腐蚀电化学中腐蚀电位分析求助
The authors added the explanation of corrosion potentials (p. 29) in which the corrosion potential of Fe-C-MoO2 is shifted to the more negative value compared with that of Fe. The reviewer can not understand this explanation. It is assumed that the authors ignore the electrochemistry, i.e., the electron transfers at the solid/electrolyte interface must obey the electrochemical rule and when the cathodic reaction rate is enhanced, the corrosion potential (i.e., the open circuit potential in a corrosion system) must be shifted to the positive direction.
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电化学电流密度增大,腐蚀电位负向移动怎解释?
电流密度大,材料与腐蚀液反应越快(动力学);腐蚀点位越负,材料发生腐蚀概率越大(热力学)
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