±±¾©Ê¯ÓÍ»¯¹¤Ñ§Ôº2026ÄêÑо¿ÉúÕÐÉú½ÓÊÕµ÷¼Á¹«¸æ
²é¿´: 291  |  »Ø¸´: 1

joeyphone

½ð³æ (СÓÐÃûÆø)

[ÇóÖú] Õâ¸ö´ÅÐÔÖÊÉó¸åÒâ¼ûÔõô´ð¸´

°ëÄêǰͶÁËÒ»·Ý¸å¼þ£¬»ØÀ´Éó¸åÒâ¼û£¬ÆäÖÐÖ÷Òª¶Ô´ÅÐÔÌá³öÁËÎÊÌ⣬¿´ÁËÁ½Ì죬²»ÖªµÀÔõô´ð¸´ºÏÊÊ£¬µ½ÕâÀïÇó´óÏÀ°ïÖúСÉúһϣ¬ÏÈÐÐллÀ²¡£
1 The decrease of the chi*T product by lowering the temperature (magnetic properties) is not due only to the eventual antiferromagnetic interactions between the Co(II) ions. It is well known that Co(II) is characterized by an important orbital contribution to the magnetic moment that leads to a similar behavior even in the absence of the exchange interactions.

2 The authors should mention in the magnetism studies how this system differs from the simple temperature dependent behaviour of high spin Co(II). Also they should state quite specifically what the red line fit is in figure 3 and how they derived it with values of this fitting. There should be a specific working out of the Weiss constant in the supporting information stating clearly how the values were obtained with graphs of the fit crossing the appropriate axes. If it is a simple straight line fitting and why did they stop at 25K and not all the way down to 2K? Also there is no mention of exchange coupling in the magnetism section. If antiferromagnetic coupling is mentioned then how does this occur? Are there literature precedents on similar ligand Cobalt systems which show the same behaviour? The magnetic behaviour looks very similar to simple temperature dependent high spin Co(II) behaviour and the authors should convince the reader that it is indeed different from just normal high spin Co(II).

Õâ¸ö´ÅÐÔÖÊÉó¸åÒâ¼ûÔõô´ð¸´
Fig. 3.JPG
»Ø¸´´ËÂ¥
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

joeyphone

½ð³æ (СÓÐÃûÆø)

×Ô¼º¶¥Ò»Ï£¬Òª³ÁÁË
2Â¥2015-08-09 15:15:40
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
Ïà¹Ø°æ¿éÌø×ª ÎÒÒª¶©ÔÄÂ¥Ö÷ joeyphone µÄÖ÷Ìâ¸üÐÂ
×î¾ßÈËÆøÈÈÌûÍÆ¼ö [²é¿´È«²¿] ×÷Õß »Ø/¿´ ×îºó·¢±í
[¿¼ÑÐ] 283·ÖÇóµ÷¼Á +10 ÊÔÊÔ¿´ß 2026-04-04 10/500 2026-04-06 23:08 by chenzhimin
[¿¼ÑÐ] ¿¼Ñе÷¼Á +7 15615482637 2026-04-04 7/350 2026-04-06 22:56 by chenzhimin
[¿¼ÑÐ] Ò»Ö¾Ô¸ÄϿƴóÉúÎïѧ297·Ö£¬Çóµ÷¼ÁÍÆ¼ö +6 Y-yyusx 2026-04-06 7/350 2026-04-06 22:39 by 52305043001
[¿¼ÑÐ] 312Çóµ÷¼Á +13 gtw1 2026-04-06 15/750 2026-04-06 20:25 by lijunpoly
[¿¼ÑÐ] 0854Çóµ÷¼Á +4 assdll 2026-04-05 4/200 2026-04-06 12:29 by ÖзÉÔº¿Õ¹ÜѧԺÑ
[¿¼ÑÐ] ÉúÎïѧÇóµ÷¼Á +5 15064154688 2026-04-03 5/250 2026-04-06 11:56 by lijunpoly
[¿¼ÑÐ] Çóµ÷¼Á +11 xzghyuj 2026-04-04 11/550 2026-04-06 11:49 by lijunpoly
[¿¼ÑÐ] Çóµ÷¼Á£¬Ò»Ö¾Ô¸Ö£ÖÝ´óѧ²ÄÁÏÓ뻯¹¤×¨Ë¶£¬Ó¢¶þÊý¶þ342·Ö£¬ÇóÀÏʦÊÕÁô +19 v12abo 2026-04-02 21/1050 2026-04-06 09:29 by À¶ÔÆË¼Óê
[¿¼ÑÐ] Ò»Ö¾Ô¸ÄϾ©º½¿Õº½Ìì´óѧ ²ÄÁÏÓ뻯¹¤329·ÖÇóµ÷¼Á +8 Mr. Z 2026-04-05 8/400 2026-04-06 09:24 by dongzh2009
[¿¼ÑÐ] »¯Ñ§µ÷¼Á +17 °¬Ö¾ºã 2026-04-03 18/900 2026-04-06 07:10 by jj987
[¿¼ÑÐ] 270Çóµ÷¼Á +9 С½Üpp 2026-03-31 11/550 2026-04-05 11:02 by ·çÓêÎÞÇç
[¿¼ÑÐ] 353Çóµ÷¼Á +10 MayUxw1 2026-04-03 10/500 2026-04-05 09:23 by Î޼ʵIJÝÔ­
[¿¼ÑÐ] 311·Ö 22408 Çóµ÷¼Á +3 bing_bot 2026-04-03 3/150 2026-04-05 00:43 by chongya
[¿¼ÑÐ] [µ÷¼ÁÐÅÏ¢]085408¹âµçÐÅÏ¢ Çóµ÷¼Á ×Ü·Ö291·ÖÊýÒ»Ó¢Ò» +3 iz11az 2026-04-02 3/150 2026-04-04 19:09 by À¶ÔÆË¼Óê
[¿¼ÑÐ] ±¾9Ò»Ö¾Ô¸2 0854µÍ·Öר˶286Çóµ÷¼Á +9 âÖÖ111 2026-04-04 9/450 2026-04-04 11:01 by tangruihua
[¿¼ÑÐ] 266Çóµ÷¼Á +8 ѧԱ97LZgn 2026-04-03 8/400 2026-04-04 09:02 by 20021109
[¿¼ÑÐ] 317·Ö Ò»Ö¾Ô¸½­ÄÏ´óѧ »¯Ñ§¹¤³Ìѧ˶ Çóµ÷¼Á +6 YinTai 2026-04-03 6/300 2026-04-03 22:30 by Î޼ʵIJÝÔ­
[¿¼ÑÐ] 289-Çóµ÷¼Á +4 ÕâÀïÊÇ_ 2026-04-03 4/200 2026-04-03 14:23 by 1753564080
[¿¼ÑÐ] 326Çóµ÷¼Á +10 áÌáÌ×Ð 2026-04-02 10/500 2026-04-03 09:08 by ÅÁ¶ûÂíÀ­ÌØ
[¿¼ÑÐ] µ÷¼Á +3 osbbx 2026-04-02 3/150 2026-04-03 07:47 by cc8418
ÐÅÏ¢Ìáʾ
ÇëÌî´¦ÀíÒâ¼û