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chpplg

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leonumn

铁杆木虫 (著名写手)

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chpplg(金币+6,VIP+0): 4-22 13:58
我有, 给金币才给
2楼2009-04-19 09:23:15
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a9998382

木虫 (正式写手)

可以把邮箱告诉他,一手交货,一手交钱
3楼2009-04-19 09:29:00
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leonumn

铁杆木虫 (著名写手)

2005
Magnetomicelles:Composite
Vol.5,No.10
1987-1991
NanostructuresfromMagnetic
NanoparticlesandCross-Linked
AmphiphilicBlockCopolymers
? ? ? ,?
Byeong-SuKim,
Jiao-MingQiu, Jian-PingWang, andT.AndrewTaton*
DepartmentofChemistryandDepartmentofElectricalandComputerEngineering,
UniVersityofMinnesota,207PleasantStreetSE,Minneapolis,Minnesota55455
ReceivedJuly19,2005;RevisedManuscriptReceivedAugust30,2005
ABSTRACT
Wereportthesynthesis,characterization,andcovalentsurfacechemistryof!àmagnetomicelles!–,cross-linked,amphiphilicblock-copolym
micellesthatencapsulatesuperparamagneticironoxidenanoparticles.Becausethesecompositenanostructuresassemblespontaneously
fromsolutionbysimultaneousdesolvationofnanoparticleandamphiphilicpoly(styrene
-block-acrylicacid )components,explicitsurface
250 13
functionalizationoftheparticlesisnotrequired,andtheencapsulationmethodwasappliedtodifferentmagneticnanoparticlesizesand
compositions.TEMimagesofthemagnetomicellesillustratedthatthenumberofencapsulatedparticlescouldbedictatedrationallybysynthetic
conditions.ThemagneticpropertiesoftheparticleswerecharacterizedbySQUIDmagnetometryandfollowedthegeneralLangevinmagnetic
modelforsuperparamagneticmaterials.Themicellarshellsoftheseparticleswerefunctionalizedusingcovalentchemistrythatwouldnot
ordinarilybepossibleonthemagneticparticlesurface.Asaresult,thisnoncovalentapproachprovidesanewroutetotechnologicalapplications
ofhydrophobicmagneticnanomaterialsthatlackappropriateconjugatesurfacechemistry.
4楼2009-04-23 08:14:16
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leonumn

铁杆木虫 (著名写手)

2005
Magnetomicelles:Composite
Vol.5,No.10
1987-1991
NanostructuresfromMagnetic
NanoparticlesandCross-Linked
AmphiphilicBlockCopolymers
? ? ? ,?
Byeong-SuKim,
Jiao-MingQiu, Jian-PingWang, andT.AndrewTaton*
DepartmentofChemistryandDepartmentofElectricalandComputerEngineering,
UniVersityofMinnesota,207PleasantStreetSE,Minneapolis,Minnesota55455
ReceivedJuly19,2005;RevisedManuscriptReceivedAugust30,2005
ABSTRACT
Wereportthesynthesis,characterization,andcovalentsurfacechemistryof!àmagnetomicelles!–,cross-linked,amphiphilicblock-copolym
micellesthatencapsulatesuperparamagneticironoxidenanoparticles.Becausethesecompositenanostructuresassemblespontaneously
fromsolutionbysimultaneousdesolvationofnanoparticleandamphiphilicpoly(styrene
-block-acrylicacid )components,explicitsurface
250 13
functionalizationoftheparticlesisnotrequired,andtheencapsulationmethodwasappliedtodifferentmagneticnanoparticlesizesand
compositions.TEMimagesofthemagnetomicellesillustratedthatthenumberofencapsulatedparticlescouldbedictatedrationallybysynthetic
conditions.ThemagneticpropertiesoftheparticleswerecharacterizedbySQUIDmagnetometryandfollowedthegeneralLangevinmagnetic
modelforsuperparamagneticmaterials.Themicellarshellsoftheseparticleswerefunctionalizedusingcovalentchemistrythatwouldnot
ordinarilybepossibleonthemagneticparticlesurface.Asaresult,thisnoncovalentapproachprovidesanewroutetotechnologicalapplications
ofhydrophobicmagneticnanomaterialsthatlackappropriateconjugatesurfacechemistry.
5楼2009-04-23 08:14:37
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leonumn

铁杆木虫 (著名写手)

183BioconjugateChem.2007, 18,183?189
EncapsulatedMagneticNanoparticlesasSupportsforProteinsandRecyclable
Biocatalysts
AimeeR.Herdt,Byeong-SuKim,andT.AndrewTaton*
UniversityofMinnesota,DepartmentofChemistry,207PleasantStreetSE,Minneapolis,Minnesota55455.
ReceivedJuly14,2006;RevisedManuscriptReceivedNovember13,2006
Thispaperdescribesthebioconjugationofhistidine-taggedenzymesandotherproteinstothesurfaceofcomposite
!àmagnetomicelles!–consistingofmagnet-Fe
O nanoparticlesencapsulatedwithincross-linkedpolystyrene-
2 3
block-polyacrylatecopolymermicelleshells.Freecarboxylicacidgroupsonthemagnetomicellesurfacewere
2+
convertedtoCu
-iminodiaceticacid(IDA)forproteincapture.TheconjugationofT4DNAligaseandenhanced
greenfluorescentproteintomagnetomicellesrevealedthatproteinswerecapturedwithahighsurfacedensity
andcouldbemagneticallyseparatedfromreactionmixturesandsubsequentlyreleasedfromthenanoparticle
surface.Additionally,bioconjugationofT7RNApolymeraseyieldedafunctionalenzymethatmaintainedits
biologicalactivityandcouldberecycledforuptothreesubsequenttranscriptionreactions.Weproposethat
protein-magnetomicellebioconjugatesareeffectiveforproteinbioseparationandenzymaticrecyclingandfurther
strengthentheideathatnanoparticlesurfaceshaveutilityinproteinimmobilization.
6楼2009-04-23 08:15:22
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