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Thank you for submitting your manuscript for publication in Energy & Fuels.  I understand from my preliminary reading that you have devised and tested a novel catalyst for the title reaction.] However, before I can send the manuscript out for review I must ask you to revise it to address a point that I am certain will concern the reviewers and two points that our policies now require of all contributions in this topical area.


Next, I must ask you to report the conversion data as reaction rates, normalized by the number of ostensible catalytic sites (i.e., as turnover rates). Preferably, the kinetics results would be captured as rate equations in which the Arrhenius parameters (normalized pre-exponential factor, apparent activation energy) could be compared with those expected from the likely rate determining step and with those obtained in other laboratories. Presumably you are exploiting the acidity of the zeolites but the results may track better with the metal function you have added. In either case, a normalization will assist the readers.

Finally, because you have studied catalysts in liquid phase, I must ask you to present evidence that the reaction rates have not been influenced by the rates of internal mass transport. A Koros-Nowak or Madon-Boudart test would suffice. Either test will require that you prepare catalysts with different loadings and then demonstrate that the normalized reaction rates are independent of loading.

You will understand that we are striving to archive results that can be readily compared across laboratories and that bear on the underlying molecular phenomena.

I am obliged to formally reject this manuscript to give you the opportunity to make those changes. If you continue to consider that Energy & Fuels can provide your work with an attentive audience then, when further experimentation, analysis, and revisions allow you to address those concerns in full we would be willing to consider a revised manuscript as a new submission. Please refer to the Manuscript ID above and include a detailed list of the changes you make when you submit the new manuscript so we can process it rapidly.

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