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1 But synthetic diiron complexes of type [(¦Ìpdt)Fe2(CO)5(L)] (L = ligand, pdt = propyldithiolate) with loosely bound ligands are inherently unstable¡£ Õâ¸öÊDz»ÊÇûÓÐÖ÷νÓïʲôµÄ£¬Ó¢ÓïС°×дÎÄÕÂÊÇÔÚÊÇÀ§ÄѰ¡ ![]() 2 The reaction of [(¦Ì-dmedt){Fe(CO)3}2] 298 mg (0.74 mmol) [6] with Me3NO 58 mg(0.76 mmol) in 5 mL CH3CN under the ice bath condition in the atmosphere of N2 for 30 min, the color turned into black from red. ÕâÖÖÓïÐò¿ÉÒÔÂð 3 The new ligand motif that a pyridine ligand to give related water-soluble hydrogenases complexes for further functional studies with an emphasis on chemistry relevant to sustainable energy cycles. лл´óÉñÁË |
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ÖÁ×ðľ³æ (ÖªÃû×÷¼Ò)
Translator and Proofreader
- ·ÒëEPI: 1690
- Ó¦Öú: 452 (˶ʿ)
- ½ð±Ò: 31580.9
- ºì»¨: 100
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- ÔÚÏß: 19966.6Сʱ
- ³æºÅ: 3328089
- ×¢²á: 2014-07-17
- רҵ: Ö×Áö·¢Éú
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°®ÓëÓêÏÂ: ½ð±Ò+1 2015-07-06 22:27:22
zx21619: ½ð±Ò+5, ·ÒëEPI+1 2015-07-12 00:42:30
°®ÓëÓêÏÂ: ½ð±Ò+1 2015-07-06 22:27:22
zx21619: ½ð±Ò+5, ·ÒëEPI+1 2015-07-12 00:42:30
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1 But the synthesis of diiron complexes of type [(¦Ìpdt)Fe2(CO)5(L)] (L = ligand, pdt = propyldithiolate) with loosely bound ligands is inherently unstable¡£ Èç¹û²»ÊÇ˵µÄºÏ³ÉÎÊÌ⣬¶øÊÇ˵ºÏ³ÉµÄdiiron...,Ôò£º 1 But the synthesized diiron complexes of type [(¦Ìpdt)Fe2(CO)5(L)] (L = ligand, pdt = propyldithiolate) with loosely bound ligands are inherently unstable¡£ Èç¹û¾ÍÊǼòµ¥ÐðÊöÕâ¸öÊÂʵ£ººÏ³É...£¬ÔòÄãµÄԾ䲢ÎÞÎÊÌâ¡£ ¾ßÌåÐèÒª¿´ÄãµÄÄ¿µÄ¡£ |
2Â¥2015-07-06 10:19:57
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ÖÁ×ðľ³æ (ÖªÃû×÷¼Ò)
Translator and Proofreader
- ·ÒëEPI: 1690
- Ó¦Öú: 452 (˶ʿ)
- ½ð±Ò: 31580.9
- ºì»¨: 100
- Ìû×Ó: 7681
- ÔÚÏß: 19966.6Сʱ
- ³æºÅ: 3328089
- ×¢²á: 2014-07-17
- רҵ: Ö×Áö·¢Éú
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zx21619: ½ð±Ò+5 2015-07-12 00:42:35
zx21619: ½ð±Ò+5 2015-07-12 00:42:35
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2 The reaction of [(¦Ì-dmedt){Fe(CO)3}2] 298 mg (0.74 mmol) [6] with Me3NO 58 mg(0.76 mmol) in 5 mL CH3CN was carried out on ice in the atmosphere of N2 for 30 min, or until the color turned into black from red. Ç°ÃæÕâ¾ä»°²»ÍêÕû£¬ÉÙνÓﲿ·Ö£»ÁíÍ⣬under the ice bath condition˵·¨ÉúÓ²£¬¼òµ¥Ëµon ice¾ÍºÃÁË¡£ºó°ë¾äÎÒ²ÂÏëÊDZíʾ·´Ó¦½áÊøºóµÄÒ»ÖÖ±íÏÖ£¬ËùÒÔ¸øÄã¸ÄдÁËһϣ¬Ö÷ÒªÊDZãÓÚǰºóÁ½¾ä»°¼äµÄÓлúÁªÂ磬²»ºÏÊÊÇë×ÔÐиÄÕý¡£ |
3Â¥2015-07-06 10:29:37
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ÖÁ×ðľ³æ (ÖªÃû×÷¼Ò)
Translator and Proofreader
- ·ÒëEPI: 1690
- Ó¦Öú: 452 (˶ʿ)
- ½ð±Ò: 31580.9
- ºì»¨: 100
- Ìû×Ó: 7681
- ÔÚÏß: 19966.6Сʱ
- ³æºÅ: 3328089
- ×¢²á: 2014-07-17
- רҵ: Ö×Áö·¢Éú
¡¾´ð°¸¡¿Ó¦Öú»ØÌû
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zx21619: ½ð±Ò+10 2015-07-12 00:42:39
zx21619: ½ð±Ò+10 2015-07-12 00:42:39
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3 The new ligand motif that a pyridine ligand to give related water-soluble hydrogenases complexes for further functional studies with an emphasis on chemistry relevant to sustainable energy cycles. Õâ¾ä»°ÈÔÈ»²»ÍêÕû£¬È±ÉÙλÓÚ²¿·Ö¡£ thatÖ®ºóµÄÐðÊö»ìÂÒ£¬¿´²»³öÆäÖеÄÂß¼¹ØÏµ£¬ËùÒÔ²»ºÃÐ޸ġ£ |
4Â¥2015-07-06 10:35:35















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