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Science Daily ¡ª Rice University chemists have discovered that tiny building blocks known as gold nanorods spontaneously assemble themselves into ring-like superstructures.
Á´½Ó£ºhttp://www.SciEI.com/news/science/Chemistry/Index.html
This finding, which will be published the chemistry journal Angewandte Chemie, could potentially lead to the development of novel nanodevices like highly sensitive optical sensors, superlenses, and even invisible objects for use in the military.

¡°Finding new ways to assemble nano-objects into superstructures is an important task because at the nanoscale, the properties of those objects depend on the arrangement of individual building blocks,¡± said principal investigator Eugene Zubarev, the Norman Hackerman-Welch Young Investigator and assistant professor of chemistry at Rice.

Although ring-like assemblies have been observed in spherical nanoparticles and other symmetrical molecules, until now such structures had not been documented with rod-shaped nanostructures.

Like many nanoscale objects, gold nanorods are several billionths of a meter, or 1,000 times smaller than a human hair. Zubarev used hybrid nanorods for this research because attached to their surface are thousands of polymer molecules, which are flexible chainlike structures. The central core of the nanorods is an inorganic crystal, but the polymers attached to the outside are organic species. The combination of the inorganic and organic features resulted in a hybrid structure that proved to be critical to the study.

Ó¢ÎÄÈ«ÎÄ£ºhttp://www.sciencedaily.com/releases/2007/03/070310145606.htm

[ Last edited by popsheng on 2007-4-28 at 18:12 ]
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Nano Structures Can Pose Big Measurement Problems
Materials scientists will tell you that to best understand, characterize and eventually utilize the properties of a specific material, you have to be able to define how the atoms within it are arranged. In the case of common crystals, there are numerous methods, such as X-ray diffraction, by which this can be done.

Not so for nanostructured materials (structures with atomic arrangements at a scale of 1-100 nanometers, or between 5 to 1,000 atoms in size) where the inability to determine atomic order with high precision has been dubbed the ¡°nanostructure problem.¡±

In a paper published in the April 27 Science, researchers Igor Levin at the National Institute of Standards and Technology and Simon J.L. Billinge at Michigan State University reviewed various classes of nanostructured materials, listed the array of methods currently used to study their atomic makeup and defined the problems inherent with each one.

Overall, the authors state that while many methods exist for probing the atomic structure on the nanoscale, no single technique can provide a unique structural solution.

The authors conclude their paper by calling for a coordinated effort by researchers to develop a coherent strategy for a comprehensive solution of the ¡°nanostructure problem¡± using inputs from multiple experimental methods and theory.

Citation: S.J.L. Billinge and I. Levin. The problem with determining atomic structure at the nanoscale. Science, 316: 5823, April 27, 2007.

Source: National Institute of Standards and Technology
8Â¥2007-04-28 17:44:30
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Aberration-Corrected Imaging of Active Sites on Industrial Catalyst
Nanoparticle

Lionel Cervera Gontard, Lan-Yun Chang, Crispin J. D. Hetherington, Angus I. Kirkland,
Dogan Ozkaya, and Rafal E. Dunin-Borkowski

Angew. Chem. Int. Ed. 2007, 46, 1 ¨C 4

http://www3.interscience.wiley.c ... /114199478/PDFSTART
2Â¥2007-03-24 14:00:24
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