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1. The .cif files do not contain the shelx instructions or the reflection intensities. The .fcf file has also not been provided by the authors. As such, the refinement cannot be independently verified by the reviewer. ûÉÏ´«fcf£¬ÊÇ×î´óµÄ×ï¹ý¡£

2. The text mentions the MOF space group is Pcca, however it is listed as Pccn in the .cif files. ÎÒµÄ´í£¬ÑÛÉñ²»ºÃ£¬Ð´´í¡£

3. Page 10, line 208: ¡°Moreover, the presence of trace (CH2)2NH2+ ions used as the counter cations¡­¡± Trace ions?!? Isn¡¯t the dimethyl ammonium the counter ion for the structure? I would expect it to be present in stoichiometric proportions, not trace amounts¡­×Ô¼º±í´ï²»Çå¡£

4. The authors claim that the (CH2)2NH2+ ion is the charge balancing cation in the MOF structures, however, the authors present no evidence to support this claim. Given that the authors claim that the cation influences the physical properties of the material (Page 10 line 208), the chemical identity of the cation should be established unambiguously.¸øÎÒ¸ö»ú»á£¬ÎÒ¿ÉÖ¤Ã÷£¬µÄÈ·  (CH2)2NH2+ÕæÊµ´æÔÚ¡£¡£

5. Several notable entries in the crystal data table (S1) are absent: number of parameters, number of restraints, cell volume, 2-theta range, Rint, hkl limits.ÎÒ¿ÉÒÔ²¹µÄ£¬µ«ÊÇÎҵıí¸ñ¾ÍÊdz­µÄÕâ¸öÔÓ־֮ǰtable¡£¡£

6. None of the datablock names in the .cif files or cifchecks matches the names in the manuscript. This unnecessarily complicates reviewer evaluations.ÄѵÀÎÒµÄcifÃüÃûΪÎÒµÄCCDCºÅÒ²ÊÇÒ»ÖÖ´íÎ󣿲»½â¡£¡£

7. The Eu structure contains 12 restraints. No details are given. ֮ǰͶ¸åûעÒâÕâ¸öÒª¡£ÒÔºó´ó¼ÒҪעÒâÁË£¬ÌرðÊǾ§ÌåѧÔÓÖ¾

8. The H2DDQ structure: H1 does not appear to be in a correctly refined position. Likewise, the protons on the water molecule have not been refined. It seems that they should be added such that they form hydrogen bonds with N2 and O2.

9. Both the Eu and Er structures contain very large residual electron density peaks. The location of the peaks should be mentioned and explained.Ï¡ÍÁ½ðÊôÈÝÒ׳öÏÖ¹í·å£¬ÎÒ¾ÍÉÙ˵ÁËÒ»¾ä¡£

10. While MOF datasets are often of poor quality and low resolution/completeness, this should not be the case for well-packed small molecules. Though the completeness is reasonable at 0.977, why is this not closer to 1.0? Was the data collected properly? Was there a problem with the data processing? ÍêÕû¶È0.977ÔÚÎÒÃÇѧУ²âÊÔ¿ÉÒÔÁË£¬ÆØ¹âʱ¼ä3S, Èýбɨһ°ã700ÕÅ

11. For all structures, the formulas should be updated to reflect the refined data. Atoms which are not present (for example, Cl and P in the H2DDQ structure) should be removed. ÒòΪÌåϵÓÐÕâ¸öÔªËØ£¬½âµÄʱºò¶¨ÁËP ClÁË£¬µ«ÊÇÕâ²»ÖÁÓھܸã°É¡£
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