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wshk1980木虫 (著名写手)
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纳米材料研究动态系列报道专栏
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希望大家多多分享好资料，了解纳米材料最新进展！！！ 如有支持者将资料发到此主题，谢谢！！！！ 希望大家多多支持！！！！ 我先抛砖引玉！！！！ 美化学家发现金纳米棒自发地将自己组装成一种环状超结构 Science Daily — Rice University chemists have discovered that tiny building blocks known as gold nanorods spontaneously assemble themselves into ring-like superstructures. 链接：http://www.SciEI.com/news/science/Chemistry/Index.html This finding, which will be published the chemistry journal Angewandte Chemie, could potentially lead to the development of novel nanodevices like highly sensitive optical sensors, superlenses, and even invisible objects for use in the military. “Finding new ways to assemble nano-objects into superstructures is an important task because at the nanoscale, the properties of those objects depend on the arrangement of individual building blocks,” said principal investigator Eugene Zubarev, the Norman Hackerman-Welch Young Investigator and assistant professor of chemistry at Rice. Although ring-like assemblies have been observed in spherical nanoparticles and other symmetrical molecules, until now such structures had not been documented with rod-shaped nanostructures. Like many nanoscale objects, gold nanorods are several billionths of a meter, or 1,000 times smaller than a human hair. Zubarev used hybrid nanorods for this research because attached to their surface are thousands of polymer molecules, which are flexible chainlike structures. The central core of the nanorods is an inorganic crystal, but the polymers attached to the outside are organic species. The combination of the inorganic and organic features resulted in a hybrid structure that proved to be critical to the study. 英文全文：http://www.sciencedaily.com/releases/2007/03/070310145606.htm [ Last edited by popsheng on 2007-4-28 at 18:12 ] |
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wshk1980
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3楼2007-03-29 16:27:40
wshk1980
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Aberration-Corrected Imaging of Active Sites on Industrial Catalyst Nanoparticle Lionel Cervera Gontard, Lan-Yun Chang, Crispin J. D. Hetherington, Angus I. Kirkland, Dogan Ozkaya, and Rafal E. Dunin-Borkowski Angew. Chem. Int. Ed. 2007, 46, 1 – 4 http://www3.interscience.wiley.c ... /114199478/PDFSTART |
2楼2007-03-24 14:00:24
zhaokelun1975
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IBM将摩尔定律推进到三维时代 赛迪网2007年4月27日讯 日前，IBM宣布在制造环境中实现了一种突破性的芯片堆叠技术，此举为制造三维芯片扫清了障碍，摩尔定律也将因此而突破原来预期的极限。这种被称为“穿透硅通道（through-silicon vias）”的技术可以大大缩小不同芯片组件之间的距离，从而设计出速度更快、体积更小和能耗更低的系统。 IBM的这项突破实现了从二维芯片设计到三维芯片堆叠的转变，将传统上并排安装在硅圆片上的芯片和内存设备以堆叠的方式相互叠加在一起，最终实现了一种紧凑的组件层状结构，大大减小了芯片的体积，并提高了数据在芯片上各个功能区之间的传输速度。 IBM半导体研发中心副总裁Lisa Su表示：“这一突破性的进展是IBM开展十多年探索研究的成果。我们可以将三维芯片从实验室走向制造生产环节，来支持各种各样的应用。” 这种IBM新方法是依靠新的穿透硅通道技术而非长金属电线来连接目前的二维芯片，这实际上是在硅圆片上蚀刻出来的垂直连接通道，并在其中注满金属。这些通道可以使多个芯片堆叠在一起，同时支持芯片之间更大信息量的传输。 这项工艺将信息在芯片上传输的距离缩短了1000倍，与二维芯片相比可以增加最多100倍的信息通道或路径。 IBM已经在自己的生产线上运行使用这种穿透硅通道技术的芯片，并将在2007年下半年开始为客户提供使用这种方法制造的芯片样本，同时在2008年投入生产。这种穿透硅通道技术最早将被用于无线通信芯片领域，这些芯片将被安装在无线LAN和蜂窝应用所使用的功率放大器之中。另外，三维技术也将应用于更广泛的芯片应用领域，包括目前那些运行在IBM高性能服务器和超级计算机中的芯片，这些服务器和超级计算机支持着全球的商业活动、政府和科学研究工作。 |
5楼2007-04-28 17:06:23
zhaokelun1975
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New nanocomposite processing technique creates more powerful capacitors 9X"M-a(n4d4x:cS|Scanning electron micrographs of barium titanate (BaTiO3) nanocomposites with polycarbonate (left, top and bottom) and Viton (right, top and bottom) polymer matrices. The images show the dramatic improvement in film uniformity through the use of phosphonic acid coated BaTiO3 nanoparticles (bottom images) as compared to uncoated nanoparticles (top images). Credit: Image courtesy of Joe PerryA new technique for creating films of barium titanate (BaTiO3) nanoparticles in a polymer matrix could allow fabrication of improved capacitors able to store twice as much energy as existing devices. The improved capacitors could be used in consumer devices such as cellular telephones – and in defense applications requiring both high energy storage and rapid current discharge. Because of its high dielectric properties, barium titanate has long been of interest for use in capacitors, but until recently materials scientists had been unable to produce good dispersion of the material within a polymer matrix. By using tailored organic phosphonic acids to encapsulate and modify the surface of the nanoparticles, researchers at the Georgia Institute of Technology’s Center for Organic Photonics and Electronics were able to overcome the particle dispersion problem to create uniform nanocomposites. Our team has developed nanocomposites that have a remarkable combination of high dielectric constant and high dielectric breakdown strength," said Joseph W. Perry, a professor in the Georgia Tech School of Chemistry and Biochemistry and the Center for Organic Photonics and Electronics. "For capacitors and related applications, the amount of energy you can store in a material is related to those two factors." The new nanocomposite materials have been tested at frequencies of up to one megahertz, and Perry says operation at even higher frequencies may be possible. Though the new materials could have commercial application without further improvement, their most important contribution may be in demonstrating the new encapsulation technique – which could have broad applications in other nanocomposite materials. "This work opens a door to effectively exploit this type of particle in nanocomposites using the coating technology we have demonstrated," explained Perry. "There are many ways we can envision making advances beyond what we’ve done already." www.nanost.net The results were reported in the April 2007 edition (Vol. 19, issue 7) of the journal Advanced Materials. The research was supported by the Office of Naval Research and the National Science Foundation. Georgia Tech has filed a patent application on the nanoparticle encapsulation technique. Because of their ability to store and rapidly discharge electrical energy, capacitors are used in a variety of consumer products such as computers and cellular telephones. And because of the increasing demands for electrical energy to power vehicles and new equipment, they also have important military applications. Key to developing thin-film capacitor materials with higher energy storage capacity is the ability to uniformly disperse nanoparticles in as high a density as possible throughout the polymer matrix. However, nanoparticles such as barium titanate tend to form aggregates that reduce the ability of the nanocomposite to resist electrical breakdown. Other research groups have tried to address the dispersal issue with a variety of surface coatings, but those coatings tended to come off during processing – or to create materials compatibility issues. The Georgia Tech research team decided to address the issue by using organic phosphonic acids to encapsulate the particles. The tailored organic phosphonic acid ligands, designed and synthesized by a research group headed by Seth Marder – a professor in the Georgia Tech School of Chemistry and Biochemistry – provide a robust coating for the particles, which range in size from 30 to 120 nanometers in diameter. "Phosphonic acids bind very well to barium titanate and to other related metal oxides," Perry said. "The choice of that material and ligands were very effective in allowing us to take the tailored phosphonic acids, put them onto the barium titanate, and then with the correct solution processing, to incorporate them into polymer systems. This allowed us to provide good compatibility with the polymer hosts – and thus very good dispersion as evidenced by a three- to four-fold decrease in the average aggregate size." gThough large crystals of barium titanate could also provide a high dielectric constant, they generally do not provide adequate resistance to breakdown – and their formation and growth can be complex and require high temperatures. Composites provide the necessary electrical properties, along with the advantages of solution-based processing techniques. "One of the big benefits of using a polymer nanocomposite approach is that you combine particles of a material that provide desired properties in a matrix that has the benefits of easy processing," Perry explained. Though the new materials may already offer enough of an advantage to justify commercializing, Perry believes there are additional opportunities for boosting their performance. The research team also wants to scale up production to make larger samples – now produced in two-inch by three-inch films – available to other researchers who may wish to develop additional applications. Perry and Marder are working with Bernard Kippelen, a professor in the Georgia Tech School of Electrical and Computer Engineering, on the use of these new nanocomposites in organic thin-film transistors in which solution-based techniques are used to fabricate inexpensive electronic components. "Beyond capacitors, there are many areas where high dielectric materials are important, such as field-effect transistors, displays and other electronic devices," Perry added. "With our material, we can provide a high dielectric layer that can be incorporated into those types of applications." Source: Georgia Institute of Technology |
6楼2007-04-28 17:32:30
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