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[交流] 两篇文献合成MOF-235方法不一样？

文献1：
For synthesis of MOF-235 at first, 0.2 g of terephthalic acid and 0.205 g of FeCl3·6H2O were dissolved in 60 mL of N,N-dimethylformamide (DMF) and then 2 mL of the reaction solution and 2 mL of ethanol transferred into a Teflon-lined autoclave and heated at 358 K for 24 h. The orange crystals were washed with DMF/ethanol mixture and dried.
参考文献：Sorption of methane, hydrogen and carbon dioxide on metal-organic framework, iron terephthalate (MOF-235) ;Journal of Industrial and Engineering Chemistry 18 (2012) 1149–1152

文献2：
An exact amount of terephthalic acid (0.205 g, 1.23 mmol; Sigma–Aldrich, 98%) was mixed with 60 mL of DMF (DC Chem., 99%). Then the mixture was stirred
for 10 min till a clear solution was formed. After that FeCl3·6H2O (0.200 g, 0.738 mmol; Duksan, 99.7%) was added into the solution and stirred for 5 min. The reactant mixture of 30 mL and 30 mL of ethanol (DC Chem., 96%) were loaded into a Teflon-lined autoclave, sealed and placed in a preheated electric oven (80C) for 1 day. Orange powder of MOF-235 was collected by centrifugation and was washed with a DMF/ethanol mixture at least three times. Then the product was dried overnight at 150 ◦C to remove DMF and then stored in a glass vial.
参考文献：Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235)；Journal of Hazardous Materials185 (2011) 507–511

区别：
对苯二甲酸的用量不一样，一个是0.2g；另一个是0.205g。
FeCl3·6H2O 也不一样，一个是0.205g；另一个是0.2g。
加入顺序不一样，一个是先后顺序加入；另一个是混合全部加入。
最后烘干方式不一样，一个是自然烘干；另一个是加热烘干。

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