somophilic isocyanide insertion什么意思?
有机合成中,又一篇英文文献中提到了“somophilic isocyanide insertion”,somophilic什么意思?整句话为“ we succeeded in incorporating
these two building blocks into heteroarenes using visible-lightpromoted somophilic isocyanide insertion”。希望各位大牛指点一二。感激不尽
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somophilic——亲单占分子轨道(新生有机化学概念)
somophilic isocyanide insertion——亲单占分子轨道的异腈插入反应
能举个例子说明一下它的反应机理吗?
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.5b02061
Photoredox-Catalyzed Tandem Insertion/Cyclization Reactions of Difluoromethyl and 1,1-Difluoroalkyl Radicals with Biphenyl Isocyanides
Transition Metal-Catalyzed Heterocycle Synthesis Via C-H Activation
作者:Xiao-Feng Wu
p.423, p.425
https://books.google.com.tw/book ... ism&f=false,