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angela1ying

铁虫 (初入文坛)

[求助] CEJ小修 审稿意见看不懂已有2人参与

小妹第一次回复审稿意见,什么都不懂,请大家帮帮忙啊!
第一个审稿人,有两个地方看不懂。
1.Catalyst characterization is well performed and linked to activity tests, but for some DRX studies that should be performed on the spent catalysts (both the LDH-based and the obtained by incipient wetting) so to complete table 3 and related discussion.
催化剂有DRX这个表征吗?是什么?还是打错了,是XRD?
2.Regarding section 3.3, discussion could be extended by calculating TOFs at zero time for the catalysts used, not only the catalyst performance at high time values. Though, from an industrial point of view, these latter ones are the interesting ones, reaction rates are proportional to TOFs calculated at zero time, and they can suggest even higher differences in activity. As hydrogen seems to saturate at pressures higher than 5 MPa (though this is not stated by authors at the end of page 16), it is probable than hydrogenation kinetics could be simplified to first order, so the kinetic constants could be calculated instead of TOFs (and more discussion performed on this basis).
一开始叫我算TOF,后面又说instead of ?啥意思啊?到底是算还是不算?
第二个审稿人。
In my opinion the article, however, lack information about the reproducibility of the results, both in the production of the catalyst i.e. parameters achieved by it, as well as the results of the proposed process.
这个reproducibility指的是什么的重现性啊?

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antericol

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angela1ying: 金币+10, ★★★★★最佳答案 2015-01-08 12:03:45
第一个审稿人

1.Catalyst characterization is well performed and linked to activity tests, but for some DRX studies that should
没听说过DRX,应该是XRD

2.Regarding section 3.3, discussion could be extended by calculating TOFs at zero time for the catalysts used, not only the catalyst performance at high time values. Though, from an industrial point of view, these latter ones are the interesting ones, reaction rates are proportional to TOFs calculated at zero time, and they can suggest even higher differences in activity.
你应该算开始的TOF,看样子是你只算了后面的TOF,没算开始的。因为审稿人认为zero time TOF更能看出催化活性的区别。
As hydrogen seems to saturate at pressures higher than 5 MPa (though this is not stated by authors at the end of page 16), it is probable than hydrogenation kinetics could be simplified to first order, so the kinetic constants could be calculated instead of TOFs (and more discussion performed on this basis).
这段是说压力大于5 MPa后,催化剂可能已经饱和,氢化过程有可能简化为一级动力学,这样就可以算出动力学常数了。因为动力学常数比TOF更通用,可以算出来就不要用TOF来比较和讨论实验结果。

这两段不矛盾,因为压力小的时候动力学常数算不出来,所以你比较催化活性就用TOF,只是要把zero time TOF也包括进来。

第二个审稿人。
In my opinion the article, however, lack information about the reproducibility of the results, both in the production of the catalyst i.e. parameters achieved by it, as well as the results of the proposed process.

information about reproducibility 用人话说就是实验重复了没有?重复了几次?误差如何?我只是很震惊你报数据没报误差,难道不都是 平均值±标准差 这样的格式吗?再用脚注说明平均值是多少次重复实验
6楼2015-01-07 03:03:23
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brucefan

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angela1ying(自私的猫1988代发): 金币+1, 鼓励交流 2015-01-31 15:29:17
第一个太专业,不敢乱说。第二个是说你的文章缺少一些让别人重复你的工作的细节。写文章要简洁,但更重要的是完整,要让内行读者能重复你的工作。

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2楼2015-01-06 13:08:29
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angela1ying

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引用回帖:
2楼: Originally posted by brucefan at 2015-01-06 13:08:29
第一个太专业,不敢乱说。第二个是说你的文章缺少一些让别人重复你的工作的细节。写文章要简洁,但更重要的是完整,要让内行读者能重复你的工作。

谢谢你的回答,我主要是不明白他指的是哪个地方。他好像说了我催化剂制备的参数,是说得到的比表面什么的要有精度吗?还是要把制备参数说清楚?还有结果重复性又是什么?
3楼2015-01-06 15:58:17
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brucefan

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感谢参与,应助指数 +1
angela1ying(自私的猫1988代发): 金币+1, 鼓励交流 2015-01-31 15:29:26
不是要精度,是你说的要各种参数。看就是说,要让别人看了你的文章能照着你的描述重复你的工作。你看别人的文章的时候也偶尔会想重复一些工作吧?

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4楼2015-01-06 16:07:37
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