±±¾©Ê¯ÓÍ»¯¹¤Ñ§Ôº2026ÄêÑо¿ÉúÕÐÉú½ÓÊÕµ÷¼Á¹«¸æ
²é¿´: 3282  |  »Ø¸´: 23

andyzhu

ľ³æ (ÕýʽдÊÖ)

[½»Á÷] ±»ÕâÑùµÄÉó¸åÒâ¼û¾Ü¸ãÁË¡£

ËäÈ»ÎÒÖªµÀÓÐ×Ô¼ºÊèºöµÄÎÊÌ⣬µ«ÊÇÏà¶ÔÓÚµÚ¶þ¸öÉó¸åÈË£¨Ìá³ö¸ü¶àʵÖÊÒâÒåµÄµÄ½¨Ò飩ÈÃÎÒ´óÐÞ£¬ÎÒ»¹ÊÇÓеãÓôÃÆ¡£°¥£¬ÔËÆø²»ºÃ£¬»¹ÊÇÎÒûÒâʶµ½ÕâЩÎÊÌâÓжàÑÏÖØ£¬Çë¸ßÊÖÖ¸µãÃÔ½ò¡£ÈçÏ¡£

1. The .cif files do not contain the shelx instructions or the reflection intensities. The .fcf file has also not been provided by the authors. As such, the refinement cannot be independently verified by the reviewer. ûÉÏ´«fcf£¬ÊÇ×î´óµÄ×ï¹ý¡£

2. The text mentions the MOF space group is Pcca, however it is listed as Pccn in the .cif files. ÎÒµÄ´í£¬ÑÛÉñ²»ºÃ£¬Ð´´í¡£

3. Page 10, line 208: ¡°Moreover, the presence of trace (CH2)2NH2+ ions used as the counter cations¡­¡± Trace ions?!? Isn¡¯t the dimethyl ammonium the counter ion for the structure? I would expect it to be present in stoichiometric proportions, not trace amounts¡­×Ô¼º±í´ï²»Çå¡£

4. The authors claim that the (CH2)2NH2+ ion is the charge balancing cation in the MOF structures, however, the authors present no evidence to support this claim. Given that the authors claim that the cation influences the physical properties of the material (Page 10 line 208), the chemical identity of the cation should be established unambiguously.¸øÎÒ¸ö»ú»á£¬ÎÒ¿ÉÖ¤Ã÷£¬µÄÈ·  (CH2)2NH2+ÕæÊµ´æÔÚ¡£¡£

5. Several notable entries in the crystal data table (S1) are absent: number of parameters, number of restraints, cell volume, 2-theta range, Rint, hkl limits.ÎÒ¿ÉÒÔ²¹µÄ£¬µ«ÊÇÎҵıí¸ñ¾ÍÊdz­µÄÕâ¸öÔÓ־֮ǰtable¡£¡£

6. None of the datablock names in the .cif files or cifchecks matches the names in the manuscript. This unnecessarily complicates reviewer evaluations.ÄѵÀÎÒµÄcifÃüÃûΪÎÒµÄCCDCºÅÒ²ÊÇÒ»ÖÖ´íÎ󣿲»½â¡£¡£

7. The Eu structure contains 12 restraints. No details are given. ֮ǰͶ¸åûעÒâÕâ¸öÒª¡£ÒÔºó´ó¼ÒҪעÒâÁË£¬ÌرðÊǾ§ÌåѧÔÓÖ¾

8. The H2DDQ structure: H1 does not appear to be in a correctly refined position. Likewise, the protons on the water molecule have not been refined. It seems that they should be added such that they form hydrogen bonds with N2 and O2.

9. Both the Eu and Er structures contain very large residual electron density peaks. The location of the peaks should be mentioned and explained.Ï¡ÍÁ½ðÊôÈÝÒ׳öÏÖ¹í·å£¬ÎÒ¾ÍÉÙ˵ÁËÒ»¾ä¡£

10. While MOF datasets are often of poor quality and low resolution/completeness, this should not be the case for well-packed small molecules. Though the completeness is reasonable at 0.977, why is this not closer to 1.0? Was the data collected properly? Was there a problem with the data processing? ÍêÕû¶È0.977ÔÚÎÒÃÇѧУ²âÊÔ¿ÉÒÔÁË£¬ÆØ¹âʱ¼ä3S, Èýбɨһ°ã700ÕÅ

11. For all structures, the formulas should be updated to reflect the refined data. Atoms which are not present (for example, Cl and P in the H2DDQ structure) should be removed. ÒòΪÌåϵÓÐÕâ¸öÔªËØ£¬½âµÄʱºò¶¨ÁËP ClÁË£¬µ«ÊÇÕâ²»ÖÁÓھܸã°É¡£
»Ø¸´´ËÂ¥

» ²ÂÄãϲ»¶

» ±¾Ö÷ÌâÏà¹Ø¼ÛÖµÌùÍÆ¼ö£¬¶ÔÄúͬÑùÓаïÖú:

ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
2Â¥2014-07-06 09:17:36
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

andyzhu

ľ³æ (ÕýʽдÊÖ)

ÒýÓûØÌû:
2Â¥: Originally posted by wwyy123 at 2014-07-06 09:17:36

3Â¥2014-07-06 09:29:11
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

supervb

Ìú¸Ëľ³æ (ÎÄ̳¾«Ó¢)

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
Сľ³æ: ½ð±Ò+0.5, ¸ø¸öºì°ü£¬Ð»Ð»»ØÌû
andyzhu: ½ð±Ò+5, ÎÒͶµÄÊǶþÇøµÄ£¬Ó¦¸Ã¶¼»áÏȼ¼ÊõÉó²é°É£¬²»¹ýÎÒ¾õµÃÄã˵µÄ¶Ô£¬¶à´Ó×ÔÉíÕÒÎÊÌâ°É£¬ 2014-07-06 09:42:29
Â¥Ö÷¸å×ÓÀï¹À¼Æ¸ú¸ÃÔÓÖ¾ÒªÇóÏà㣵Ķ«Î÷Ì«¶àÁË£¨ÓÈÆäÊǼ¼Êõ¸ñʽºÍÎļþÉÏ´«ÒªÇóµÈµÈ£©£¬±»Éó¸åÈËÕâôһÂÞÁгöÀ´£¬±à¼­Ò»¿´¿Ï¶¨¾Ü¸å°¡£¡ÆäʵÕâÖÖÇé¿ö»»µ½ÈκÎÔÓÖ¾£¨¹úÄڵIJ»Ëã¡¢ÊÕ·ÑË®»õ²»Ë㣩¶¼Òª±»¾Ü¸åµÄ£¬ÒòΪ²»·ûºÏÂÛÎÄÉÏ´«ÒªÇóÁË£¬Èç¹û¼¼ÊõÉó²éÔÚǰµÄ»°£¬¶¼²»ÓÃËÍÉó¾ÍÖ±½Ó¾ÜÁË¡£
Õâ²»ÊÇÔËÆø²»ºÃ£¬ÕâÊÇ·¸´íÌ«¶à£¡´òÌú»¹Ðè×ÔÉíÓ²°¡£¡
ÔÛÊÇ×ö·ÇÏßÐÔËæ»ú¶¯Á¦Ñ§µÄÓ´
4Â¥2014-07-06 09:35:17
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

b040426

гæ (ÖªÃû×÷¼Ò)

¡ï
Сľ³æ: ½ð±Ò+0.5, ¸ø¸öºì°ü£¬Ð»Ð»»ØÌû
·´·´¸´¸´µÄ·­³ª v ±¦±´Äã¿´ ii
5Â¥2014-07-06 10:01:19
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

¿§à¬VSÍÁ¶¹

ÈÙÓþ°æÖ÷ (ÎÄ̳¾«Ó¢)

ÎÄÏ׽ܳö¹±Ï×

¡ï ¡ï ¡ï
Сľ³æ: ½ð±Ò+0.5, ¸ø¸öºì°ü£¬Ð»Ð»»ØÌû
andyzhu: ½ð±Ò+2, лл£¬»¹ÊÇ×Ô¼ºÃ»µ½»ðºò¡¢ 2014-07-06 15:27:30
³Ôһǵ³¤Ò»ÖÇ£¬ÕâÖÖ´íÎóÏ´β»·¸¾Í¿ÉÒÔÁË
ÌìµÀ³êÇÚ
6Â¥2014-07-06 10:03:21
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
¡ï
andyzhu: ½ð±Ò+1 2014-07-06 15:27:33
7Â¥2014-07-06 10:20:18
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

luxtal

ÖÁ×ðľ³æ (Ö°Òµ×÷¼Ò)

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
Сľ³æ: ½ð±Ò+0.5, ¸ø¸öºì°ü£¬Ð»Ð»»ØÌû
andyzhu: ½ð±Ò+10, ¶÷£¬ÆäÊµÕæÐľõµÃÕâ²»Ó¦¸ÃÊǾܸåµÄÀíÓÉ£¬µ«ÊÇÈç¹û×Ô¼º×öµÄ¸üºÃµã£¬½á¹û¿Ï¶¨¸üºÃ¡£ 2014-07-06 15:28:50
ÅöÉϸö¾ÍÊìϤ¾§Ìå½á¹¹¾«ÐÞµÄÉó¸åÈË£¬Ã»ÌáʲôÓм¼Êõº¬Á¿µÄÎÊÌ⣬¶¼ÊÇë´Ì£¡
»»¸öÔÓÖ¾°É£¬Ã»É¶´ó²»ÁË£¡
What_we_observe_is_not_nature_itself,_but_nature_exposed_to_our_method_of_questioning----Werner_Karl_Heisenberg
8Â¥2014-07-06 10:22:03
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

xiaochong98

ľ³æ (Ö°Òµ×÷¼Ò)

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
Сľ³æ: ½ð±Ò+0.5, ¸ø¸öºì°ü£¬Ð»Ð»»ØÌû
andyzhu: ½ð±Ò+5, ÆäʵֻÓÐÒ»´¦²»Ò»Ö£¬¾ÍÊǿռäȺд´í¡£¶øÇÒÎÒÕâ¸öÎÄÕÂÊǺÜÓÐÓ°ÏìµÄÒ»ÇøÎÄÕ±»¾Üºó¸ÄͶµÄ¡£ÎÒÖ»ÄÜ˵ÕâЩÎÊÌâÊÇÅöµ½Ò»¸ö¸ü¼Ó¾«Í¨¾§ÌåѧµÄÀÏʦ£¬Àä¾²ÏÂÀ´£¬ÎÒÏÖÔÚ¸üÓ¦¸Ã·´Ê¡¡£Ð»Ð»¡£ 2014-07-06 15:32:32
¸çÃÇ¡£Ö÷ÒªÊÇÄãµÄCIFÎļþÓëÂÛÎÄÖжദ´æÔÚ²»Ò»Öµĵط½£¬ÕâÖÖ¸å¼þ£¬Ò»·½ÃæÌåÏÖͶ¸åÕß×ÔÉíÒµÎñ²»Ê죬µÚ¶þ£¬ÌåÏÖͶ¸åÈË̬¶È²»ÈÏÕæ£¬ÕâÑùµÄ¸å¼þ£¬ÎÒÒ²»áÖ±½Ó¾ÜµôµÄ¡£
±±¾©ÈË
9Â¥2014-07-06 10:27:35
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
¡ï
andyzhu: ½ð±Ò+1, 3Q 2014-07-06 15:32:45
×£¸£¡£¡£¡£¡£¡£¡£¡£¡£¡£¡£¡£
10Â¥2014-07-06 10:34:32
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
Ïà¹Ø°æ¿éÌø×ª ÎÒÒª¶©ÔÄÂ¥Ö÷ andyzhu µÄÖ÷Ìâ¸üÐÂ
×î¾ßÈËÆøÈÈÌûÍÆ¼ö [²é¿´È«²¿] ×÷Õß »Ø/¿´ ×îºó·¢±í
[¿¼ÑÐ] 08600ÉúÎïÓëÒ½Ò©-327 +6 18755400796 2026-04-05 6/300 2026-04-05 22:03 by imissbao
[¿¼ÑÐ] 296Çóµ÷¼Á +3 Íô£¡£¿£¡ 2026-04-05 4/200 2026-04-05 20:13 by à£à£à£0119
[¿¼ÑÐ] Çóµ÷¼Áµ½0856²ÄÁϹ¤³Ì +3 ³Ì9915 2026-04-05 3/150 2026-04-05 18:15 by À¶ÔÆË¼Óê
[¿¼ÑÐ] 348Çóµ÷¼Á +6 wukira 2026-04-04 6/300 2026-04-05 18:11 by Öí»á·É
[¿¼ÑÐ] Çóµ÷¼Á +4 wos666 2026-04-03 4/200 2026-04-05 11:48 by arrow8852
[¿¼ÑÐ] 270Çóµ÷¼Á +9 С½Üpp 2026-03-31 11/550 2026-04-05 11:02 by ·çÓêÎÞÇç
[¿¼ÑÐ] Ò»Ö¾Ô¸Ö£´ó0705Çóµ÷¼Á +3 éÙʮһ 2026-04-02 4/200 2026-04-05 00:05 by chongya
[¿¼ÑÐ] 277Çóµ÷¼Á +4 12A3 2026-04-02 5/250 2026-04-04 20:28 by À¶ÔÆË¼Óê
[¿¼ÑÐ] 319Çóµ÷¼Á +4 ÐÇÐDz»Õ£ÑÛà¶ 2026-04-03 4/200 2026-04-04 16:25 by ÖзÉÔº¿Õ¹ÜѧԺÑ
[¿¼ÑÐ] 357Çóµ÷¼Á +13 1050389037 2026-04-03 13/650 2026-04-03 22:27 by Î޼ʵIJÝÔ­
[¿¼ÑÐ] 322Çóµ÷¼Á +6 FZAC123 2026-04-03 6/300 2026-04-03 22:23 by ¿ÆÑÐСר¼Ò
[¿¼ÑÐ] ¿¼Ñе÷¼Á +5 СsunÒªºÃÔË 2026-04-03 5/250 2026-04-03 21:43 by à£à£à£0119
[¿¼ÑÐ] 286Çóµ÷¼Á +8 lim0922 2026-04-02 8/400 2026-04-03 20:19 by rzh123456
[¿¼ÑÐ] ÍÁľˮÀû328·ÖÇóµ÷¼Á +6 ¼²·çÖª¾¢²Ý666 2026-04-02 6/300 2026-04-03 11:38 by znian
[¿¼ÑÐ] 279Çóµ÷¼Á +5 ¸µÎÄÇï 2026-04-02 5/250 2026-04-02 18:10 by ±ÊÂä½õÖÝ
[¿¼ÑÐ] Ò»Ö¾Ô¸±±½»´ó²ÄÁϹ¤³Ì×Ü·Ö358 +3 cs0106 2026-04-02 5/250 2026-04-02 11:37 by olim
[¿¼ÑÐ] 279Çóµ÷¼Á +7 Īxiao 2026-04-01 7/350 2026-04-01 22:05 by ¿Í¶ûÃÀµÂ
[˶²©¼ÒÔ°] ¿¼Ñе÷¼Á +5 ÂæÍÕÄÐÈË 2026-04-01 5/250 2026-04-01 14:28 by syjjj0321
[¿¼ÑÐ] ÍÁľ304Çóµ÷¼Á +5 ¶¥¼¶²Á²Á 2026-03-31 5/250 2026-04-01 08:15 by fdcxdystjk£¤
[¿¼ÑÐ] Ò»Ö¾Ô¸Î÷µç085401ÊýÒ»Ó¢Ò»299Çóµ÷¼Á Áù¼¶521 +4 °®³Ô´óѼÀæ 2026-03-31 4/200 2026-03-31 11:51 by ²«»÷518
ÐÅÏ¢Ìáʾ
ÇëÌî´¦ÀíÒâ¼û