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metalmood

铜虫 (小有名气)

[求助] 外行求助——CrystEngCommn 审稿意见不知咋改

本人晶体小白一个,不会解晶体。这次投rsc的 CrystEngCommn ,审稿人要求小修,意见如下:
完全不知道咋改和咋回应,请各位高手详细的指点一下,步骤越具体越好
Please add details of the absortion correction to the CIF at_exptl_absorpt_process_details    ?

You have described your attempts to model the water molecules as multi-site- it would be useful to add this information to the description of the x-ray experiment in the ESI and to the CIF.  This is particularly relevant to your description of H-bonding.

There are checkCIF alerts, which may be related to the poor model for this electron density:

DIFMN02_ALERT_2_C The minimum difference density is < -0.1*ZMAX*0.75
_refine_diff_density_min given = -0.673
Test value = -0.600
DIFMN03_ALERT_1_C The minimum difference density is < -0.1*ZMAX*0.75
The relevant atom site should be identified.
DIFMX01_ALERT_2_C The maximum difference density is > 0.1*ZMAX*0.75
_refine_diff_density_max given = 0.711
Test value = 0.600
DIFMX02_ALERT_1_C The maximum difference density is > 0.1*ZMAX*0.75
The relevant atom site should be identified.

The closest atom site to these areas of residual electron density should be identified in the CIF and an indication of what you have tried to model this also included.
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【答案】应助回帖

linhua0402313: 这是求助帖,不要随便点应助,你可以开个新帖 2012-07-15 21:44:50
谁在http://journals.iucr.org/c/journalhomepage.html,acta c上投过稿,小弟想请教一下,谢谢大侠。
多多请教
2楼2012-07-15 21:33:40
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