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Science Daily ¡ª Rice University chemists have discovered that tiny building blocks known as gold nanorods spontaneously assemble themselves into ring-like superstructures.
Á´½Ó£ºhttp://www.SciEI.com/news/science/Chemistry/Index.html
This finding, which will be published the chemistry journal Angewandte Chemie, could potentially lead to the development of novel nanodevices like highly sensitive optical sensors, superlenses, and even invisible objects for use in the military.

¡°Finding new ways to assemble nano-objects into superstructures is an important task because at the nanoscale, the properties of those objects depend on the arrangement of individual building blocks,¡± said principal investigator Eugene Zubarev, the Norman Hackerman-Welch Young Investigator and assistant professor of chemistry at Rice.

Although ring-like assemblies have been observed in spherical nanoparticles and other symmetrical molecules, until now such structures had not been documented with rod-shaped nanostructures.

Like many nanoscale objects, gold nanorods are several billionths of a meter, or 1,000 times smaller than a human hair. Zubarev used hybrid nanorods for this research because attached to their surface are thousands of polymer molecules, which are flexible chainlike structures. The central core of the nanorods is an inorganic crystal, but the polymers attached to the outside are organic species. The combination of the inorganic and organic features resulted in a hybrid structure that proved to be critical to the study.

Ó¢ÎÄÈ«ÎÄ£ºhttp://www.sciencedaily.com/releases/2007/03/070310145606.htm

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Placing single nanowires: NIST makes the connection

Schematic of NIST single nanowire manipulation system. Credit: NISTResearchers at the National Institute of Standards and Technology have devised a system for manipulating and precisely positioning individual nanowires on semiconductor wafers. Their technique, described in a recent paper, allows them to fabricate sophisticated test structures to explore the properties of nanowires, using only optical microscopy and conventional photolithographic processing in lieu of advanced (and expensive) tools such as focused ion or electron beams.

Nanowires and nanotubes are being studied intensively as essential elements for future nanoscale electronics, but some fundamentals remain to be worked out¡ªamong them, how to put wires only a handful of atoms in diameter where you want them. The smallest-diameter nanowires today are built in a ¡°bottom-up¡± fashion, assembled atom-by-atom through a chemical growth process such as chemical vapor deposition.

Scanning electron microscope image shows a single silicon nanowire positioned in an etched trench using NIST's nanowire manipulation technique. The trench helps keep the nanowire in position during the fabrication of the rest of the test structure, which measures metal/nanowire contact resistance. The scale bar is 20 micrometers long. Credit: NISTThis is essentially a bulk process; it produces haystacks of jumbled nanowires of varying lengths and diameters. ¡°The normal research approach,¡± explains NIST electronics engineer Curt Richter, ¡°is to throw a whole bunch of these down on the test surface, hunt around with a microscope until you find a good-looking wire in about the right place, and use lithography to attach electrical contacts to it.¡±
To achieve better control, the NIST engineers modified a standard probe station used to test individual components in microelectronic circuits. The station includes a high-resolution optical microscope and a system for precisely positioning work surfaces under a pair of customized titanium probes with tips less than 100 nanometers in diameter.

In a two-step process, silicon nanowires suspended in a drop of water are deposited on a special staging wafer patterned with a grid of tiny posts, and dried. Resting on the tops of the posts, selected nanowires can be picked up by the two probe tips, which they cling to by static electricity. The test structure wafer is positioned under the probes, the nanowire is oriented by moving either the probe tips or the wafer, and then placed on the wafer in the desired position.

Although not at all suited to mass production, the technique¡¯s fine level of control allows NIST engineers to place single nanowires wherever they want to create elaborate structures for testing nanowire properties. They¡¯ve demonstrated this by building a multiple-electrical-contact test structure for measuring the resistance of a nanowire independent of contact resistance, and a simple electromechanical ¡°switch¡± suitable for measuring the flexibility of nanowires. They¡¯ve used the technique successfully with nanowires greater than about 60 nm in diameter, and say sharper probe tips and high-resolution microscopes could push the limit lower.

Citation: Q. Li, S. Koo, C.A. Richter, M.D. Edelstein, J.E. Bonevich, J.J. Kopanski, J.S. Suehle and E.M. Vogel. Precise alignment of single nanowires and fabrication of nanoelectromechanical switch and other test structures. IEEE Transactions on Nanotechnology. V.6, No.2. March 2007.

Source: National Institute of Standards and Technology
9Â¥2007-04-28 17:45:41
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Aberration-Corrected Imaging of Active Sites on Industrial Catalyst
Nanoparticle

Lionel Cervera Gontard, Lan-Yun Chang, Crispin J. D. Hetherington, Angus I. Kirkland,
Dogan Ozkaya, and Rafal E. Dunin-Borkowski

Angew. Chem. Int. Ed. 2007, 46, 1 ¨C 4

http://www3.interscience.wiley.c ... /114199478/PDFSTART
2Â¥2007-03-24 14:00:24
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