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2 The reaction of [(¦Ì-dmedt){Fe(CO)3}2] 298 mg (0.74 mmol) [6] with Me3NO 58 mg(0.76 mmol) in 5 mL CH3CN under the ice bath condition in the atmosphere of N2 for 30 min, the color turned into black from red.
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3 The new ligand motif that a pyridine ligand to give related water-soluble hydrogenases complexes for further functional studies  with an emphasis on chemistry relevant to sustainable energy cycles.
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°®ÓëÓêÏÂ: ½ð±Ò+1 2015-07-06 22:27:22
zx21619: ½ð±Ò+5, ·­ÒëEPI+1 2015-07-12 00:42:30
1  But the synthesis of diiron complexes of type [(¦Ìpdt)Fe2(CO)5(L)] (L = ligand, pdt = propyldithiolate) with loosely bound ligands is inherently unstable¡£
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zx21619: ½ð±Ò+5 2015-07-12 00:42:35
2 The reaction of [(¦Ì-dmedt){Fe(CO)3}2] 298 mg (0.74 mmol) [6] with Me3NO 58 mg(0.76 mmol) in 5 mL CH3CN was carried out on ice in the atmosphere of N2 for 30 min, or until the color turned into black from red.
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zx21619: ½ð±Ò+10 2015-07-12 00:42:39
3 The new ligand motif that a pyridine ligand to give related water-soluble hydrogenases complexes for further functional studies  with an emphasis on chemistry relevant to sustainable energy cycles.
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