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shanshi2676

铁虫 (小有名气)

[求助] 求助修改意见,急用!!!!

最近投以一篇ACTA  E
审稿人意见:Please describe treatment of methyl hydrogens. Particularly - if their position were optimized rotationally (this is important because you declare C(Me)-H...O bond formation using geometrically calculated hydrogen's position).
我的refinement:All non-hydrogen atoms were refined with anisotropic displacement parameters. Hydrogen atoms attached to anisotropically refined atoms were placed in geometrically idealized positions and included as riding atoms with C—H = 0.95Å and Uiso(H) = 1.2Ueq(C) (aromatic); C—H = 0.96 and 0.98Å and Uiso(H) = 1.5Ueq(C) (methyl); C—H = 0.96 and 0.99 Å and Uiso(H) = 1.2Ueq(C) (methylene).
请问怎么修改?????
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hawkklins

铜虫 (正式写手)

就是说,他觉得你通过理论加氢的方法修出来的氢用来说明你的C-H...O键的生成可能不合适。希望你说明一下你加氢的方法。
想办法说服他,你这样的加氢方法对于证明你的C-H...O键的存在是合理的就行了。
2楼2012-03-28 19:40:52
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