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金虫 (小有名气)

[求助] 求神们帮助翻译成中文》.《写材料急用

Ironeiron hydrogenase active subunit covalently linking to organic chromophore for light-driven hydrogen evolution
a b s t r a c t
The first photocatalytic [FeFe]-hydrogenase ([FeFe]-H2ase) mimic 3 with noble-metal-free benzothiazole as donating photosensitizer had been successfully constructed via an easily accessible approach, and fully characterized by various spectroscopic and X-ray crystallographic techniques. Steady-state spectroscopy and electrochemistry revealed the evidences indicating that the photo-induced electron transfer occurred in 3. The reduced [FeIFe0] species was further confirmed by laser flash photolysis and considered to be responsible for the light-driven H2 evolution. As a result, the photocatalytic system consisting of the photocatalyst 3 and the sacrificial electron donor in the presence of proton source indeed produced H2 with a turnover number (TON) of 24.2 under light irradiation. The TON indicated a remarkably photocatalytic efficiency for an [FeFe]-H2ase mimic assembled by the covalent combination of a photosensitizer to the catalytic center. The results demonstrated the tremendous potential of present synthetic strategy for the construction of compact, inexpensive, easily accessible [FeFe]-H2ase model complexes as photocatalysts.

求神们帮助翻译成中文》.《写材料急用
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1楼 2015-05-24 10:39:10
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huczustc

至尊木虫 (知名作家)

【答案】应助回帖

你应该把专业词汇给出来，别人才好给你进行翻译
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因为相信，所以简单
2楼2015-05-24 19:49:22
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