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Ï£Íû´ó¼Ò¶à¶à·ÖÏíºÃ×ÊÁÏ£¬Á˽âÄÉÃײÄÁÏ×îнøÕ¹£¡£¡£¡ ÈçÓÐÖ§³ÖÕß½«×ÊÁÏ·¢µ½´ËÖ÷Ì⣬лл£¡£¡£¡£¡ Ï£Íû´ó¼Ò¶à¶àÖ§³Ö£¡£¡£¡£¡ ÎÒÏÈÅ×שÒýÓñ£¡£¡£¡£¡ ÃÀ»¯Ñ§¼Ò·¢ÏÖ½ðÄÉÃ×°ô×Ô·¢µØ½«×Ô¼º×é×°³ÉÒ»ÖÖ»·×´³¬½á¹¹ Science Daily ¡ª Rice University chemists have discovered that tiny building blocks known as gold nanorods spontaneously assemble themselves into ring-like superstructures. Á´½Ó£ºhttp://www.SciEI.com/news/science/Chemistry/Index.html This finding, which will be published the chemistry journal Angewandte Chemie, could potentially lead to the development of novel nanodevices like highly sensitive optical sensors, superlenses, and even invisible objects for use in the military. ¡°Finding new ways to assemble nano-objects into superstructures is an important task because at the nanoscale, the properties of those objects depend on the arrangement of individual building blocks,¡± said principal investigator Eugene Zubarev, the Norman Hackerman-Welch Young Investigator and assistant professor of chemistry at Rice. Although ring-like assemblies have been observed in spherical nanoparticles and other symmetrical molecules, until now such structures had not been documented with rod-shaped nanostructures. Like many nanoscale objects, gold nanorods are several billionths of a meter, or 1,000 times smaller than a human hair. Zubarev used hybrid nanorods for this research because attached to their surface are thousands of polymer molecules, which are flexible chainlike structures. The central core of the nanorods is an inorganic crystal, but the polymers attached to the outside are organic species. The combination of the inorganic and organic features resulted in a hybrid structure that proved to be critical to the study. Ó¢ÎÄÈ«ÎÄ£ºhttp://www.sciencedaily.com/releases/2007/03/070310145606.htm [ Last edited by popsheng on 2007-4-28 at 18:12 ] |
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wshk1980
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Aberration-Corrected Imaging of Active Sites on Industrial Catalyst Nanoparticle Lionel Cervera Gontard, Lan-Yun Chang, Crispin J. D. Hetherington, Angus I. Kirkland, Dogan Ozkaya, and Rafal E. Dunin-Borkowski Angew. Chem. Int. Ed. 2007, 46, 1 ¨C 4 http://www3.interscience.wiley.c ... /114199478/PDFSTART |
2Â¥2007-03-24 14:00:24
wshk1980
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3Â¥2007-03-29 16:27:40
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4Â¥2007-03-29 18:47:14
zhaokelun1975
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IBM½«Ä¦¶û¶¨ÂÉÍÆ½øµ½Èýάʱ´ú ÈüµÏÍø2007Äê4ÔÂ27ÈÕѶ ÈÕǰ£¬IBMÐû²¼ÔÚÖÆÔì»·¾³ÖÐʵÏÖÁËÒ»ÖÖÍ»ÆÆÐÔµÄоƬ¶Ñµþ¼¼Êõ£¬´Ë¾ÙÎªÖÆÔìÈýάоƬɨÇåÁËÕϰ£¬Ä¦¶û¶¨ÂÉÒ²½«Òò´Ë¶øÍ»ÆÆÔÀ´Ô¤ÆÚµÄ¼«ÏÞ¡£ÕâÖÖ±»³ÆÎª¡°´©Í¸¹èͨµÀ£¨through-silicon vias£©¡±µÄ¼¼Êõ¿ÉÒÔ´ó´óËõС²»Í¬Ð¾Æ¬×é¼þÖ®¼äµÄ¾àÀ룬´Ó¶øÉè¼Æ³öËٶȸü¿ì¡¢Ìå»ý¸üСºÍÄܺĸüµÍµÄϵͳ¡£ IBMµÄÕâÏîÍ»ÆÆÊµÏÖÁË´Ó¶þάоƬÉè¼Æµ½ÈýάоƬ¶ÑµþµÄת±ä£¬½«´«Í³Éϲ¢ÅŰ²×°ÔÚ¹èԲƬÉϵÄоƬºÍÄÚ´æÉ豸ÒԶѵþµÄ·½Ê½Ï໥µþ¼ÓÔÚÒ»Æð£¬×îÖÕʵÏÖÁËÒ»ÖÖ½ô´ÕµÄ×é¼þ²ã×´½á¹¹£¬´ó´ó¼õСÁËоƬµÄÌå»ý£¬²¢Ìá¸ßÁËÊý¾ÝÔÚоƬÉϸ÷¸ö¹¦ÄÜÇøÖ®¼äµÄ´«ÊäËÙ¶È¡£ IBM°ëµ¼ÌåÑз¢ÖÐÐĸ±×ܲÃLisa Su±íʾ£º¡°ÕâÒ»Í»ÆÆÐԵĽøÕ¹ÊÇIBM¿ªÕ¹Ê®¶àÄê̽Ë÷Ñо¿µÄ³É¹û¡£ÎÒÃÇ¿ÉÒÔ½«ÈýάоƬ´ÓʵÑéÊÒ×ßÏòÖÆÔìÉú²ú»·½Ú£¬À´Ö§³Ö¸÷ÖÖ¸÷ÑùµÄÓ¦Óᣡ± ÕâÖÖIBMз½·¨ÊÇÒÀ¿¿ÐµĴ©Í¸¹èͨµÀ¼¼Êõ¶ø·Ç³¤½ðÊôµçÏßÀ´Á¬½ÓĿǰµÄ¶þάоƬ£¬Õâʵ¼ÊÉÏÊÇÔÚ¹èԲƬÉÏÊ´¿Ì³öÀ´µÄ´¹Ö±Á¬½ÓͨµÀ£¬²¢ÔÚÆäÖÐ×¢Âú½ðÊô¡£ÕâЩͨµÀ¿ÉÒÔʹ¶à¸öоƬ¶ÑµþÔÚÒ»Æð£¬Í¬Ê±Ö§³ÖоƬ֮¼ä¸ü´óÐÅÏ¢Á¿µÄ´«Êä¡£ ÕâÏÒÕ½«ÐÅÏ¢ÔÚоƬÉÏ´«ÊäµÄ¾àÀëËõ¶ÌÁË1000±¶£¬Óë¶þάоƬÏà±È¿ÉÒÔÔö¼Ó×î¶à100±¶µÄÐÅϢͨµÀ»ò·¾¶¡£ IBMÒѾÔÚ×Ô¼ºµÄÉú²úÏßÉÏÔËÐÐʹÓÃÕâÖÖ´©Í¸¹èͨµÀ¼¼ÊõµÄоƬ£¬²¢½«ÔÚ2007ÄêϰëÄ꿪ʼΪ¿Í»§ÌṩʹÓÃÕâÖÖ·½·¨ÖÆÔìµÄоƬÑù±¾£¬Í¬Ê±ÔÚ2008ÄêͶÈëÉú²ú¡£ÕâÖÖ´©Í¸¹èͨµÀ¼¼Êõ×îÔ罫±»ÓÃÓÚÎÞÏßͨÐÅоƬÁìÓò£¬ÕâЩоƬ½«±»°²×°ÔÚÎÞÏßLANºÍ·äÎÑÓ¦ÓÃËùʹÓõŦÂÊ·Å´óÆ÷Ö®ÖС£ÁíÍ⣬Èýά¼¼ÊõÒ²½«Ó¦ÓÃÓÚ¸ü¹ã·ºµÄоƬӦÓÃÁìÓò£¬°üÀ¨Ä¿Ç°ÄÇЩÔËÐÐÔÚIBM¸ßÐÔÄÜ·þÎñÆ÷ºÍ³¬¼¶¼ÆËã»úÖеÄоƬ£¬ÕâЩ·þÎñÆ÷ºÍ³¬¼¶¼ÆËã»úÖ§³Ö×ÅÈ«ÇòµÄÉÌÒµ»î¶¯¡¢Õþ¸®ºÍ¿ÆÑ§Ñо¿¹¤×÷¡£ |
5Â¥2007-04-28 17:06:23
zhaokelun1975
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New nanocomposite processing technique creates more powerful capacitors![]() 9X"M-a(n4d4x:cS|Scanning electron micrographs of barium titanate (BaTiO3) nanocomposites with polycarbonate (left, top and bottom) and Viton (right, top and bottom) polymer matrices. The images show the dramatic improvement in film uniformity through the use of phosphonic acid coated BaTiO3 nanoparticles (bottom images) as compared to uncoated nanoparticles (top images). Credit: Image courtesy of Joe PerryA new technique for creating films of barium titanate (BaTiO3) nanoparticles in a polymer matrix could allow fabrication of improved capacitors able to store twice as much energy as existing devices. The improved capacitors could be used in consumer devices such as cellular telephones ¨C and in defense applications requiring both high energy storage and rapid current discharge. Because of its high dielectric properties, barium titanate has long been of interest for use in capacitors, but until recently materials scientists had been unable to produce good dispersion of the material within a polymer matrix. By using tailored organic phosphonic acids to encapsulate and modify the surface of the nanoparticles, researchers at the Georgia Institute of Technology¡¯s Center for Organic Photonics and Electronics were able to overcome the particle dispersion problem to create uniform nanocomposites. Our team has developed nanocomposites that have a remarkable combination of high dielectric constant and high dielectric breakdown strength," said Joseph W. Perry, a professor in the Georgia Tech School of Chemistry and Biochemistry and the Center for Organic Photonics and Electronics. "For capacitors and related applications, the amount of energy you can store in a material is related to those two factors." The new nanocomposite materials have been tested at frequencies of up to one megahertz, and Perry says operation at even higher frequencies may be possible. Though the new materials could have commercial application without further improvement, their most important contribution may be in demonstrating the new encapsulation technique ¨C which could have broad applications in other nanocomposite materials. "This work opens a door to effectively exploit this type of particle in nanocomposites using the coating technology we have demonstrated," explained Perry. "There are many ways we can envision making advances beyond what we¡¯ve done already." www.nanost.net The results were reported in the April 2007 edition (Vol. 19, issue 7) of the journal Advanced Materials. The research was supported by the Office of Naval Research and the National Science Foundation. Georgia Tech has filed a patent application on the nanoparticle encapsulation technique. Because of their ability to store and rapidly discharge electrical energy, capacitors are used in a variety of consumer products such as computers and cellular telephones. And because of the increasing demands for electrical energy to power vehicles and new equipment, they also have important military applications. Key to developing thin-film capacitor materials with higher energy storage capacity is the ability to uniformly disperse nanoparticles in as high a density as possible throughout the polymer matrix. However, nanoparticles such as barium titanate tend to form aggregates that reduce the ability of the nanocomposite to resist electrical breakdown. Other research groups have tried to address the dispersal issue with a variety of surface coatings, but those coatings tended to come off during processing ¨C or to create materials compatibility issues. The Georgia Tech research team decided to address the issue by using organic phosphonic acids to encapsulate the particles. The tailored organic phosphonic acid ligands, designed and synthesized by a research group headed by Seth Marder ¨C a professor in the Georgia Tech School of Chemistry and Biochemistry ¨C provide a robust coating for the particles, which range in size from 30 to 120 nanometers in diameter. "Phosphonic acids bind very well to barium titanate and to other related metal oxides," Perry said. "The choice of that material and ligands were very effective in allowing us to take the tailored phosphonic acids, put them onto the barium titanate, and then with the correct solution processing, to incorporate them into polymer systems. This allowed us to provide good compatibility with the polymer hosts ¨C and thus very good dispersion as evidenced by a three- to four-fold decrease in the average aggregate size." gThough large crystals of barium titanate could also provide a high dielectric constant, they generally do not provide adequate resistance to breakdown ¨C and their formation and growth can be complex and require high temperatures. Composites provide the necessary electrical properties, along with the advantages of solution-based processing techniques. "One of the big benefits of using a polymer nanocomposite approach is that you combine particles of a material that provide desired properties in a matrix that has the benefits of easy processing," Perry explained. Though the new materials may already offer enough of an advantage to justify commercializing, Perry believes there are additional opportunities for boosting their performance. The research team also wants to scale up production to make larger samples ¨C now produced in two-inch by three-inch films ¨C available to other researchers who may wish to develop additional applications. Perry and Marder are working with Bernard Kippelen, a professor in the Georgia Tech School of Electrical and Computer Engineering, on the use of these new nanocomposites in organic thin-film transistors in which solution-based techniques are used to fabricate inexpensive electronic components. "Beyond capacitors, there are many areas where high dielectric materials are important, such as field-effect transistors, displays and other electronic devices," Perry added. "With our material, we can provide a high dielectric layer that can be incorporated into those types of applications." Source: Georgia Institute of Technology |
6Â¥2007-04-28 17:32:30
zhaokelun1975
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7Â¥2007-04-28 17:43:39
zhaokelun1975
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Nano Structures Can Pose Big Measurement Problems Materials scientists will tell you that to best understand, characterize and eventually utilize the properties of a specific material, you have to be able to define how the atoms within it are arranged. In the case of common crystals, there are numerous methods, such as X-ray diffraction, by which this can be done. Not so for nanostructured materials (structures with atomic arrangements at a scale of 1-100 nanometers, or between 5 to 1,000 atoms in size) where the inability to determine atomic order with high precision has been dubbed the ¡°nanostructure problem.¡± In a paper published in the April 27 Science, researchers Igor Levin at the National Institute of Standards and Technology and Simon J.L. Billinge at Michigan State University reviewed various classes of nanostructured materials, listed the array of methods currently used to study their atomic makeup and defined the problems inherent with each one. Overall, the authors state that while many methods exist for probing the atomic structure on the nanoscale, no single technique can provide a unique structural solution. The authors conclude their paper by calling for a coordinated effort by researchers to develop a coherent strategy for a comprehensive solution of the ¡°nanostructure problem¡± using inputs from multiple experimental methods and theory. Citation: S.J.L. Billinge and I. Levin. The problem with determining atomic structure at the nanoscale. Science, 316: 5823, April 27, 2007. Source: National Institute of Standards and Technology |
8Â¥2007-04-28 17:44:30
zhaokelun1975
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9Â¥2007-04-28 17:45:41
zhaokelun1975
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Optoelectronic tweezers push nanowires around In efforts that can improve studies of biological objects and the construction of nanotech materials, researchers at the University of California-Berkeley have invented "optoelectronic tweezers," a new way of controlling nanometer-scale objects. The research will be presented at the upcoming CLEO/QELS meeting in Baltimore. In the design, the researchers reflect light from a digitally controlled array of mirrors, sending the light through a magnifying lens, and then into a sandwich of semiconductor planes, creating (at the interface between two of the planes) as many as 15,000 traps that can be addressed separately. In each of the traps, objects such as biological cells can be studied Optoelectronic tweezers, which use optical energy to create powerful electric forces in carefully prescribed places, differ from ordinary optical tweezers, which use optical energy to create mechanical forces that can push things around, helping to make the technique potentially easier for laboratories to implement. According to Berkeley's Aaron Ohta, the optoelectronic approach uses much less power than optical tweezers and doesn't need to be as carefully focused. In recent months the Berkeley group has had some success in using their locally controlled electric fields to manipulate the positions of tiny nanorods (100 nanometers in diameter and 1-50 microns long). The rods are suspended in a thin layer of water by sound waves and then transferred to the tweezer apparatus. Ohta says that the lateral-field optoelectronic device will possibly be used to place rods for the sake of building 3-D circuitry or for positioning oblong-shaped cells or cell protrusions with micron-level precision. Source: Optical Society of America |
10Â¥2007-04-28 17:46:33














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