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dk8060

银虫 (小有名气)

[求助] 单晶投稿---解析----求指教!!!已有1人参与

紧急求助,编辑后面这几个问题到底是什么意思(投单晶文章,编辑回了一些问题,下面是不懂得问题,我该怎样修改)?请高手指点啊!急死了:
5) Abstract:  As mentioned in review 1, please give the graph-set notation for the main hydrogen-bonding ring motif.

6) Comment:  The hydrogen bonding description is still inadequate.  I assume that by "O1...N2", you actually mean "N2...H2a...O1".  Please include Etter's graph-set notation.

7) Refinement:  H atom description is still not sufficient.  Riding H atoms have no SU on the distance(这里不懂)。.  The N-H and O-H hydrogens are not even mentioned. 这是,该问题的原文: H atoms were placed in calculated positions withC---H = 0.97(1), 0.96 and 0.93(1) \%A for methylene, methyl and
aryl H-atoms. All H atoms included in the final cycles of refinement using a riding model, with <i>U</i>~iso~(H) =  1.5<i>U</i>~eq~ (sp3) or
1.2<i>U</i>~eq~ of the carrier atoms.
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jackdeng

专家顾问 (著名写手)

【答案】应助回帖

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感谢参与,应助指数 +1
dk8060: 金币+60, ★★★★★最佳答案, 非常感谢你的帮助。谢谢! 2014-03-27 09:47:45
我对你的问题逐条回复,但仅供参考
5) Abstract:  As mentioned in review 1, please give the graph-set notation for the main hydrogen-bonding ring motif.
这个问题是说你应该对你化合物中出现的氢键环给出类似于R^n^~m~(A)的表示方法,其中n为氢键受体数,上标,m为氢键给体数,下标,A为氢键环数。
6) Comment:  The hydrogen bonding description is still inadequate.  I assume that by "O1...N2", you actually mean "N2...H2a...O1".  Please include Etter's graph-set notation.
这个问题跟上一个类似,说你对氢键的描述不够充分,说白了,就是描述的不够深入,加一些有关氢键环表示的描述(同上)就行了。
7) Refinement:  H atom description is still not sufficient.  Riding H atoms have no SU on the distance(这里不懂)。.  The N-H and O-H hydrogens are not even mentioned. 这是,该问题的原文: H atoms were placed in calculated positions withC---H = 0.97(1), 0.96 and 0.93(1) \%A for methylene, methyl and
aryl H-atoms. All H atoms included in the final cycles of refinement using a riding model, with <i>U</i>~iso~(H) =  1.5<i>U</i>~eq~ (sp3) or
1.2<i>U</i>~eq~ of the carrier atoms.
这个问题你真不应该犯这样的错误,通常情况下,理论加的氢是不应该出现不确定度的,也就是说,0.97和0.93后不应该跟括号,而你文中又没有给出N和O上的氢是用什么方法加的,所以审稿人才会提这样的问题。因此,你需要在修改稿中加入N和O上的加氢方式。
基本就是这样了,祝你好运!
2楼2014-03-26 21:43:54
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