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| This has been attributed to slow mass transport and faster back reaction of photo-injected electrons with the oxidized redox species coupled with the slow regeneration of the Co(II) species at the cathode. Recently, cobalt redox shuttles have attracted renewed attention after Feldt et al. increased the power conversion efficiency (PCE) to 6.7% by employing a newly designed D-¦Ð-A organic sensitizer, coded D35, in conjunction with the cobalt (III/II) tris-bipyridyl complex, [Co(III)(bpy)3](PF6)3/[Co(II)(bpy)3](PF6)2 couple. |
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