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【请教】NEXAFS

作者 hustnano
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在文献中看到一种表征方法near edge x-ray absorption fine structure spectroscopy(NEXAFS)用来表征分子面与基底的夹角,想请教一下该方法的原理。 返回小木虫查看更多

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  • 化学041

    引用回帖:
    Originally posted by semimetal at 2009-3-25 10:11:
    EXAFS就是用来测原子的配位结构的,这时入射光的能量要大于吸收边的,光子就会与电子相互作用在测量原子周围进行多次散射,在谱中表现为震荡,再经过一系列处理即可得到配位信息。我这有些资料,谁要要的话我可以 ...

    很是需要,wlxl03150415@126.com,太感谢了,太及时了!

  • renart306

    用这个可以测试固体表面聚合物链的螺旋结构吧,比如说13/6螺旋等?
    不知道北京哪里可以做这个测试?网上搜了一下也没有查到,呵呵

    或者有没有别的简单一些的方法?

  • semimetal

    引用回帖:
    Originally posted by renart306 at 2009-5-14 11:22:
    用这个可以测试固体表面聚合物链的螺旋结构吧,比如说13/6螺旋等?
    不知道北京哪里可以做这个测试?网上搜了一下也没有查到,呵呵

    或者有没有别的简单一些的方法?

    我不知道你的聚合物具体是什么东西,EXAFS最多能得到测试原子3、4个壳层的配位信息。北京高能所的同步可以做,不过开的时间太少;现在上海同步今年已建好EXAFS站,你可以试一下申请到那里去做。

  • yhw9102

    EXAFS(包括近边)这个东东在国内可以做的地方很少,北京高能所、合肥同步辐射、上海新光源的站不知道好了没有。
    做试验比较简单 数据处理的工作非常麻烦
    除非你和做试验的老师关系比较好 让他多教教你
    要是你自己搞呀 呵呵 我先佩服你一下!
    先看看文献综述把原理搞明白
    数据处理软件呀 国际主流都用UW一帮人搞的Feff系列的
    光是这个软件就够你琢磨很久的啦


    祝你好运!

  • scu_hth

    NEXAFS: near edge X-ray absorption fine structure  
    The Kronig near edge structure has been mostly referred to as the X-ray absorption near edge structure, XANES, or the near edge X-ray absorption fine structure, NEXAFS. The term XANES is more commonly used for solids and inorganic complexes while NEXAFS is used more in conjunction with surfaces. In fact, the name NEXAFS was created in part because it rhymes with SEXAFS, the surface version of EXAFS, and it constitutes the first part of a SEXAFS spectrum. Alternatively, one can think of "N" EXAFS as "Not" EXAFS. We use the term NEXAFS specifically for K-shell excitation spectra of low-Z molecules adsorbed on surfaces.

    The above paragraph is excerpted from the following book:
    Book Name: NEXAFS Spectroscopy
    Author: Joachim Stohr
    Publisher: Springer

    I have this book in hand. If you need it, I can e-mail it to you,

  • liuqiying

    引用回帖:
    Originally posted by scu_hth at 2009-5-30 23:44:
    NEXAFS: near edge X-ray absorption fine structure  
    The Kronig near edge structure has been mostly referred to as the X-ray absorption near edge structure, XANES, or the near edge X-ray absorption ...

    can your send this book to me: lqy501@dicp.ac.cn
    this book is very important for me, thank you so much!

  • scu_hth

    为了方便大家下载,我已将该书上传到纳米机器人,链接如下,欢迎大家下载:
    http://www.namipan.com/d/NEXAFS% ... 1cf48c75adc89217d00

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