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Dr. Mohammad Omary
Associate Professor of Chemistry
University of North Texas
Department of Chemistry
NSF CAREER Award, 2004
I-APS Young Investigator Award, Inter-American Photochemical Society, 2006 Recepient
60. Omary, M. A.; Elbjeirami, O.; Palehepitiya Gamage, C. S.; Sherman, K.; Dias, H. V. R. "Phosphorescence Enhancement of Naphthalene-Sandwiched Trinuclear Silver(I) Complexes of 3,5-Bis(trifluoromethyl)pyrazolate", Inorg. Chem. 2009, 47, in press: DOI: 10.1021/ic8021326.PDF
59. Yang, C.; Wang, X.; Omary, M. A. "Crystallographic observation of the dynamic gas adsorption sites and thermal expansion in a breathable fluorous metal-organic framework", Angew. Chem. 2009, in press: DOI: 10.1002/anie.200804739: (JOURNAL COVER). PDF
58. Rabaa, H.; Cundari, T. R.; Omary, M. A. "Combined Tight Binding/DFT Investigation of the Electronic Structure of Triimine-Platinum(II)/TCNQ Extended Stacks: Theoretical Prediction of Metallic Behavior", Can. J. Chem. (special issue) 2008, in press: DOI: 10.1139/V08-175. INVITED ARTICLE. PDF
57. Elbjeirami, O.; Gonser, M. W. A.; Stewart, B. N.; Bruce, A. E.; Bruce, M. R. M.; Cundari, T. R.; Omary, M. A. "Luminescence, Structural, and Bonding Trends upon Varying the Halogen in Isostructural Aurophilic Dimers", Dalton Trans. 2008, in press: DOI: 10.1039/b81385c; (JOURNAL COVER). PDF
56. Quevedo-Lopez, M. A.; Alshareef, H. N.; Jia, H.; Bhansali, U.; Avendano, A.; Gnade, B. E.; Omary, M. A. "Organic Light Emitting Diodes for Flexible Electronics", Future FAB 2008, 26, 30-36. PDF
55. Tekarli, S. M.; Cundari, T. R.; Omary, M. A. "Rational Design of Macrometallocyclic Trinuclear Complexes with Superior p-Acidity and p-Basicity", J. Am. Chem. Soc. 2008, 130, 1669-1675. PDF
54. Taylor, T. J.; Elbjeirami, O.; Burress, C. N.; Tsunoda, M.; Bodine, M. I.; Omary, M. A.; Gabbai, F. P. "Complexation of tolane by fluorinated organomercurials - Structures and luminescence properties of an unusual class of supramolecular p-coordination polymers", J. Inorg. Organomet. Polym. 2008, 18, 175-179. PDF
53. Yang, C.; Wang, X.; Omary, M. A. "Fluorous Metal-Organic Frameworks for High-Density Gas Adsorption", J. Am. Chem. Soc. 2007, 129, 15454-15455. PDF HIGHLIGHTED IN: a) Angew. Chem. Int. Ed. 2008, 47, 8164-8164. b) THE E-JOURNAL "ENTREPRENEUR"; SEE: http://www.entrepreneur.com/tradejournals/article/177363186.html
52. Elbjeirami, O.; Omary, M. A. “Photochemistry of Neutral Isonitrile Gold(I) Complexes: Modulation of Photoreactivity by Aurophilicity and p-Acceptance Ability”, J. Am. Chem. Soc. 2007, available online. PDF
51. Arvapally, R. K.; Sinha, P.; Hettiarachchi, S. R.; Coker, N. L.; Bedel, C. E.; Patterson, H. H.; Elder, R. C.; Wilson, A. K.; Omary, M. A. “Photophysics of Bis(thiocyanato)gold(I) Complexes: Intriguing Structure-Luminescence Relationships”, J. Phys. Chem. C 2007, 111, 10689-10699. PDF
50. Elbjeirami, O.; Burress, C. N.; Gabbaï, F. P.; Omary, M. A. “Simultaneous External and Internal Heavy-Atom Effects in Binary Adducts of 1-Halonaphthalenes with Trinuclear Perfluoro-ortho-phenylene Mercury(II): A Structural and Photophysical Study”, J. Phys. Chem. C 2007, 111, 9522-9529. PDF
49. Omary, M. A.; Colis, J. C. F.; Larochelle, C. L.; Patterson, H. H. “Optical Memory and Multi-step Luminescence Thermochromism in Single Crystals of K2Na[Ag(CN)2]3”, Inorg. Chem. 2007, 46, 3798-3800. PDF
48. Elbjeirami, O.; Yockel, S.; Campana, C. F.; Wilson, A. K.; Omary, M. A. “Photophysics and Bonding in Neutral Gold(I) Organometallic Complexes with an Extended Aurophilic Supramolecular Structure”, Organometallics 2007, 26, 2550-2560. PDF
47. Burress, C. N.; Bodine, M. I.; Elbjeirami, O.; Reibenspies, J. H.; Omary, M. A.; Gabbaï, F. P. “Enhancement of External Spin-Orbit Coupling Effects Caused by Metal-Metal Cooperativity”, Inorg. Chem. 2007, 46, 1388-1395. PDF
46. Yang, C.; Messerschmidt, M.; Coppens, C.; Omary, M. A. “Trinuclear Gold(I) Triazolates: A New Class of Wide-Band Phosphors and Sensors”, Inorg. Chem. 2006, 45, 6592-6594. PDF
45. Barakat, K. A.; Cundari, T. R.; Rabaâ, H.; Omary, M. A. “Disproportionation of Gold(II) Complexes. A Density Functional Study of Ligand and Solvent Effects”, J. Phys. Chem. B 2006, 110, 14645-14651. PDF
44. Grimes, T.; Omary, M. A.; Dias, H. V. R.; Cundari, T. R. “Intertrimer and Intratrimer Metallophilic and Excimeric Bonding in the Ground and Phosphorescent Excited States of Trinuclear Coinage Metal Pyrazolates: A Computational Study”, J. Phys. Chem. A 2006, 110, 5823-5830. PDF
43. Chen, W. –H.; Reinheimer, E. W.; Dunbar, K. R.; Omary, M. A. “Coarse- and Fine-Tuning the Electronic Energies of Triimine Platinum (II) Square Planar Complexes”, Inorg. Chem. 2006, 45, 2770-2772. PDF
42. Sinha, P.; Wilson, A. K.; Omary, M. A. “Beyond a T-Shape”, J. Am. Chem. Soc. 2005, 127, 12488-12489. PDF
41. Omary, M. A.; Rawashdeh-Omary, M. A.; Gonser, M. W. A.; Elbjeirami, O.; Grimes, T.; Cundari, T. R.; Diyabalanage, H, V. K.; Palehepitiya Gamage, C. S.; Dias, H. V. R. “Metal Effect on the Supramolecular Structure, Photophysics, and Acid/Base Character of Trinuclear Pyrazolato Coinage Metal Complexes”, Inorg. Chem. 2005, 44, 8200-8210. PDF JOURNAL COVER; URL: http://pubs.acs.org/action/showLargeCover?issue=40364397
40. Burress, C.; Elbjeirami, O.; Omary, M. A.; Gabbaï, F. P. “Five-Order-of-Magnitude Reduction of the Triplet Lifetimes of N-Heterocycles by Complexation to a Trinuclear Mercury Complex”, J. Am. Chem. Soc. 2005, 127, 12166-12167. PDF
39. Mohamed, A. A.; Rawashdeh-Omary, M. A.; Omary, M. A.; Fackler, J. P., Jr. “External heavy-atom effect of gold in a supramolecular acid-base p stack” Dalton Trans. 2005, 2597–2602.
38. Vorontsov, I. I.; Kovalevsky, A. Yu.; Chen, Y-S.; Graber, T.; Novozhilova, I. V.; Omary, M. A.; Coppens, P. “Shedding Light on the Structure of a Photo-induced Transient Excimer by Time-resolved Diffraction” Phys. Rev. Lett. 2005, 94, 193003/1–193003/4.
37. Dias, H. V. R.; Diyabalanage, H. V. K.; Eldabaja, M. G.; Elbjeirami, O.; Rawashdeh-Omary, M. A.; Omary, M. A. “Brightly Phosphorescent Trinuclear Copper(I) Complexes of Pyrazolates: Substituent Effects on the Supramolecular Structure and Photophysics”, J. Am. Chem. Soc. 2005, 127, 7489-7501. PDF
36. Omary, M. A.; Sinha, P.; Bagus, P.S.; Wilson, A.K. “Electronic Structure of Mercury Oligomers and Exciplexes: Models for Long-range/Multi-center Bonding in Phosphorescent Transition Metal Compounds”, J. Phys. Chem. A 2005, 109, 690-702. PDF
35. Omary, M. A.; Mohamed, A. A.; Rawashdeh-Omary, M. A.; Fackler, J. P., Jr. “Photophysics of Supramolecular Binary Stacks Consisting of Electron-rich Trinuclear Au(I) Complexes and Organic Electrophiles” Coord. Chem. Rev. 2005, 249, 1372-1381.
34. Elbjeirami, O.; Omary, M. A.; Stender, M.; Balch, A. L. “Anomalous structure-luminescence relationship in phosphorescent gold(I) isonitrile neutral complexes” Dalton Trans. 2004, 3173 - 3175.
33. Omary, M. A.; Rawashdeh-Omary, M. A.; Diyabalanage, H. V. K.; Dias, H. V. R. “Blue Phosphors of Dinuclear and Mononuclear Copper (I) and Silver(I) Complexes of 3,5-Bis(trifluoromethyl)pyrazolate and the Related Bis(pyrazolyl)borate” Inorg. Chem. 2003, 42, 8612-8614. PDF
32. Hettiarachchi, S. R.; Patterson, H. H.; Omary, M. A. “"Write/Read/Erase" with Laser Irradiation of Dicyanoargentate(I) Doped and Pure Crystals” J. Phys. Chem. B 2003, 107, 14249-14254. PDF
31. Dunbar, K. R.; Schelter, E. J.; Palii, A. V.; Ostrovsky, S. M.; Mirovitskii, V. Y.; Hudson, J. M.; Omary, M. A.; Klokishner, S. I.; Tsukerblat, B. S. “Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature Independent Paramagnetism” J. Phys. Chem. A 2003, 107, 11102-11111. PDF
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