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小木虫论坛-学术科研互动平台 » 化学化工区 » 电化学 » 电化基础 » 阻抗谱如何解释传输现象主要发生在表面？
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dengweia

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[求助] 阻抗谱如何解释传输现象主要发生在表面？

最近投ML，审稿等了一个多月，审稿人扯了半天就提了一个问题：
审稿意见原文：
Reviewer #1: I can enhance that the performance of the described supercapacitor is so efficient, according to that we can see in the graph 3b, that is; the times for charge and discharge of the device for different current densities and also it is observed the same behavior for any of the densities. That indicates that the material keeps the same level of charge even for fast charge; that is, for high current densities (10 A/g). The figure 3c corroborates this because it is observed how the specific capacitance (capacitance/unitary volumen) decreases slightly as the current density increases); that is; the material keeps the extent of the charge in a constant way nevertheless of the charge/discharge process to which the capacitor is subjected. Finally in figure 3d it is observed how the capacitance does not change (which is defined as the storage of voltage in an electric field in the device). In addition, the capacitnace is increased as the charge discharge cycles of the supecpacitor are increased and the storaged potential is kept constant. We can conlude from the aforemenionedthat that the material is not affected in a considerable way by electric phenomemna: at least during the tests to which the device is subjected. That could be posible only if the transport phenomena on the material are superficial and not volumetric. To confirm that it is necessary to make additonal tests of electrical conductivity.

里面好多错别单词，图3c明明是比重量电容，最后让我用电导性测试证明传输现象是发生在表面的。

我做的是超电容，赝电容原理上就是电极表面附近发生的快速氧化还原反应的，还要我去证明？其实就是想让我测一下阻抗吧！感觉是提不出意见找意见的。
阻抗谱，不怎么懂，求高手指导一下，如何用阻抗谱解释传输现象主要在表面发生，非常感谢！
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