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Science Daily ¡ª Rice University chemists have discovered that tiny building blocks known as gold nanorods spontaneously assemble themselves into ring-like superstructures.
Á´½Ó£ºhttp://www.SciEI.com/news/science/Chemistry/Index.html
This finding, which will be published the chemistry journal Angewandte Chemie, could potentially lead to the development of novel nanodevices like highly sensitive optical sensors, superlenses, and even invisible objects for use in the military.

¡°Finding new ways to assemble nano-objects into superstructures is an important task because at the nanoscale, the properties of those objects depend on the arrangement of individual building blocks,¡± said principal investigator Eugene Zubarev, the Norman Hackerman-Welch Young Investigator and assistant professor of chemistry at Rice.

Although ring-like assemblies have been observed in spherical nanoparticles and other symmetrical molecules, until now such structures had not been documented with rod-shaped nanostructures.

Like many nanoscale objects, gold nanorods are several billionths of a meter, or 1,000 times smaller than a human hair. Zubarev used hybrid nanorods for this research because attached to their surface are thousands of polymer molecules, which are flexible chainlike structures. The central core of the nanorods is an inorganic crystal, but the polymers attached to the outside are organic species. The combination of the inorganic and organic features resulted in a hybrid structure that proved to be critical to the study.

Ó¢ÎÄÈ«ÎÄ£ºhttp://www.sciencedaily.com/releases/2007/03/070310145606.htm

[ Last edited by popsheng on 2007-4-28 at 18:12 ]
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zhaokelun1975

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Scientists Hand-Make Devices Smaller than 10 Nanometers
by Laura Mgrdichian

Two intersecting nanowires (left panel) were made into a four-terminal nanogap transistor (right panel) using the TEBAL method.A research team from the University of Pennsylvania has used an electron beam to hand-carve ultra-small metal structures and devices, all with dimensions below 10 nanometers, from very thin metal sheets. Their technique could impact the development of many nanotechnologies, including nanoelectronics.

Among the structures created by the two scientists, professor Marija Drndić and graduate student Michael Fischbein, the paper's lead author, are nanodisks, nanorings, nanowires, nanoholes, and multi-terminal nano-transistors.

¡°Many different approaches have been undertaken to fabricate the small structures needed to probe the phenomena that take place at the nanoscale, but the most widely used and versatile techniques are limited to tens of nanometers,¡± Drndić said to PhysOrg.com. ¡°Reliably and consistently fabricating devices at the sub-10-nanometer scale from the top down is generally still challenging, but our technique offers a route to this regime.¡±
¡°It¡¯s like using a magnifying glass and sun rays to sculpt an ice cube,¡± says Fischbein. ¡°However, using an electron beam instead of sun rays allows for precision on the atomic scale.¡±

Among its advantages over other techniques, Drndić and Fischbein say, is the fact that theirs uses the imaging beam of a transmission electron microscope, which means the structures can be imaged with atomic resolution and inspected in real time as they are created. These characteristics result in structures with smooth surfaces (atomically speaking) and high reproducibility ¨C creating nearly identical copies of the same structure.

Additionally, the technique (referred to as TEBAL, for transmission electron beam ablation lithography) allows the contacts between a nanostructure and its leads to be resistance-free, and thus more efficient. Structures made from bottom-up techniques, i.e., assembled from smaller components, typically first need to be placed on a chip and then connected to larger circuitry. TEBAL avoids these steps.

All of the structures created using TEBAL were done so by hand, with a human user guiding the electron beam and watching each structure take shape. ¡°Computer control should offer an even higher degree of precision than we've demonstrated and produce highly intricate patterns over a wide area,¡± said Fischbein.

TEBAL has many potential applications in nanoscience because it has the ability to produce a wide variety of nanostructures. Running a current through TEBAL-created nanowires could allow them to be used as nanomagnets. Or, the wires could be used to test the effects of wire shape and size on their conductivity, using both regular and superconducting wires. The tiny transistors Drndić and Fischbein created have many uses in molecular electronics. Nanogap-nanohole devices can be used in the manufacture of single-molecule detectors and provide new opportunities for DNA nanopore sequencing.

This research is described in detail in the April 17, 2007, online edition of Nano Letters.

Citation: Michael D. Fischbein and Marija Drndić, ¡°Sub-10 nm Device Fabrication in a Transmission Electron Microscope.¡± Nano Lett. ASAP Article, DOI: 10.1021/nl0703626

Copyright 2007 PhysOrg.com.
7Â¥2007-04-28 17:43:39
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Aberration-Corrected Imaging of Active Sites on Industrial Catalyst
Nanoparticle

Lionel Cervera Gontard, Lan-Yun Chang, Crispin J. D. Hetherington, Angus I. Kirkland,
Dogan Ozkaya, and Rafal E. Dunin-Borkowski

Angew. Chem. Int. Ed. 2007, 46, 1 ¨C 4

http://www3.interscience.wiley.c ... /114199478/PDFSTART
2Â¥2007-03-24 14:00:24
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