For a reversible reaction, ip∝ v^1/2，since the electrode reaction is reversible while the fragmentation reaction is irreversible, the different between cathodic peak current density icp and anodic peak current density iap should be responsible for the a-* consumption, then you can determine k

引用回帖:

2楼: Originally posted by 小毛球 at 2020-08-04 00:54:49
For a reversible reaction, ip∝ v^1/2，since the electrode reaction is reversible while the fragmentation reaction is irreversible, the different between cathodic peak current density icp and anodic  ...

Sorry the computer in the campus dont provide chinese input method... Really thank you for the explanation. I now figure out how the rate constate relates to the current density but still feel confused about the function of the halfwave potential during a CV exp. Could you please help or suggest a book or an article? Thank you
，

引用回帖:

3楼: Originally posted by cherubruby at 2020-08-04 19:36:43
Sorry the computer in the campus dont provide chinese input method... Really thank you for the explanation. I now figure out how the rate constate relates to the current density but still feel confu ...

《Electrochemical Methods Fundamentals and applications》 by Allen J. Bard, this book is really classic