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金子01

银虫 (小有名气)


[交流] 亲爱的童鞋们,你们在投稿时是否遇到过不懂审稿人给的修改意见的时候啊?

俺的处女作出审稿意见了,可审稿人抓住俺一个问题不放,一口气问了俺五个关于俺的xps的问题,杯具的是俺都不知道他在说些什么,因为他的问题很专业,俺只想用XPS证明点小东西,而且在俺引用的文章当中这种数据分析得出来的结论已经是很成熟的了,可他还是问了很多俺看不懂的问题,叫额如何回答他呢?郁闷闷中……
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mlanqiang

木虫之王 (文学泰斗)



金子01(金币+1):谢谢参与
找找专门做xps的人给指导一下。
13楼2011-12-16 13:43:46
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金子01(金币+1):谢谢参与
金子01(金币+1): 2011-12-16 13:14:02
找身边的高手请教
2楼2011-12-16 12:52:18
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feixiang8131

银虫 (正式写手)



金子01(金币+1):谢谢参与
金子01(金币+2): 2011-12-16 13:13:54
那就一一按照他给的回答,你可以把能够贴出来的意见拿出来问问大家。

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3楼2011-12-16 13:07:42
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金子01

银虫 (小有名气)


Comments 4: The binding energy shift for Zn2+, even if it is real (see point one of this report), it is accompanied by a similar shift in the O 1s peak assigned to ZnO. This simultaneous shift could also be due to the confinement of the ZnO dots. In fact, BE=-E(orbital) only in the absence of relaxations. In solids, mainly in oxides, relaxation effects may be so strong that, for may oxides, the binding energy for the metal ion in an oxide MO (M2+) may be higher than for a M2O3 (M3+). It should not be surprising if the confinement of the ZnO into a quantum dot resulted into a very different relaxation effect for the hole left behind by the ejected photoelectron and it is a very well known effect for the BE of metals in nanoparticles: it raises when the nanoparticle size decreases.
Moreover, if the occurrence of Zn-O-Si bonds occurred at the surface, yet in the core of the quantum dot, a few bonds Zn-O-Zn should also exist. And given the dimensions of the quantum dots, the corresponding signal should not suffer considerable attenuation. Why should the Zn 2p3/2 present a single component?
4楼2011-12-16 13:14:42
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