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tsh8167

ľ³æ (СÓÐÃûÆø)

[½»Á÷] ¡¾ÇóÖú¡¿Ëã·Ö×ÓÄܯ׵Äʱºò½á¹ûÈ«¶¼Îª¸ºÊý£¬ÊÇÎÊÌâÒýÆðµÄ£¿ ÒÑÓÐ4È˲ÎÓë

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[ Last edited by tsh8167 on 2010-6-28 at 11:29 ]
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redhaier

½ð³æ (СÓÐÃûÆø)

¡ï
tsh8167(½ð±Ò+1): 2010-06-25 09:36:22
qasd(½ð±Ò+1):лл 2010-06-28 20:11:38
what data?DOS?
ÒýÓûØÌû:
Originally posted by tsh8167 at 2010-06-24 15:41:57:
ÎÒÔÚ¼ÆËã˫̽ÕëÌåϵÖеķÖ×ÓÄܯ׵Äʱºò£¬µÃ³öµÄÊý¾ÝÊÇ´Ó-9942.9µ½-5474.78£¬ÕâÊÇÎÒ¼ÓÈëÒ»¸öÏõ»ùºó³öÏֵĴíÎó¡£
    µ«ÊǼÓÁíÒ»ÖÖ°±»ùºÍû¼Ó²à»ùÍÅËù¼ÆËãµÄ½á¹û¶¼ÊÇÕý³£µÄ¡£ÕâÈýÖÖÌåϵ¶¼ÊÇÓÃͬһÖÖ·½·¨¹¹½¨£¬¶¼Óà ...

2Â¥2010-06-24 17:15:00
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

tsh8167

ľ³æ (СÓÐÃûÆø)

ÊÇEnergy Spectrum
ÒýÓûØÌû:
Originally posted by redhaier at 2010-06-24 17:15:00:
what data?DOS?


[ Last edited by tsh8167 on 2010-6-24 at 17:44 ]
3Â¥2010-06-24 17:43:19
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

redhaier

½ð³æ (СÓÐÃûÆø)

¡ï
hedaors(½ð±Ò+1):лл½»Á÷ 2010-06-25 22:47:19
tsh8167(½ð±Ò+1):лл£¬ÎÒÊÔÊÔ 2010-06-26 17:31:22
Ok, they should be the same, try to decrease the lower energy bound in the green function
integral contour.
ÒýÓûØÌû:
Originally posted by tsh8167 at 2010-06-24 17:43:19:
ÊÇEnergy Spectrum


[ Last edited by tsh8167 on 2010-6-24 at 17:44 ]

4Â¥2010-06-25 22:41:36
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

tsh8167

ľ³æ (СÓÐÃûÆø)

[quote]Originally posted by redhaier at 2010-06-25 22:41:36:
Ok, they should be the same, try to decrease the lower energy bound in the green function
integral contour.

ÎÒÊÔÁË£¬¼ÆËã½á¹û»¹ÊÇÄÇÑù£¬
5Â¥2010-06-27 10:28:58
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

redhaier

½ð³æ (СÓÐÃûÆø)

¡ï
tsh8167(½ð±Ò+1): 2010-06-30 11:16:28
gavinliu7390(½ð±Ò+1):лл½»Á÷£¡ 2010-07-04 10:16:06
It is hard to say why since there is no input file.
ÒýÓûØÌû:
Originally posted by tsh8167 at 2010-06-27 10:28:58:
[quote]Originally posted by redhaier at 2010-06-25 22:41:36:
Ok, they should be the same, try to decrease the lower energy bound in the green function
integral contour.

ÎÒÊÔÁË£¬¼ÆËã½á¹û ...

6Â¥2010-06-28 19:54:31
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

tsh8167

ľ³æ (СÓÐÃûÆø)

[quote]Originally posted by redhaier at 2010-06-28 19:54:31:
It is hard to say why since there is no input file.


ÊäÈëÎļþµÄ²ÎÊýÉèÖᢼÆË㲿·Ö£º


# Set up electrodes
electrode_configuration = PeriodicAtomConfiguration(
    electrode_cell,
    electrode_elements,
    electrode_coordinates
    )

# Set up two-probe configuration
twoprobe_configuration = TwoProbeConfiguration(
    (electrode_configuration,electrode_configuration),
    scattering_elements,
    scattering_coordinates,
    electrode_repetitions=[[3,3],[3,3]],
    equivalent_atoms=([0,0],[2,77])
    )
if processIsMaster(): nlPrint(twoprobe_configuration)
if processIsMaster(): file.addToSample(twoprobe_configuration, 'twoprobe_configuration')

######################################################################
# Central region parameters
######################################################################
exchange_correlation_type = LDA.PZ

iteration_mixing_parameters = iterationMixingParameters(
    algorithm = IterationMixing.Pulay,
    diagonal_mixing_parameter = 0.1,
    quantity = IterationMixing.Hamiltonian,
    history_steps = 6
)

electron_density_parameters = electronDensityParameters(
    mesh_cutoff = 150.0*Rydberg
)

basis_set_parameters = basisSetParameters(
    type = SingleZetaPolarized,
    radial_sampling_dr = 0.001*Bohr,
    energy_shift = 0.01*Rydberg,
    delta_rinn = 0.8,
    v0 = 40.0*Rydberg,
    charge = 0.0,
    split_norm = 0.15
)

iteration_control_parameters = iterationControlParameters(
    tolerance = 1e-005,
    criterion = IterationControl.TotalEnergy,
    max_steps = 100
)

electrode_voltages = (0.0,0.0)*Volt

two_probe_algorithm_parameters = twoProbeAlgorithmParameters(
    electrode_constraint = ElectrodeConstraints.Off,
    initial_density_type = InitialDensityType.EquivalentBulk
)

energy_contour_integral_parameters = energyContourIntegralParameters(
    circle_points = 30,
    integral_lower_bound = 3*Rydberg,
    fermi_line_points = 10,
    fermi_function_poles = 4,
    real_axis_infinitesimal = 0.01*electronVolt,
    real_axis_point_density = 0.02*electronVolt
)

two_center_integral_parameters = twoCenterIntegralParameters(
    cutoff = 2500.0*Rydberg,
    points = 1024
)

######################################################################
# Left electrode parameters
######################################################################
left_electrode_electron_density_parameters = electronDensityParameters(
    mesh_cutoff = 150.0*Rydberg
)

left_electrode_iteration_control_parameters = iterationControlParameters(
    tolerance = 1e-005,
    criterion = IterationControl.TotalEnergy,
    max_steps = 100
)

left_electrode_brillouin_zone_integration_parameters = brillouinZoneIntegrationParameters(
    monkhorst_pack_parameters = (3, 3, 100)
)

left_electrode_iteration_mixing_parameters = iterationMixingParameters(
    algorithm = IterationMixing.Pulay,
    diagonal_mixing_parameter = 0.1,
    quantity = IterationMixing.Hamiltonian,
    history_steps = 6
)

left_electrode_eigenstate_occupation_parameters = eigenstateOccupationParameters(
    temperature = 300.0*Kelvin
)

######################################################################
# Collect left electrode parameters
######################################################################
left_electrode_parameters = ElectrodeParameters(
    brillouin_zone_integration_parameters = left_electrode_brillouin_zone_integration_parameters,
    electron_density_parameters = left_electrode_electron_density_parameters,
    eigenstate_occupation_parameters = left_electrode_eigenstate_occupation_parameters,
    iteration_mixing_parameters = left_electrode_iteration_mixing_parameters,
    iteration_control_parameters = left_electrode_iteration_control_parameters
)

######################################################################
# Right electrode parameters
######################################################################
right_electrode_electron_density_parameters = electronDensityParameters(
    mesh_cutoff = 150.0*Rydberg
)

right_electrode_iteration_control_parameters = iterationControlParameters(
    tolerance = 1e-005,
    criterion = IterationControl.TotalEnergy,
    max_steps = 100
)

right_electrode_brillouin_zone_integration_parameters = brillouinZoneIntegrationParameters(
    monkhorst_pack_parameters = (3, 3, 100)
)

right_electrode_iteration_mixing_parameters = iterationMixingParameters(
    algorithm = IterationMixing.Pulay,
    diagonal_mixing_parameter = 0.1,
    quantity = IterationMixing.Hamiltonian,
    history_steps = 6
)

right_electrode_eigenstate_occupation_parameters = eigenstateOccupationParameters(
    temperature = 300.0*Kelvin
)

######################################################################
# Collect right electrode parameters
######################################################################
right_electrode_parameters = ElectrodeParameters(
    brillouin_zone_integration_parameters = right_electrode_brillouin_zone_integration_parameters,
    electron_density_parameters = right_electrode_electron_density_parameters,
    eigenstate_occupation_parameters = right_electrode_eigenstate_occupation_parameters,
    iteration_mixing_parameters = right_electrode_iteration_mixing_parameters,
    iteration_control_parameters = right_electrode_iteration_control_parameters
)

######################################################################
# Initialize self-consistent field calculation
######################################################################
two_probe_method = TwoProbeMethod(
    electrode_parameters = (left_electrode_parameters,right_electrode_parameters),
    exchange_correlation_type = exchange_correlation_type,
    iteration_mixing_parameters = iteration_mixing_parameters,
    electron_density_parameters = electron_density_parameters,
    basis_set_parameters = basis_set_parameters,
    iteration_control_parameters = iteration_control_parameters,
    energy_contour_integral_parameters = energy_contour_integral_parameters,
    two_center_integral_parameters = two_center_integral_parameters,
    electrode_voltages = electrode_voltages,
    algorithm_parameters = two_probe_algorithm_parameters
)
if processIsMaster(): nlPrint(two_probe_method)

# Restore self consistent calculation from check point file
scf = restoreSelfConsistentCalculation(
    filename = 'D:/VNL/newmolecule/newmolecule-Au-NO2/newmolecule-Au-NO2-opt.nc'
)

runtime_parameters = runtimeParameters(
    verbosity_level = 5,
    checkpoint_filename = 'D:/VNL/newmolecule/newmolecule-Au-NO2/newmolecule-Au-NO2.nc'
)

# Using initial density from self consistent calculation
scf = executeSelfConsistentCalculation(
    twoprobe_configuration,
    two_probe_method,
    initial_calculation = scf,
    runtime_parameters = runtime_parameters
)
######################################################################
# Calculate physical properties
######################################################################
projected_hamiltonian_energy_spectrum = calculateProjectedHamiltonianEnergySpectrum(
    self_consistent_calculation = scf,
    projection_atoms = (0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77)
)
if processIsMaster(): nlPrint(projected_hamiltonian_energy_spectrum)
if processIsMaster(): file.addToSample(projected_hamiltonian_energy_spectrum, 'twoprobe_configuration', 'Projected Hamiltonian Energy Spectrum')

import numpy
transmission_spectrum = calculateTransmissionSpectrum(
    self_consistent_calculation = scf,
    energies = numpy.arange(-2.0, 2.0+0.002, 0.02)*electronVolt,
    brillouin_zone_integration_parameters = brillouinZoneIntegrationParameters((1, 1)),
    green_function_infinitesimal = 0.0001*electronVolt
)
if processIsMaster(): nlPrint(transmission_spectrum)
if processIsMaster(): file.addToSample(transmission_spectrum, 'twoprobe_configuration', 'Transmission Spectrum')




[ Last edited by tsh8167 on 2010-6-30 at 11:18 ]
7Â¥2010-06-30 11:16:15
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

panjinbo87

ľ³æ (ÕýʽдÊÖ)

¡ï ¡ï
lvjian8596(½ð±Ò+2):¸Ðл½»Á÷£¡ 2010-07-04 09:23:45
tsh8167(½ð±Ò+1):лл½»Á÷ 2010-07-04 09:37:51
Äã¿´ÏÂÄã˵µÄoutÎļþ£¬¿Ï¶¨Ã¿¸öÔ­×ÓÉϵĵç×ÓÊýΪ0.ÕâÊǽÐ×öÒ»¸öʲô¼ÆËãÒç³ö¡£¸úÄãѡȡʲô»ùº¯ÊýµÈûʲô¹ØÏµ¡£Äã¿ÉÒÔÊÔ×ÅÓÅ»¯Ï½ṹ£¬ÔÙÖØÐÂËã¡£»òÕßÉÔ΢Ôö´ó·Ö×ÓÓëµç¼«¼äµÄ¾àÀ루ÈçÁ½±ß¶¼Ôö´ó0.1°¦£©¡£
8Â¥2010-07-04 06:36:05
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

tsh8167

ľ³æ (СÓÐÃûÆø)

ÒýÓûØÌû:
Originally posted by panjinbo87 at 2010-07-04 06:36:05:
Äã¿´ÏÂÄã˵µÄoutÎļþ£¬¿Ï¶¨Ã¿¸öÔ­×ÓÉϵĵç×ÓÊýΪ0.ÕâÊǽÐ×öÒ»¸öʲô¼ÆËãÒç³ö¡£¸úÄãѡȡʲô»ùº¯ÊýµÈûʲô¹ØÏµ¡£Äã¿ÉÒÔÊÔ×ÅÓÅ»¯Ï½ṹ£¬ÔÙÖØÐÂËã¡£»òÕßÉÔ΢Ôö´ó·Ö×ÓÓëµç¼«¼äµÄ¾àÀ루ÈçÁ½±ß¶¼Ôö´ó0.1°¦£©¡£

outÎļþ£º
# Electrodes 0 and 1
# -----------------------------------------------------------------------------
# Index  Element  x (Ang)  y (Ang)  z (Ang)
      0       Au     0.00     0.00     0.00
      1       Au     0.00     1.66     2.35
      2       Au     1.44     0.83     4.71
# -----------------------------------------------------------------------------
# Supercell Vectors
# -----------------------------------------------------------------------------
# Vector number  x (Ang)  y (Ang)  z (Ang)
              0     2.88     0.00     0.00
              1    -1.44     2.50     0.00
              2     0.00     0.00     7.06
# -----------------------------------------------------------------------------
# Two Probe Method
# -----------------------------------------------------------------------------

# -----------------------------------------------------------------------------
# Basis Set Parameters
# -----------------------------------------------------------------------------
Type               = SZP
Radial Sampling dr = 0.001 Bohr
Energy Shift       = 0.01 Rydberg
Delta R(inner)     = 0.8
v0                 = 40 Rydberg
Charge             = 0
Split Norm         = 0.15
Element            = All

# -----------------------------------------------------------------------------
# Exchange Correlation
# -----------------------------------------------------------------------------
Exchange Correlation Type = LDA.PZ

# -----------------------------------------------------------------------------
# ElectronDensityParameters
# -----------------------------------------------------------------------------
Mesh Cutoff         = 150.00 Rydberg

# -----------------------------------------------------------------------------
# Two Center Integral Parameters
# -----------------------------------------------------------------------------
Cutoff           = 2500.0 Rydberg
Number Of Points = 1024

# -----------------------------------------------------------------------------
# Iteration Mixing Parameters
# -----------------------------------------------------------------------------
Algorithm                 = Pulay
Diagonal Mixing Parameter = 0.1
Quantity                  = Hamiltonian
History Steps             = 6

# -----------------------------------------------------------------------------
# Iteration Control Parameters
# -----------------------------------------------------------------------------
Tolerance  = 1e-005
Criterion  = TotalEnergy
Max. Steps = 100

# -----------------------------------------------------------------------------
# Energy Contour Integral Parameters
# -----------------------------------------------------------------------------
Circle Points           = 30
Integral Lower Bound    = 3 Rydberg
Fermi Function Poles    = 4
Real Axis Infinitesimal = 0.01 eV
Real Axis Point Density = 0.02 eV

# -----------------------------------------------------------------------------
# Electrode Voltages
# -----------------------------------------------------------------------------
Voltage at Electrode 0 = 0.00 V
Voltage at Electrode 1 = 0.00 V

# -----------------------------------------------------------------------------
# TwoProbe Algorithm Parameters
# -----------------------------------------------------------------------------
Electrode Constraint = ElectrodeConstraints.Off
Initial Density Type = InitialDensityType.EquivalentBulk

# sc  0 : q =   -0.00341 e
# sc  1 : q =   -0.00341 e  dRho = 4.2404E-009
# sc  2 : q =   -0.00341 e  Etot = 171607.35005 Ry  dRho = 4.1350E-011
# sc  3 : q =   -0.00341 e  Etot = 171607.35006 Ry  dRho = 3.9736E-010  dEtot = 5.6953E-006 Ry
# -----------------------------------------------------------------------------
# Energy Spectrum
# -----------------------------------------------------------------------------
# Energy (eV)
     -9942.95
     -9932.08
     -9930.06
     -9923.08
     -9923.03
     -9917.18
     -9914.21
     -9911.05
     -9908.87
     -9908.56
     -9905.48
     -9903.00
     -9902.30
     -9899.47
     -9897.87
     -9896.94
     -9896.45
     -9895.84
     -9894.46
  **Öм䲿·ÖÊ¡ÂÔ****   
     -6235.33
     -6235.28
     -6235.25
     -6234.25
     -6234.24
     -6234.16
     -5942.77
     -5942.37
     -5936.24
     -5936.10
     -5936.04
     -5935.39
     -5935.31
     -5934.71
     -5919.22
     -5919.20
     -5919.17
     -5918.54
     -5918.48
     -5918.31
     -5918.04
     -5918.03
     -5911.29
     -5911.12
     -5507.89
     -5485.27
     -5485.24
     -5485.07
     -5484.65
     -5484.57
     -5484.55
     -5474.77
     -5474.77
# -----------------------------------------------------------------------------
# Transmission Spectrum
# -----------------------------------------------------------------------------
# Energy (eV)   Coefficient
        -2.00        0.0000
        -1.98        0.0000
        -1.96        0.0000
        -1.94        0.0000
        -1.92        0.0000
        -1.90        0.0000
        -1.88        0.0000
        -1.86        0.0000
        -1.84        0.0000
        -1.82        0.0000
        -1.80        0.0000
        -1.78        0.0000
        -1.76        0.0000
        -1.74        0.0000
        -1.72        0.0000
        -1.70        0.0000
        -1.68        0.0000
        -1.66        0.0000
        -1.64        0.0000
        -1.62        0.0000
        -1.60        0.0000
        -1.58        0.0000
        -1.56        0.0000
        -1.54        0.0000
        -1.52        0.0000
        -1.50        0.0000
        -1.48        0.0000
        -1.46        0.0000
        -1.44        0.0000
        -1.42        0.0000
        -1.40        0.0000
        -1.38        0.0000
        -1.36        0.0000
        -1.34        0.0000
        -1.32        0.0000
        -1.30        0.0000
        -1.28        0.0000
        -1.26        0.0000
        -1.24        0.0000
        -1.22        0.0000
        -1.20        0.0000
        -1.18        0.0000
        -1.16        0.0000
        -1.14        0.0000
        -1.12        0.0000
        -1.10        0.0000
        -1.08        0.0000
        -1.06        0.0000
        -1.04        0.0000
        -1.02        0.0000
        -1.00        0.0000
        -0.98        0.0000
        -0.96        0.0000
        -0.94        0.0000
        -0.92        0.0000
        -0.90        0.0000
        -0.88        0.0000
        -0.86        0.0000
        -0.84        0.0000
        -0.82        0.0000
        -0.80        0.0000
        -0.78        0.0000
        -0.76        0.0000
        -0.74        0.0000
        -0.72        0.0000
        -0.70        0.0000
        -0.68        0.0000
        -0.66        0.0000
        -0.64        0.0000
        -0.62        0.0000
        -0.60        0.0000
        -0.58        0.0000
        -0.56        0.0000
        -0.54        0.0000
        -0.52        0.0000
        -0.50        0.0000
        -0.48        0.0000
        -0.46        0.0000
        -0.44        0.0000
        -0.42        0.0000
        -0.40        0.0000
        -0.38        0.0000
        -0.36        0.0000
        -0.34        0.0000
        -0.32        0.0000
        -0.30        0.0000
        -0.28        0.0000
        -0.26        0.0000
        -0.24        0.0000
        -0.22        0.0000
        -0.20        0.0000
        -0.18        0.0000
        -0.16        0.0000
        -0.14        0.0000
        -0.12        0.0000
        -0.10        0.0000
        -0.08        0.0000
        -0.06        0.0000
        -0.04        0.0000
        -0.02        0.0000
         0.00        0.0000
         0.02        0.0000
         0.04        0.0000
         0.06        0.0000
         0.08        0.0000
         0.10        0.0000
         0.12        0.0000
         0.14        0.0000
         0.16        0.0000
         0.18        0.0000
         0.20        0.0000
         0.22        0.0000
         0.24        0.0000
         0.26        0.0000
         0.28        0.0000
         0.30        0.0000
         0.32        0.0000
         0.34        0.0000
         0.36        0.0000
         0.38        0.0000
         0.40        0.0000
         0.42        0.0000
         0.44        0.0000
         0.46        0.0000
         0.48        0.0000
         0.50        0.0000
         0.52        0.0000
         0.54        0.0000
         0.56        0.0000
         0.58        0.0000
         0.60        0.0000
         0.62        0.0000
         0.64        0.0000
         0.66        0.0000
         0.68        0.0000
         0.70        0.0000
         0.72        0.0000
         0.74        0.0000
         0.76        0.0000
         0.78        0.0000
         0.80        0.0000
         0.82        0.0000
         0.84        0.0000
         0.86        0.0000
         0.88        0.0000
         0.90        0.0000
         0.92        0.0000
         0.94        0.0000
         0.96        0.0000
         0.98        0.0000
         1.00        0.0000
         1.02        0.0000
         1.04        0.0000
         1.06        0.0000
         1.08        0.0000
         1.10        0.0000
         1.12        0.0000
         1.14        0.0000
         1.16        0.0000
         1.18        0.0000
         1.20        0.0000
         1.22        0.0000
         1.24        0.0000
         1.26        0.0000
         1.28        0.0000
         1.30        0.0000
         1.32        0.0000
         1.34        0.0000
         1.36        0.0000
         1.38        0.0000
         1.40        0.0000
         1.42        0.0000
         1.44        0.0000
         1.46        0.0000
         1.48        0.0000
         1.50        0.0000
         1.52        0.0000
         1.54        0.0000
         1.56        0.0000
         1.58        0.0000
         1.60        0.0000
         1.62        0.0000
         1.64        0.0000
         1.66        0.0000
         1.68        0.0000
         1.70        0.0000
         1.72        0.0000
         1.74        0.0000
         1.76        0.0000
         1.78        0.0000
         1.80        0.0000
         1.82        0.0000
         1.84        0.0000
         1.86        0.0000
         1.88        0.0000
         1.90        0.0000
         1.92        0.0000
         1.94        0.0000
         1.96        0.0000
         1.98        0.0000
         2.00        0.0000
9Â¥2010-07-04 09:41:17
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tsh8167

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10Â¥2010-07-04 09:47:18
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