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北京石油化工学院2026年研究生招生接收调剂公告
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doudounba

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[求助] 翻译一段中文

对实验数据进行分析发现在降温过程中A分子和B分子的分子内氢键及分子内氢键之间的竞争行为引起了A的S=O双键和B分子的O-H键的拉曼谱带的变化。进一步分析表明:在27℃至-30℃降温过程A与B之间氢键加强,-30℃至-60℃降温过程A与A之间氢键代替A与B之间的氢键。这为丰富溶液的氢键理论提供了实验依据。

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小小烧饼

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爱与雨下: 金币+2 2012-12-03 18:59:48
doudounba: 金币+10, 翻译EPI+1, 有帮助 2012-12-15 17:12:50
Through the analysis of the experimental data i found intramolecular hydrogen bond of  A molecule and B molecule
and the change of Raman spectrum band of the S=O double bond of A molecule and O=H bond of B molecule
by the competative behavior of intramolecular hydrogen bond
in the process of  temperature drop.
Further analysis shows that : hydrogen bond between A and B strengthened during the 27-
(-30℃) temperature drop, the hydrogen bond between  A and A
replace hydrogen bond of A and B during the -30~-60℃ temperature drop process. And this provides  a scientific basis for the enrich of hodrogen theory of solution .

外行翻译的,见笑了。句子有点长,不是很好翻译。
冰冻三尺,非一日之寒
2楼2012-12-03 17:56:29
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qfzcom

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Carena: 金币+2, 感谢应助,辛苦了 2012-12-04 19:06:58
doudounba: 金币+10, ★★★★★最佳答案 2012-12-15 17:14:22
From the analysis of the experimental data it is observed that the competition behavior of intramolecular hydrogen bond between A molecule and B molecule as well as intramolecular hydrogen bond themselves leads to the variation of raman band of the S=O double bond of A molecule and O=H bond of B molecule in the cooling process.Further  analysis indicates hydrogen bond between A and B was reinforced in the cooling process from 27℃ to -30℃ while hydrogen bond between A and A was replaced by hydrogen bond between A and B in the cooling process from -30℃to -60℃, which provides experimental basis for enriching hydrogen bond of solution.
3楼2012-12-03 21:23:42
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lize886622

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doudounba: 金币+10, ★★★很有帮助 2012-12-15 17:14:28
it is observed that the change of Raman spectrum band of the S=O double of A molecule and O-H bond of B molecule by the analysis of the experimental data, due to the competition behavior of intramolecular hydrogen
bond of A molecule and B molecule. Futher analysis indacates that indicates hydrogen bond between A and B was reinforced in the cooling process from 27℃ to -30℃ while hydrogen bond between A and A was replaced by hydrogen bond between A and B in the cooling process from -30℃to -60℃, And this provides  a theory basis for the enrich of hodrogen bond of solution .
hero
4楼2012-12-03 22:58:13
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doudounba

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谢谢三位的帮助!
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5楼2012-12-15 17:18:15
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