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waiy2001(½ð±Ò+3,VIP+0):лл£¬Í¬ÉÏ 8-10 16:48
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Seth M. Cohen Associate Professor University of California, San Diego Research Interests Metalloprotein Inhibitors Researchers: Agrawal, Jacobsen, Yan. The design, synthesis, and evaluation of inhibitors of metalloproteins is the focus of this project. A number of metalloproteins are associated with diseases ranging from heart disease to cancer to anthrax infections. Using fundamental principles of inorganic chemistry we have developed inhibitors that better target the metal active sites of these proteins. The majority of our work has focused on matrix metalloproteinases (MMPs, see figure on left); however, we are branching out to other targets such as the anthrax lethal factor (LF). Our work in this area has also lead us to the exploration of the coordination chemistry of thiopyrone and hydroxypyridinethione ligands (see figure on right). Metal-Organic Frameworks Researchers: Garibay, Okamura, Stork, Tanabe, Thoi, Wang. The design, synthesis, characterization, and evaluation of new metal-organic frameworks (MOFs) is the goal of this project. MOFs are an up-and-coming class of materials that combine organic ligands and metal ions to generate porous materials with defined topologies. In our laboratory, we have concentrated on replacing the organic ligand component with a 'metalloligand' (e.g. coordination complex) that can impart new spectroscopic or catalytic properties to the MOF. Our studies have largely focused on dipyrromethene (dipyrrin) complexes as building blocks (see figure on left), and as such we have a general interest in developing the coordination chemistry of these interesting pyrrolic ligands. In a new component of this project, we are examining the ability of small organic reagents to perform postsynthetic modification on preformed MOFs (see figure on right). Other Projects Researchers: Various. In the course of our research we often run across a variety of interesting findings that we choose to investigate. One major effort was understanding the mechanism of the metalloregulatory protein MntR (and homologues) is the aim of this project. MntR (see figure) is a metalloregulatory protein (metal-activated, DNA-binding protein) from B. subtillis that helps to regulate manganese(II) homeostasis. We have focused on trying to understand how MntR is selective for this metal ion in its DNA-binding response. We are also trying to elucidate some of the structural features involved in the allosteric mechanism of activation for MntR. These topics are addressed by using a variety of biophysical methods, including: fluorescence anisotropy, absorbance/fluorescence titrations, circular dichroism spectroscopy, and others. Some projects in the lab that we have investigated from time to time have involved the study of lead(II) chelators, thioflavone metal complexes, and various other topics in bioinorganic chemistry. Cohen Research Group Publications Cut and paste the DOI codes into Google to find the articles on the web. 71. Diego Romero-Perez, Arpita Agrawal, Jennifer A. Jacobsen, Yi-Long Yan, Robert Thomas, Seth M. Cohen, and Francisco J. Villarreal, "Effects of Novel Semi-selective MMP Inhibitors on Ex vivo Cardiac Structure/Function" J. Cardiovas. Pharma. 2009, accepted for publication. DOI: ??????????????? 70. Yi-Long Yan, Melissa T. Miller, Yuchen Cao, and Seth M. Cohen, "Synthesis of Hydroxypyrone- and Hydroxythiopyrone-based Matrix Metalloproteinase Inhibitors: Developing a Structure-activity Relationship" Bioorg. Med. Chem. Lett. 2009, 19, 1970-1976. DOI: 10.1016/j.bmcl.2009.02.044 69. Zhenqiang Wang and Seth M. Cohen, "Postsynthetic Modification of Metal-Organic Frameworks" Chem. Soc. Rev. 2009, 38, 1315-1329. DOI: 10.1039/b802258p 68. Arpita Agrawal, C¨¦sar Augusto F. de Oliveira, Yuhui Cheng, Jennifer A. Jacobsen, J. Andrew McCammon, and Seth M. Cohen, "Thioamide Hydroxypyrothiones Supersede Amide Hydroxypyrothiones in Potency Against Anthrax Lethal Factor" J. Med. Chem. 2009, 52, 1063-1074. DOI: 10.1021/jm8013212 67. Zhenqiang Wang, Kristine K. Tanabe, and Seth M. Cohen, "Accessing Postsynthetic Modification in a Series of Metal-Organic Frameworks and the Influence of Framework Topology on Reactivity" Inorg. Chem. 2009, 48, 296-306. DOI: 10.1021/ic801837t 66. Sergio J. Garibay, Jay R. Stork, and Seth M. Cohen, "The Use of Metalloligands in Metal-Organic Frameworks" Prog. Inorg. Chem. 2009, 56, 335-378. DOI: N/A 65. Van S. Thoi, Jay R. Stork, Edwards T. Niles, Ezra C. Depperman, David L. Tierney, and Seth M. Cohen, "Diamidodipyrrins: Versatile Bipyrrolic Ligands with Multiple Metal Binding Modes" Inorg. Chem. 2008, 47, 10533-10541. DOI: 10.1021/ic8011876 64. Emily Dugan, Zhenqiang Wang, Marilyn Okamura, Annette Medina, and Seth M. Cohen, "Covalent Modification of a Metal-Organic Framework with Isocyanates: Probing Substrate Scope and Reactivity" Chem. Commun. 2008, 3366-3368 (featured cover article). DOI: 10.1039/b806150e10 63. Faith E. Jacobsen, Matthew W. Buczynski, Edward A. Dennis, and Seth M. Cohen, "A Macrophage Cell Model for Selective Metalloprotein Inhibitor Design" ChemBioChem 2008, 9, 2087-2095. DOI: 10.1002/cbic.200800148 62. Kristine K. Tanabe, Zhenqiang Wang, and Seth M. Cohen, "Systematic Functionalization of a Metal-Organic Framework via a Postsynthetic Modification Approach" J. Am. Chem. Soc. 2008, 130, 8508-8517. DOI: 10.1021/ja801848j .......................... |

22Â¥2009-06-23 13:26:18
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2Â¥2009-05-27 00:23:37
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±±¾©¿Æ¼¼´óѧ²ÄÁÏϵ ½ÌÊÚ¡¢²©Ê¿Éúµ¼Ê¦ ½ÌÓý¼òÀú£º 1977Äê,¶«±±¹¤Ñ§Ôº£¬½ðÊô²ÄÁÏϵ£¬±ÏÒµ 1981Äê,±±¾©¸ÖÌúѧԺ£¬²ÄÁÏ¿ÆÑ§Ó빤³Ìϵ£¬Ë¶Ê¿±ÏÒµ 1988Äê,µÂ¹úÑÇ衹¤Òµ´óѧ, ½ðÊôѧÑо¿Ëù£¬¹¤Ñ§²©Ê¿±ÏÒµ ¹¤×÷¼òÀú£º 1981 - ½ñ£¬ ±±¾©¿Æ¼¼´óѧ,½Ìʦ Ö÷ÒªÑо¿·½Ïò£º 1£©µç½âµçÈÝÆ÷ÂÁ²µÄ²ÄÁÏѧÔÀí¼°Ð²úÆ·¿ª·¢£» 2£©µç¹¤¸Ö²ÄÁÏѧÔÀí¼°ÐÂÐ͵繤¸ÖÆ·ÖֵĿª·¢Ñо¿£» 3£©¸ßÇ¿¶È¸Ö²Ä¸÷ÏòÒìÐԵĿª·¢ÓëÀûÓã» 4£©¶à¾§Ìå·Ç½ðÊô²ÄÁϾ§Ìåѧ¸÷ÏòÒìÐÔµÄÐγÉÓëÀûÓã» 5£©¸ßЧÇáÖʸ´ºÏµç´ÅÆÁ±Î²ÄÁϵĿª·¢Ñо¿£» ½üÆÚ·¢±íµÄÂÛÎÄ: 1. Mao W, Ren H, Yu Y, Precipition behavior of an Fe-1.03wt.% Cu alloy, Z. Metallkd., 2004, 95(1): 57-59. 2.Mao W, Yu Y, Effect of elastic reaction stress on plastic behaviors of grains in polycrystalline aggregate during tensile deformation, Materials Science & Engineering, 2004,367:277-281. 3.ëÎÀÃñ, ÈÎ»ÛÆ½, ÓàÓÀÄþ, ½á¹¹¸ÖÖк¬ÍÎö³öÏàµÄʱЧǿ»¯×÷ÓÃ, ²ÄÁÏÈÈ´¦Àí, 2004;25(2):1-4. 4. ëÎÀÃñ, ³ÂÀÝ, ÈøÀöÂü, ÓàÓÀÄþ, ÀîÔÆ·å, ¾§½ç¶ÔµÍѹµç½âµçÈÝÆ÷ÂÁ²¸¯Ê´½á¹¹µÄÓ°Ïì, ÖйúÓÐÉ«½ðÊôѧ±¨, 2004;14(1):1-5. 5.ëÎÀÃñ, Ñîºê, ÑîÆ½, ·ë»Ýƽ, ÍË»ð¶Ô¸ßѹµç½âµçÈÝÆ÷ÂÁ²Î¢Á¿ÔªËغ͸¯Ê´ÐÔÄܵÄÓ°Ïì, ½ðÊôÈÈ´¦Àí, 2004; 29(9): 3-6. 6.ëÎÀÃñ, ¸ß±ÈµçÈݵÍѹÑô¼«ÂÁ²µÄ±íÃæÎ¢¹Û×éÖ¯, ÊÀ½ç¿Æ¼¼Ñо¿Óë·¢Õ¹, 2004; 26(3): 16-21. 7. ëÎÀÃñ, ºÎÒµ¶«, ¹ú²úµç½âµçÈÝÆ÷Óü«ÂÁ²µÄ·¢Õ¹ÓëÕ¹Íû, ÊÀ½çÓÐÉ«½ðÊô, 2004; (8): 23-27. 8.ëÎÀÃñ, ³ÂÀä, ÑîÆ½, ·ë»Ýƽ, ÍË»ðÂÁ°åÖ¯¹¹X ÉäÏß¿ìËÙ¼ì²âÔÀí, ¿ÆÑ§Í¨±¨, 2004, 49 (20), 2128-2129. 9.ëÎÀÃñ, ½¯ºã, ÑîÆ½, ·ë»Ýƽ, ÓàÓÀÄþ, ΢¹Û½á¹¹ºÍ΢Á¿ÔªËضÔÂÁ²¸¯Ê´½á¹¹µÄÓ°Ïì, ÖйúÓÐÉ«½ðÊôѧ±¨, Vol. 14(10) 2004, 1627-1631. 10.Mao W, Jiang H, Yang P, Feng H, Yu Y, Distribution of microelements and their influence on the corrosion behavior of Aluminum foil, J. Material Science and Technology, vol. 21 (1), 2005, 43-46. 11.ëÎÀÃñ, ·½öï, ÎâÆäêÊ, ·ë»Ýƽ, µ¼µç¾Û±½°·/ôÊ»ùÌú·Û¸´ºÏÎü²¨²ÄÁÏ, ¸´ºÏ²ÄÁÏѧ±¨, 2005, Vol. 22(1), 11-14 12.Mao W, Chen L, Yang P, Yu Y, Reaction Stresses among the Grains during Tensile Deformation of Polycrystalline Metals, Solid State Phenomena, Vol. 105 (2005) pp. 95-100. 13.Mao W, Yu Y, Reaction Stress Model and Relaxation of Reaction Stress among the Grains during Tensile Deformation of FCC metals, Materials Science Forum, 2005, Vol. 495-497, p. 995-1000. 14. ëÎÀÃñ, Öìºêϲ, ³ÂÀä, ·ë»Ýƽ, ÂÀ·´ÐÞ, CVD×ÔÖ§³Å½ð¸Õʯ±¡Ä¤µÄºê¹ÛÖ¯¹¹Óë΢¹ÛÂϾ§, ÎÞ»ú²ÄÁÏѧ±¨, 2006, 21(1), 239-244. 15.ëÎÀÃñ, ÂíÈ«²Ö, ·ë»Ýƽ, ³Â²ýÔÆ, À±ò, ³åѹÂÁ°åËÜÐÔÓ¦±ä±ÈµÄÔÚÏß¼ì²â¼¼Êõ, ÖйúÓÐÉ«½ðÊôѧ±¨, 2006, 16(7), 1149-1154. 16.ëÎÀÃñ, ³åѹ¸Ö°åËÜÐÔÓ¦±ä±ÈrÖµµÄÔÚÏß¼ì²â¼¼Êõ, ¸ÖÌú, 2006, 41(11), 37-41. 17.ëÎÀÃñ, ÑîÆ½, ¾¼ÃÐÍÈ¡Ïòµç¹¤¸ÖµÄ¶¨Î»Óë·¢Õ¹, ÊÀ½ç¿Æ¼¼Ñо¿Óë·¢Õ¹, 2006, 28(6): 23-26. 18.Mao W, Li D, Yu Y, Influence of surface oxide films on elastic behaviors of straight screw dislocations parallel to the surface of pure aluminum, J. Material Science and Technology, vol. 23(3), 2007, 392-394. [ Last edited by ÄÉÃ×Äø·Û on 2009-5-27 at 06:36 ] |

3Â¥2009-05-27 06:34:25
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ÐÕÃû: ³ÂСÃ÷ µ¥Î»:ÖÐɽ´óѧ»¯Ñ§Ó뻯ѧ¹¤³ÌѧԺ ÁìÓò:¾§Ì幤³Ì Òµ¼¨(ÂÛÎÄ,׍ָµÈµÈ) 1) Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, ja-2008-089872. 2) Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold-interpenetration: (3,5)-connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2009, cg-2008-01308u. 3) Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Inorg. Chem. 2009, ic-2008-02446m. 4) A spin-frustrated complex, [FeIIFeIII(trans-1,4-cyclohexanedicarboxylate)1.5]¡Þ: Interplay between single-chain magnet behavior and magnetic ordering Zheng, Y.-Z.; Xue, W.; Zhang, W.-X.; Tong, M.-L.; Chen, X.-M., Grandjean, F.; Long, G. J.; Ng, S. W.; Panissod, P.; Drillon M., Inorg. Chem. 2009, 48, 2028¨C2042. 5) Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue, W.; Chen, X.-M., Dalton Trans. 2009, 1396-1406. 6) Syntheses, structures and sorption properties of two framework-isomeric porous copper-coordination polymers Xue, D.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., CrystEngComm 2009, 11, 183-188.. (2008) 7) Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Chen, X.-M., Zheng, S.-L. Inorg. Chem. 2008, 47, 11202¨C11211. 8) Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.; Chen, X.-M.; Cryst. Growth Des. 2008, 8, 4559-4563. 9) Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.; Chen, X.-M.; Cryst. Growth Des. 2008, 8, 3673¨C3679. 10) (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.; Chen, X.-M., CrystEngComm 2008, 10, 1770-1776. 11) Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.; Chen, X.-M., Ng, S.W. Chem. Commun. 2008, 4019¨C4021. 12) Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N.; Xue, W.; Zhang, W.-X.; Chen, X.-M., Chem. Mater. 2008, 20, 5345¨C5350. 13) Pentanuclear and heptanuclear metal helicates by self-assembly of d10 metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 7389-7395.. 14) Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F.; Zhang, Y.-B.; Cheng, X.-N.; Chen, X.-M., CrystEngComm 2008, 10, 753¨C758. 15) A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G.J., Inorg. Chem. 2008, 47, 4077-4087. 16) Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010¨C6017. 17) N¨¦el temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534¨C1538. 18) Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.; Chen, X.-M.; Wang, H.-Z., Chem. Commun. 2008, 1551-1553. 19) Porous metal-organic framework based on ¦Ì4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 1346-1351. (2007) 20) Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739. 21) Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology Hu, S.; Zhang, J.-P.; Tong, M.-L.; Chen, X.-M.; Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289. 22) A ¡°star¡± antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China) 23) From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.; Chen, X.-M., Inorg. Chem. 2007, 46, 6437-6443. 24) A tetracarboxylate¨Cbridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 1332-1336. 25) Unprecedented (3,9)-connected (42.6)3(46.621.89) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 980¨C983. 26) A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494¨C1498. 27) Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170. 28) In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M., Inorg. Chem. 2007, 46, 1135-1143. (2006) 29) Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 2739-2746. 30) A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.; Chen, X.-M., Dalton Trans. 2006, 5294-5303. 31) Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.; Chen, X.-M., Gao, S. Inorg. Chem. 2006, 45, 7069-7076. 32) Assembling ¡°magnetic nanowires¡± into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314. 33) The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]¥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.; Chen, X.-M., Chem. Commun. 2006, 3603-3605. 34) Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1684-1689. 35) Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate Huang, X.-C.; Li, D.; Chen, X.-M., CrystEngComm 2006, 8, 351-355. 36) One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1194-1198. 37) (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.; Chen, X.-M., Chem. Commun. 2006, 1689-1699. 38) Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559. 39) From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 519¨C523. 40) Coexistence of spin frustration and long-range magnetic ordering in a triangular CoII3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Chem. Commun. 2006, 165¨C167. (2005) 41) Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; and Chen, X.-M., Inorg. Chem. 2005, 44, 8285-8292. 42) Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Dalton Trans. 2005, 3681-3685. 43) Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163. 44) Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 1609-1616. 45) Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 4270-4275. 46) A solvothermally in-situ generated mixed-ligand approach for NLO-active metal¨Corganic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Inorg. Chem. 2005, 44, 4148-4149. 47) Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082. 48) Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2005, 44, 3146-3150. 49) Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2005, 2232¨C2234. 50) Copper(I) 1,2,4-triazolates and related complexes: Studies of the olvothermal ligand reactions, network topologies, and photoluminescence roperties Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506. 51) Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 695¨C700. 52) Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 617-622. 53) Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Chem. Commun. 2005, 1258¨C1260. (Hot Paper) 54) (Review Article) Metal-organic molecular architectures with 2,2¡¯-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545¨C565. 55) Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = GdIII or NdIII) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 559-565. 56) Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Dalton Trans. 2005, 424-426. (Hot Paper, Highlighted in Chemical Science) 57) Metallophilicity versus p-p interactions: Ligand-unsupported rgentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = CuI or AgI, L = tridentate ligand) Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Chem. Eur. J. 2005, 11, 552-561. http://ce.sysu.edu.cn/cxm/ [ Last edited by ÄÉÃ×Äø·Û on 2009-6-5 at 18:59 ] |
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