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1986zd

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[求助] 关于电化学方面的审稿意见求助!急!

本人是做纳米材料包覆缓蚀剂并掺杂进涂料改进金属防腐性的。刚投了一篇论文在surface and coatings technology上,给了大修,下面是审稿人的部分意见,关于电化学方面的,我不是很明白,望大侠指点!

  (1) The EIS plots do not contain results from the low frequency range where the corrosion process exists. It can be seen from the remarks on the Nyquist plots that EIS values have been obtained until 10Hz. So, the demonstrated equivalent circuit for the coating of copper is not representative. Furthermore, a table included all the date obtained from the EIS fitting parameters should have been added.

  (2) I am not sure on the correctness of the inhibition efficiency results based on figure 17 as the coating applied on the copper substrate is organic resulting in reduced exposed area of the copper substrate to the corrosive environment through the coating pores. So the used exposed substrate area is unknown and cannot be used for the determination of the current density and then the determination of Icorr.
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