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脫毛脥霉脛锚脪禄脩霉拢卢陆帽脛锚路篓鹿煤虏篓露没露脿麓贸脩搂碌脛CSC鹿芦脜脡脫脰驴陋脢录脕脣拢卢脭脵麓脦脢脺脰庐脟掳脜贸脫脩脦炉脥脨拢卢掳茂脳陋路垄脪脭脧脗2016脛锚碌脛PhD脮脨脜脝鹿茫赂忙 (Deadline: Feb 18th 2016拢卢碌芦脢脟禄鹿脢脟戮隆脭莽脕陋脧碌脦陋潞脙拢卢卤冒赂脧脭脷脳卯潞贸脪禄脤矛)拢卢脠莽鹿没赂脨脨脣脠陇碌脛拢卢脟毛麓脫脣脵拢禄脧拢脥没脫脨脰戮脕么路篓碌脛脜贸脫脩脙脟脛脺禄媒录芦脡锚脟毛拢卢虏篓露没露脿虏禄禄谩脠脙脛茫脙脟脢搂脥没拢卢:-)  脮芒赂枚脢脟路篓鹿煤脫毛csc碌脛鹿芦脜脡脳篓脧卯拢卢脙驴脛锚icmcb露录脛脺脛脙碌陆录赂赂枚脙没露卯拢卢脣霉脪脭脰禄脨猫脪陋脰卤陆脫脕陋脧碌脌脧掳氓拢卢脠禄潞贸脳脽脧脗csc碌脛鹿脵路陆鲁脤脨貌录麓驴脡隆拢拢篓脫脨脨漏脨脜脧垄脪虏驴脡脪脭虏茅脭脛脦脪脰庐脟掳脠媒脛锚碌脛脤没脳脫拢潞https://muchong.com/bbs/viewthread.php?tid=6898912 潞脥 https://muchong.com/bbs/viewthread.php?tid=5513969拢禄 https://muchong.com/bbs/viewthread.php?tid=8383308拢漏

戮脽脤氓脡锚脟毛禄貌脮脽脳脡脩炉拢卢脟毛脰卤陆脫脕陋脧碌 Prof. Corine MATHONIERE: corine.mathoniere@icmcb.cnrs.fr拢卢陆篓脪茅赂陆脡脧脛茫碌脛CV拢卢 brief summary of you education background, research experience, reserach interest, motivation letter, list of publication, list of referrences with detailed contact information, proof of good level of French or English language proficiency 脪脭录掳脝盲脣没脛茫戮玫碌脙脫脨脫脙碌脛脨脜脧垄隆拢陆脴脰脕脠脮脝脷 Feb. 18th 2016拢禄脭脵麓脦陆篓脪茅麓贸录脪脭陆脭莽脕陋脧碌脭陆潞脙隆拢

路脟脩搂脢玫脦脢脤芒拢卢驴脡脪脭路垄脦脪脫脢录镁liujizgd@gmail.com禄貌脮脽脮戮脛脷脨脜拢卢脦脪戮隆脦脪脣霉脛脺禄脴赂麓脛茫脙脟隆拢

脮芒脌茂脦脪脣鲁卤茫脤霉鲁枚ICMCB corine 驴脦脤芒脳茅碌脛脨脜脧垄拢卢https://sites.google.com/site/m3 ... s/corine-mathoniere拢卢 脕铆脥芒赂陆录镁脌茂脙忙禄鹿脫脨脣媒碌脛赂枚脠脣cv拢卢脫脨脨脣脠陇碌脛驴脡脪脭脧脗脭脴驴麓脧脗隆拢

脪脭脧脗脢脟research proposal拢卢麓贸录脪驴脡脪脭脥篓鹿媒脮芒脨漏脕脣陆芒脧脗戮脽脤氓碌脛驴脦脤芒路陆脧貌隆拢

CSC Ph Project proposed by Corine Mathoni篓篓re, University of Bordeaux.
Photomagnetic compounds based on [M(CN)8]4- building blocks M = Mo(IV) and W(IV)

The photoswitchable molecular compounds are an interesting class of materials because they can be used in data storage devices or sensors. In general, these systems have two (or more) distinct electronic states that can be addressed by temperature, visible light, pressure, electric field... When the two states have different magnetic behaviors, the systems are called photomagnetic compounds. Some of these photomagnetic systems are based on [M(CN)8]4- complexes linked to 3d metal ions and show an exceptional stability on their photo-induced states. Nevertheless, the electronic phenomenon at the origin of the photomagnetism in these systems is still a debate. Some studies affirm that an metal-metal electron transfer occurs between the [M(CN)8]4-and its 3d ionic neighbours,[1] and others propose a spin crossover in the [M(CN)8]4- unit.[2,3]

The proposed phD work consists of elucidating the mechanism responsible for the switching process in the [M(CN)8]4-/3d systems. The phD student will synthetize known and new compounds to have a large family of systems necessary for comparison and understanding of the photomagnetic properties. Then he(she) will study the photo-induced properties using different techniques: X-ray diffraction, spectroscopic measurements (IR, Raman, optical spectroscopy), cyclic voltammetry and magnetism. A special attention will be also devoted to the development of new systems with optimized switching properties. During the phD, measurements on synchrotron beamlines will be planned to perform local spectrocopies XANES and XMCD measurements in collaboration with the group of P. Sainctavit (Univ. Paris VI).

[1] J. M. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, C. Mathoni篓篓re, Angew. Chem. Int. Ed., 2004, 43, 5468.
[2] M.-A. Arrio, J. Long, C. Cartier dit Moulin, A. Bachschmitt, V. Marvaud, A. Rogalev, C. Mathoni篓篓re, F. Wilhem, P. Sainctavit, J. Phys. Chem. C, 2010, 114, 593.
[3] O. Stefanczyk, A. M. Majcher, M. Rams, W. Nitek, C. Mathoni篓篓re, B. Sieklucka, J. Mater. Chem. C, 2015, 3, 8712.[ Last edited by liujizgd on 2016-1-26 at 20:05 ]

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