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1. In the EIS analysis (Table 8), the unit of CPEdl-T is wrong. CPEdl-T from ZView does not have a unit of capacitance. The impedance of CPE is defined as Z=1/(CPE_T*(i*Omega)^CPE_P). So the unit of CPE_T is a little strange, though it can be normally treated as a similar term of capacitance. To calculate the real capacitance, the discussions in the following papers are helpful. G.J. Brug, A.L.G.VanDenEeden, M. Sluyters-Rehbach, J.H. Sluyters, J. Electroanal. Chem. 176 (1984) 275. S.P. Harrington, T.M. Devine, J. Electrochem. Soc. 155 (2008) C381. C.H. Hsu and F. Mansfeld, CORROSION, 2001, Vol. 57, No. 9, p747 ³ýÁËÐÞ¸Ä CPEdl-TµÄµ¥Î»£¬»¹Òª¸ù¾ÝÌṩµÄÎÄÏ×¼ÆËãthe real capacitanceÂ𣿠2. The error of utilization efficiency in 600s seems high, if compared with long term experiment result, is there some difference between them? ÕâÀïÊDz»ÊÇÐèÒª²¹³äʵÑé°¡£¿×öÒ»ÏÂong term experiment£¬µÃ³öµÄ½á¹ûÔÙÓë600s¶Ô±È£¿£¿ |
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