|
|
[ÇóÖú]
MOFs-ÍØÆË·ÖÎö
¸÷λ´óÏÀÄãÃǺã¡×î½ü·¢ÁËһƪÎÄÕ£¬ÔÚÎÄÕÂÖÐÌáµ½ÁËÓë½á¹¹Ïà¹ØµÄÍØÆËÃèÊö¡£Éó¸åÒâ¼û»ØÀ´ÒÔºó£¬ÓÐλÉó¸åÈ˶ÔÎÒÔÚÍØÆË½á¹¹µÄÃèÊöÌá³öÁËÖÊÒÉ¡£¶Ô´Ë£¬ÎÒÒѾÀ§»óºÜ¾ÃÁË£¬°Ù˼²»µÃÆä½â¡£×Ô¼ºÈÏΪ¶ÔÆäÃèÊöÊǶԵģ¬¿ÉÊÇÉó¸åÈ˲»ÕâôÈÏΪ£¬²»ÖªÈçºÎ»Ø´ðºÍ¸ÄÕý¡£ÇëÇóËïÀÏʦ¿É·ñ°ïÎÒ½â¾öÒ»ÏÂÕâÑùÒ»¸ö¼èÄѵÄÎÊÌâ¡£¿É·ñ°ïÎÒ¿´¿´µ½µ×ÊÇÎÒ¶ÔÆä±í´ïÓÐÎÊÌ⻹ÊÇÉó¸åÈ˵ÄÎÊÌâ²»¶ÔÄØ£¿Ôڴ˷dz£¸ÐлÄú£¡£¡£¡Í¼ÒÔ¸½¼þµÄÐÎʽ·¢¸øÄú£¬±íÊöÈçÏ£º
From the topological perspective, If the [Zn2C2O4] can be regarded as a 4-connected node and the L4− anion ligand as 4-connected node, the complicated architecture of 1 is simplified to a (4,4)-connected 3D PtS topological network with the point (Schläfli) symbol of {42.84} as shown in Figure 3. There is two different T sites and two unique tiles [84] + [42.82] in the PtS network (Figure 4).
Éó¸åÈËÎÊÌ⣺
Reviewer #3:
Question 1: The topology of this MOF is PtS and there is two different T sites and two unique tiles [84] + [42.82] in the PtS network. This description is not right. As we know, there two 4-connected node in the PtS topology, one is the plane coordination, other one is tetrahedral coordination. While, the point symble of both node are {4^2, 8^4}. So please re-check the topology of the compound carefully.![MOFs-ÍØÆË·ÖÎö]()
Topology Picture.jpg |
» ±¾Ìû¸½¼þ×ÊÔ´Áбí
-
»¶Ó¼à¶½ºÍ·´À¡£ºÐ¡Ä¾³æ½öÌṩ½»Á÷ƽ̨£¬²»¶Ô¸ÃÄÚÈݸºÔð¡£
±¾ÄÚÈÝÓÉÓû§×ÔÖ÷·¢²¼£¬Èç¹ûÆäÄÚÈÝÉæ¼°µ½ÖªÊ¶²úȨÎÊÌ⣬ÆäÔðÈÎÔÚÓÚÓû§±¾ÈË£¬Èç¶Ô°æÈ¨ÓÐÒìÒ飬ÇëÁªÏµÓÊÏ䣺xiaomuchong@tal.com
- ¸½¼þ 1 : Topology_Picture.jpg
2014-08-08 12:06:05, 276.29 K
» ²ÂÄãϲ»¶
|