Ag atom is heavier than Zn atom ,therefore according to the well established theories of irrational modes in mixed crystals the substitution should result in a
downward shift of the fundamental transverse optical phonon mode.
按谷歌翻译,theories of irrational modes译为非理性模式理论,但是搜这个理论中文名字木有找到!我觉得翻译有问题,有虫友知道这种理论吗?