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xyljilin

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1. Did the authors check the presence of M to ligand charge- transfer in their sytstems? The ligand should possess a good antenna effect.
ÎÒ×öµÄÕâ¸öÊÇPbµÄÅäºÏÎÁ½ÖÖÅäÌåµÄ·¢¹â·åλ·Ö±ðÔÚ 354 nmºÍ 444 nm´¦£¬ÅäºÏÎïµÄ·¢¹â·åλÔÚ508 nm¡£ÎÒ°ÑËü¹éΪ¡° a metal-centered transition involving the s and p metal orbitals¡±¡£±à¼­Ìá³öÈçÉÏÒÉÒ壬µ½µ×Ó¦¸Ã¹éÊô³ÉÊ²Ã´ÄØ£¿
2. Also, the structures of complexes 2 and 3 should be discussed in more details taken in consideration the backing effects.
ʲôÊÇ¡°the backing effects¡±£¿
3. Figure 2: Why is the water molecule omitted from the network structure of complex 1? The water molecules should play an essential role in connecting the 1D-chains creating 3D- network. If this is not the case, the authors should clear this argument.
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4. -In the discussion the authors should discuss how their new structure relates to similar compounds such as. Citation are only for M-O and M-N lengths. Please correct.
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5. -In last sentence of TGA section, the authors have writen: "We believe that different coordinated modes are the main reasons that lead to the difference in their TGA". But, TGA curves of samples are similar and I do not see differences in their TGA. Please explain and correct.
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xyljilin

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