看了崔屹Nano Today的文献《Designing nanostructured Si anodes for high energy lithium ion batteries》,P417里有一句话是这样的,我没太能理解是什么意思。请各位锂离子电池的大神解释一下!金币不多,真心求解!
In other words, for smaller structures, the stress-relief volume accompanying crack growth is not significant enough to overcome the surface energy penalty associated with the crack growth.