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swition

新虫 (小有名气)

[求助] 关于锂硫电池的电极电势变化分析 已有1人参与

想问一下,Angew. Chem. Int. Ed. 2013, 52, 2 – 18,Lithium–Sulfur Batteries: Electrochemistry, Materials, and Prospects
这篇文章里面有句话,

Upon discharging, S reacts with Li by a two-electron reduction
process to form polysulfide intermediates (Li 2 S x , x = 2–8), and
to generate Li sulfide (Li 2 S) at the end of discharge. This
process is accompanied by an increase in cathode electro-
chemical potential (Figure 1b) until the battery reaches the
terminal voltage (F, normally  1.5 V). The reverse reaction
occurs when an external electric field with a certain potential
difference is applied, leading to the decomposition of Li 2 S
back to Li and S. During this time, the cathode electro-
chemical potential gradually decreases till the battery voltage
returns to F oc (Figure 1c).

这句话里,S嵌锂的过程,为什么是电极电位升高?这样的话根据能斯特方程好像解释不通啊,对于整个电池电压也不一致啊,怎么理解,

这篇综述是大牛写的。。。。

关于锂硫电池的电极电势变化分析
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swition

新虫 (小有名气)

引用回帖:
2楼: Originally posted by 卡卡贝卡 at 2014-10-17 15:29:12
这是不是从电池内部的电极电势考虑的。

不知道呢,从内部怎么考虑?能解释以下吗,想不通
3楼2014-10-19 23:30:42
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卡卡贝卡

木虫 (著名写手)

【答案】应助回帖

感谢参与,应助指数 +1
这是不是从电池内部的电极电势考虑的。
人生在世,多有不适
2楼2014-10-17 15:29:12
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