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金子01

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[交流] 亲爱的童鞋们,你们在投稿时是否遇到过不懂审稿人给的修改意见的时候啊?

俺的处女作出审稿意见了,可审稿人抓住俺一个问题不放,一口气问了俺五个关于俺的xps的问题,杯具的是俺都不知道他在说些什么,因为他的问题很专业,俺只想用XPS证明点小东西,而且在俺引用的文章当中这种数据分析得出来的结论已经是很成熟的了,可他还是问了很多俺看不懂的问题,叫额如何回答他呢?郁闷闷中……
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金子01

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引用回帖:
5楼: Originally posted by 金子01 at 2011-12-16 13:16:34:
这个是其中一个评论,最不理解的就是他提到的BE那块,什么松弛效应,我们做的方向还没遇到过这类东东呢

还有一个问题,俺现在好像看出点眉目来
Comments 1: It is not mentioned how the compensation of accumulated positive charged was performed and which was the reference taken. Thence, the absolute values for binding energy are meaningless.
这个是不是要标准值:the reference value measured for calibration of spectrometer
那这个值在测量xps结果中有吗,我看遍了我的xps数据只找到一个Analyser Mode        CAE : Pass Energy 20.0 eV        觉得这个可能跟那个相近,求高手指教
10楼2011-12-16 13:27:56
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金子01(金币+1):谢谢参与
金子01(金币+1): 2011-12-16 13:14:02
找身边的高手请教
2楼2011-12-16 12:52:18
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feixiang8131

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金子01(金币+1):谢谢参与
金子01(金币+2): 2011-12-16 13:13:54
那就一一按照他给的回答,你可以把能够贴出来的意见拿出来问问大家。

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3楼2011-12-16 13:07:42
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金子01

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Comments 4: The binding energy shift for Zn2+, even if it is real (see point one of this report), it is accompanied by a similar shift in the O 1s peak assigned to ZnO. This simultaneous shift could also be due to the confinement of the ZnO dots. In fact, BE=-E(orbital) only in the absence of relaxations. In solids, mainly in oxides, relaxation effects may be so strong that, for may oxides, the binding energy for the metal ion in an oxide MO (M2+) may be higher than for a M2O3 (M3+). It should not be surprising if the confinement of the ZnO into a quantum dot resulted into a very different relaxation effect for the hole left behind by the ejected photoelectron and it is a very well known effect for the BE of metals in nanoparticles: it raises when the nanoparticle size decreases.
Moreover, if the occurrence of Zn-O-Si bonds occurred at the surface, yet in the core of the quantum dot, a few bonds Zn-O-Zn should also exist. And given the dimensions of the quantum dots, the corresponding signal should not suffer considerable attenuation. Why should the Zn 2p3/2 present a single component?
4楼2011-12-16 13:14:42
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