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最近在阅读关于PEMFC中metal-free催化剂相关的文献，其中有这样一句话： Terakura et al.59 noted that only N-derived, free, lone-pair electrondoped Stone–Wales defect sites appeared to provide for reasonable active sites, so that future studies have concentrated on optimizing the geometry within this precise region. 其中Stone–Wales (SW) defect 具体是什么意思，网上搜不到相关解释，求牛人解答！ |
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Stone–Wales (SW)缺陷是一种晶体缺陷，所涉及的2个π键的碳原子的连接性发生变化，从而导致它们的键相对于其中点旋转90°。 A Stone–Wales defect is a crystallographic defect that involves the change of connectivity of two π-bonded carbon atoms, leading to their rotation by 90° with respect to the midpoint of their bond。 https://en.wikipedia.org/wiki/Stone%E2%80%93Wales_defect |
2楼2015-10-21 04:31:56
3楼2015-10-21 11:31:23