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joeyphone金虫 (小有名气)
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[求助]
这个磁性质审稿意见怎么答复
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半年前投了一份稿件，回来审稿意见，其中主要对磁性提出了问题，看了两天，不知道怎么答复合适，到这里求大侠帮助小生一下，先行谢谢啦。 1 The decrease of the chi*T product by lowering the temperature (magnetic properties) is not due only to the eventual antiferromagnetic interactions between the Co(II) ions. It is well known that Co(II) is characterized by an important orbital contribution to the magnetic moment that leads to a similar behavior even in the absence of the exchange interactions. 2 The authors should mention in the magnetism studies how this system differs from the simple temperature dependent behaviour of high spin Co(II). Also they should state quite specifically what the red line fit is in figure 3 and how they derived it with values of this fitting. There should be a specific working out of the Weiss constant in the supporting information stating clearly how the values were obtained with graphs of the fit crossing the appropriate axes. If it is a simple straight line fitting and why did they stop at 25K and not all the way down to 2K? Also there is no mention of exchange coupling in the magnetism section. If antiferromagnetic coupling is mentioned then how does this occur? Are there literature precedents on similar ligand Cobalt systems which show the same behaviour? The magnetic behaviour looks very similar to simple temperature dependent high spin Co(II) behaviour and the authors should convince the reader that it is indeed different from just normal high spin Co(II).  Fig. 3.JPG |
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joeyphone
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