(英一)求调剂 +3 sbdksD 2026-03-24 4/200 2026-03-25 18:16 by xcjcqu
[考研] 308求调剂 +3 墨墨漠 2026-03-25 3/150 2026-03-25 17:49 by lenovolsw
[考研] 333求调剂 +6 87639 2026-03-21 11/550 2026-03-25 16:17 by 87639
[考研] 材料与化工考研调剂 +9 孅華 2026-03-22 9/450 2026-03-25 13:09 by cmz0325
[考研] 求调剂 +3 李李不服输 2026-03-25 3/150 2026-03-25 13:03 by cmz0325
[考研] 生物学学硕求调剂 +7 小羊睡着了? 2026-03-23 10/500 2026-03-25 02:24 by 清风拂扬。 m
[考研] 上海电力大学材料防护与新材料重点实验室招收调剂研究生(材料、化学、电化学,环境) +4 我爱学电池 2026-03-23 4/200 2026-03-25 00:59 by 1027_324
[考研] 化工专硕求调剂 +3 question挽风 2026-03-24 3/150 2026-03-24 18:48 by jhhcooi
[考研] 一志愿211 初试270分 求调剂 +5 谷雨上岸 2026-03-23 6/300 2026-03-24 16:32 by laoshidan
[考研] 333求调剂 +3 ALULU4408 2026-03-23 3/150 2026-03-23 19:04 by macy2011
[考研] 350求调剂 +6 weudhdk 2026-03-19 6/300 2026-03-23 15:47 by tangyuan0840221
[考研] 323求调剂 +6 洼小桶 2026-03-18 6/300 2026-03-23 00:29 by king123!
[考研] 生物学调剂 +5 Surekei 2026-03-21 5/250 2026-03-22 14:39 by tcx007
[考研] 0703化学297求调剂 +3 Daisy☆ 2026-03-20 3/150 2026-03-21 17:45 by ColorlessPI
[考研] 求调剂 +3 白QF 2026-03-21 3/150 2026-03-21 13:12 by zhukairuo
[考研] 一志愿南昌大学,327分,材料与化工085600 +9 Ncdx123456 2026-03-19 9/450 2026-03-20 23:41 by lovewei0727
[考研] 考研调剂求学校推荐 +3 伯乐29 2026-03-18 5/250 2026-03-20 22:59 by JourneyLucky
[考研] 一志愿苏州大学材料求调剂,总分315(英一) +5 sbdksD 2026-03-19 5/250 2026-03-20 22:10 by luoyongfeng
[考研] 0856调剂,是学校就去 +8 sllhht 2026-03-19 9/450 2026-03-20 14:25 by 无懈可击111
信息提示
请填处理意见