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姓名: 陈小明
单位:中山大学化学与化学工程学院
领域:晶体工程
业绩(论文,专著等等)
1)        Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, ja-2008-089872.
2)        Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold-interpenetration: (3,5)-connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2009, cg-2008-01308u.
3)        Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Inorg. Chem. 2009, ic-2008-02446m.
4)        A spin-frustrated complex, [FeIIFeIII(trans-1,4-cyclohexanedicarboxylate)1.5]∞: Interplay between single-chain magnet behavior and magnetic ordering
Zheng, Y.-Z.; Xue, W.; Zhang, W.-X.; Tong, M.-L.; Chen, X.-M., Grandjean, F.; Long, G. J.; Ng, S. W.; Panissod, P.; Drillon M., Inorg. Chem. 2009, 48, 2028–2042.
5)        Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue, W.; Chen, X.-M., Dalton Trans. 2009, 1396-1406.
6)        Syntheses, structures and sorption properties of two framework-isomeric porous copper-coordination polymers Xue, D.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., CrystEngComm 2009, 11, 183-188.. (2008)
7)        Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Chen, X.-M., Zheng, S.-L. Inorg. Chem. 2008, 47, 11202–11211.
8)        Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.; Chen, X.-M.; Cryst. Growth Des. 2008, 8, 4559-4563.
9)        Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.; Chen, X.-M.; Cryst. Growth Des. 2008, 8, 3673–3679.
10)     (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.; Chen, X.-M., CrystEngComm 2008, 10, 1770-1776.
11)     Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.; Chen, X.-M., Ng, S.W. Chem. Commun. 2008, 4019–4021.
12)     Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N.; Xue, W.; Zhang, W.-X.; Chen, X.-M., Chem. Mater. 2008, 20, 5345–5350.
13)     Pentanuclear and heptanuclear metal helicates by self-assembly of d10 metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 7389-7395..
14)     Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F.; Zhang, Y.-B.; Cheng, X.-N.; Chen, X.-M., CrystEngComm 2008, 10, 753–758.
15)     A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition
Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G.J., Inorg. Chem. 2008, 47, 4077-4087.
16)     Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017.
17)     Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538.
18)     Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.; Chen, X.-M.; Wang, H.-Z., Chem. Commun. 2008, 1551-1553.
19)     Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 1346-1351.
(2007)
20)     Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer  Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739.
21)     Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology Hu, S.; Zhang, J.-P.; Tong, M.-L.; Chen, X.-M.; Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289.
22)     A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China)
23)     From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.; Chen, X.-M., Inorg. Chem. 2007, 46, 6437-6443.
24)     A tetracarboxylate–bridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 1332-1336.
25)     Unprecedented (3,9)-connected (42.6)3(46.621.89) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 980–983.
26)     A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498.
27)     Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170.
28)     In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M., Inorg. Chem. 2007, 46, 1135-1143.
(2006)
29)     Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 2739-2746.
30)     A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.; Chen, X.-M., Dalton Trans. 2006, 5294-5303.
31)     Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.; Chen, X.-M., Gao, S. Inorg. Chem. 2006, 45, 7069-7076.
32)     Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314.
33)     The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]¥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.; Chen, X.-M., Chem. Commun. 2006, 3603-3605.
34)     Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1684-1689.
35)     Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate
Huang, X.-C.; Li, D.; Chen, X.-M., CrystEngComm 2006, 8, 351-355.
36)     One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1194-1198.
37)     (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.; Chen, X.-M., Chem. Commun. 2006, 1689-1699.
38)     Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559.  
39)     From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 519–523.  
40)     Coexistence of spin frustration and long-range magnetic ordering in a triangular CoII3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Chem. Commun. 2006, 165–167.  (2005)
41)     Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; and Chen, X.-M., Inorg. Chem. 2005, 44, 8285-8292.  
42)     Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Dalton Trans. 2005, 3681-3685.  
43)     Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163.  
44)     Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 1609-1616.  
45)     Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 4270-4275.  
46)     A solvothermally in-situ generated mixed-ligand approach for NLO-active metal–organic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Inorg. Chem. 2005, 44, 4148-4149.  
47)     Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082.  
48)     Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces
Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2005, 44, 3146-3150.  
49)     Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2005, 2232–2234.  
50)     Copper(I) 1,2,4-triazolates and related complexes: Studies of the olvothermal ligand reactions, network topologies, and photoluminescence roperties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506.  
51)     Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 695–700.  
52)     Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 617-622.
53)     Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Chem. Commun. 2005, 1258–1260. (Hot Paper)  
54)     (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565.  
55)     Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = GdIII or NdIII) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 559-565.  
56)     Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Dalton Trans. 2005, 424-426. (Hot Paper, Highlighted in Chemical Science)  
57)     Metallophilicity versus p-p interactions: Ligand-unsupported rgentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = CuI or AgI, L = tridentate ligand)  Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Chem. Eur. J. 2005, 11, 552-561.  
http://ce.sysu.edu.cn/cxm/

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