参考文献 1.Synlett (2007), (17), 2671-2674.
2.Dehydration of aldoximes over H-zeolites: A convenient and highly atom economic method for the preparation of nitriles. Thomas, Bejoy; Prathapan, S.; Sugunan, S. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, India. Chemical Engineering Journal (Amsterdam, Netherlands) (2007), 133(1-3), 59-68.
3.Solvent-free synthesis of nitriles from aldehydes catalyzed by KF/Al2O3, montmorillonite KSF and K10. Li, Li-Jun; Song, Ying-Xia; Gao, Yan-Su; Li, Yan-Feng; Zhang, Jian-Feng. College of Chemistry and Environmental Science, Hebei University, Baoding, Hebei Province, Peop. Rep. China. E-Journal of Chemistry (2006), 3(12), 164-168.
4.ZnO/CH3COCl: A new and highly efficient catalyst for dehydration of aldoximes into nitriles under solvent-free condition. Sarvari, Mona Hosseini. Department of Chemistry, Faculty of Science, Shiraz University, Shiraz, Iran. Synthesis (2005), (5), 787-790，
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参考文献 1.Synlett (2007), (17), 2671-2674.
2.Dehydration of aldoximes over H-zeolites: A convenient and highly atom economic method for the preparation of nitriles. Thomas, Bejoy; Prathapan, S.; Sugunan, S. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, India. Chemical Engineering Journal (Amsterdam, Netherlands) (2007), 133(1-3), 59-68.
3.Solvent-free synthesis of nitriles from aldehydes catalyzed by KF/Al2O3, montmorillonite KSF and K10. Li, Li-Jun; Song, Ying-Xia; Gao, Yan-Su; Li, Yan-Feng; Zhang, Jian-Feng. College of Chemistry and Environmental Science, Hebei University, Baoding, Hebei Province, Peop. Rep. China. E-Journal of Chemistry (2006), 3(12), 164-168.
4.ZnO/CH3COCl: A new and highly efficient catalyst for dehydration of aldoximes into nitriles under solvent-free condition. Sarvari, Mona Hosseini. Department of Chemistry, Faculty of Science, Shiraz University, Shiraz, Iran. Synthesis (2005), (5), 787-790，
我帮你搜了一下
搜索结果如下，你自己看看好了
附件中是"对羟基苯甲腈合成方法"
成肟脱水成腈基的过程一气呵成
[ Last edited by gtyhlag on 2008-6-21 at 02:24 ]
burgess试剂，试试吧，会有惊喜的
谢谢分享！我已得到做终产物，是用ZnO和乙酰氯做的，NMR和MS都是对的，但是原料没反应完，转化率太低，只有50%转化，可能是搅拌不好。请问你们做这步反应产率能达到多少？具体怎么操作的？
我现在正在试P2O5.希望找一个操作简单又经济实惠的方法，希望有经验的虫子分享分享，谢谢！
没人理我了。。。
好难啊，也许是我制备的醛不纯，肟也没纯化，现在我是先过柱，再重结晶，产率还是没提上去。。。不知谁能帮我啊。。。。
还有，我想问下，苯环上一个醛基的产率能达到80%吗？谢谢 ！