24小时热门版块排行榜    

CyRhmU.jpeg
查看: 1096  |  回复: 7
本帖产生 1 个 翻译EPI ,点击这里进行查看

红星闪闪001

已阅   关注TA 给TA发消息 送TA红花 TA的回帖

水飘零

金虫 (著名写手)

金陵家族之潜水人士

金属配合物中苯环的光谱位移?

翻译的很不好,最好有上下文
花自飘零水自流,一种相思,两处闲愁;此情无计可消除,才下眉头,却上心头
2楼2010-05-20 22:38:34
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

红星闪闪001

We have been interested for some time in the synthetic
applications of the photochemical displacement of benzene from
M(II) complexes (M ) Fe, Ru, Os).1-4 For instance, photolysis
of [CpRu(Bz)]+ (Cp ) è5-C5H5, Bz ) è6-C6H6) in acetonitrile
solution gives [CpRu(CH3CN)3]+
原文
3楼2010-05-20 23:40:47
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

pharmjackie

木虫 (正式写手)

红星闪闪001(金币+1, 翻译EPI+1):谢谢 2010-05-23 13:44:59
photochemical displacement of benzene from
M(II) complexes (M =Fe, Ru, Os).  将苯环从M(II)复合物中以光化学方法置换出来(M=Fe, Ru, Os)。
4楼2010-05-21 07:39:02
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

沧浪之水1282

金虫 (小有名气)

同意ls的翻译
漫步人生路
5楼2010-05-21 09:34:43
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

jwdxbjzh

至尊木虫 (职业作家)

红星闪闪001(金币+1):谢谢 2010-05-23 13:45:23
用光化学法将苯环从M(II)配合物中置换出来。例如,“photolysis
of [CpRu(Bz)]+ (Cp ) è5-C5H5, Bz ) è6-C6H6) in acetonitrile
solution gives [CpRu(CH3CN)3]+”中用光化学法用乙腈将[CpRu(Bz)]+ (Cp ) è5-C5H5, Bz ) è6-C6H6)中的苯环从中置换出来得到[CpRu(CH3CN)3]+。
jwd
6楼2010-05-21 11:24:24
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

jwdxbjzh

至尊木虫 (职业作家)

见文献:Photochemical displacement of the benzene ligand in [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) ,Inorganica Chimica Acta,Volume 357, Issue 9, 5 July 2004, Pages 2721-2727。

Wolfgang Lacknera, Christina Maria Standfest-Hausera, Kurt Mereiterb, Roland Schmida and Karl Kirchnera, ,

aInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria

bInstitute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria

Received 10 February 2004;  accepted 28 February 2004.  Available online 9 April 2004.

Abstract
Photoirradiation with a 150 W medium-pressure Hg lamp for 17 h in acetontrile as the solvent replaces the benzene ligand in the cationic complexes [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) with acetonitrile. These replacements are equally clean to those reported before for analogous CpRu+ complexes. Crystal structures of the products obtained are included.

Photoirradiation with a 150 W medium-pressure Hg lamp for 17 h in acetontrile as the solvent replaces the benzene ligand in the cationic complexes [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) with acetonitrile. These replacements are equally clean to those reported before for analogous CpRu+ complexes.
jwd
7楼2010-05-21 11:26:05
已阅   关注TA 给TA发消息 送TA红花 TA的回帖

公羊羽

木虫 (正式写手)

将苯环从M(II)(二价金属)配合物中置换出来的光化学法
8楼2010-05-21 18:54:09
已阅   关注TA 给TA发消息 送TA红花 TA的回帖
相关版块跳转 我要订阅楼主 红星闪闪001 的主题更新
信息提示
请填处理意见