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°®ÓëÓêÏÂ: ½ð±Ò+2 2012-12-03 18:59:48
doudounba: ½ð±Ò+10, ·­ÒëEPI+1, ¡ïÓаïÖú 2012-12-15 17:12:50
Through the analysis of the experimental data i found intramolecular hydrogen bond of  A molecule and B molecule
and the change of Raman spectrum band of the S=O double bond of A molecule and O=H bond of B molecule
by the competative behavior of intramolecular hydrogen bond
in the process of  temperature drop.
Further analysis shows that : hydrogen bond between A and B strengthened during the 27-
(-30¡æ£© temperature drop, the hydrogen bond between  A and A
replace hydrogen bond of A and B during the -30~-60¡æ temperature drop process. And this provides  a scientific basis for the enrich of hodrogen theory of solution .

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2Â¥2012-12-03 17:56:29
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qfzcom

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Carena: ½ð±Ò+2, ¸ÐлӦÖú£¬ÐÁ¿àÁË 2012-12-04 19:06:58
doudounba: ½ð±Ò+10, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2012-12-15 17:14:22
From the analysis of the experimental data it is observed that the competition behavior of intramolecular hydrogen bond between A molecule and B molecule as well as intramolecular hydrogen bond themselves leads to the variation of raman band of the S=O double bond of A molecule and O=H bond of B molecule in the cooling process.Further  analysis indicates hydrogen bond between A and B was reinforced in the cooling process from 27¡æ to -30¡æ while hydrogen bond between A and A was replaced by hydrogen bond between A and B in the cooling process from -30¡æto -60¡æ, which provides experimental basis for enriching hydrogen bond of solution.
3Â¥2012-12-03 21:23:42
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

lize886622

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doudounba: ½ð±Ò+10, ¡ï¡ï¡ïºÜÓаïÖú 2012-12-15 17:14:28
it is observed that the change of Raman spectrum band of the S=O double of A molecule and O-H bond of B molecule by the analysis of the experimental data, due to the competition behavior of intramolecular hydrogen
bond of A molecule and B molecule. Futher analysis indacates that indicates hydrogen bond between A and B was reinforced in the cooling process from 27¡æ to -30¡æ while hydrogen bond between A and A was replaced by hydrogen bond between A and B in the cooling process from -30¡æto -60¡æ, And this provides  a theory basis for the enrich of hodrogen bond of solution .
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4Â¥2012-12-03 22:58:13
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

doudounba

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