| 查看: 952 | 回复: 2 | |||
雷焕银虫 (小有名气)
|
[求助]
可能是什么物质？ 已有1人参与
|
|
由于接触波谱较少，解谱迷茫，先求助各大神能给予帮助，这些可能是哪些物质？非常感谢 4号 13C NMR (101 MHz, MeOD) δ 170.89 (s, 7H), 153.34 (s, 14H), 144.41 (s, 9H), 128.43 (s, 15H), 112.50 (s, 8H), 105.09 (s, 1H), 100.96 (s, 3H), 100.12 (s, 16H), 98.16 (s, 15H), 78.02 (s, 13H), 77.99 – 77.35 (m, 22H), 75.09 – 74.42 (m, 20H), 73.25 (s, 6H), 71.67 – 71.08 (m, 20H), 62.46 (d, J = 8.7 Hz, 21H), 61.27 (s, 16H), 57.33 (s, 1H), 55.49 (s, 3H), 49.87 (s, 1H), 49.74 (d, J = 20.6 Hz, 12H), 49.32 (d, J = 21.5 Hz, 43H), 49.03 (s, 7H), 49.03 (s, 19H), 49.07 – 48.52 (m, 94H), 48.57 (s, 14H), 48.47 (d, J = 21.5 Hz, 23H), 46.78 (s, 16H), 39.52 (s, 15H), 36.37 (s, 15H). 5号 13C NMR (101 MHz, MeOD) δ 150.78 (s, 2H), 148.91 (d, J = 26.6 Hz, 3H), 147.32 (t, J = 13.6 Hz, 3H), 137.35 (d, J = 9.5 Hz, 2H), 133.67 (s, 2H), 131.26 (s, 1H), 120.46 – 119.60 (m, 6H), 119.35 (s, 1H), 117.83 (s, 3H), 116.09 (s, 5H), 111.54 (d, J = 5.9 Hz, 3H), 110.97 (s, 3H), 110.53 (s, 1H), 102.68 (s, 3H), 88.92 (s, 1H), 87.36 (s, 3H), 86.98 (s, 2H), 83.43 (s, 1H), 78.04 (s, 4H), 77.69 (s, 5H), 74.80 (s, 5H), 72.60 (d, J = 4.8 Hz, 6H), 71.97 (s, 2H), 71.23 (s, 4H), 70.64 (s, 2H), 62.42 (s, 4H), 56.74 (s, 5H), 56.44 (s, 7H), 55.58 (s, 2H), 55.27 (d, J = 17.6 Hz, 5H), 51.12 (s, 1H), 49.64 (s, 5H), 49.47 (s, 2H), 49.32 (d, J = 21.5 Hz, 41H), 49.00 (s, 32H), 48.83 (s, 4H), 48.68 (d, J = 21.4 Hz, 38H), 48.36 (s, 5H). 6号 13C NMR (101 MHz, MeOD) δ 78.04 (s, 2H), 77.72 (s, 2H), 77.39 (s, 2H), 48.59 (s, 1H), 48.37 (s, 3H), 48.16 (s, 5H), 47.95 (s, 6H), 47.74 (s, 5H), 47.52 (s, 3H), 47.31 (s, 1H). 7号 13C NMR (101 MHz, MeOD) δ 105.51 (s, 1H), 104.56 (s, 2H), 101.22 (s, 3H), 99.68 (d, J = 5.4 Hz, 3H), 77.86 (s, 8H), 76.10 (s, 2H), 75.00 (s, 10H), 73.39 (d, J = 16.8 Hz, 14H), 71.80 (s, 5H), 71.46 (s, 9H), 69.79 (s, 1H), 67.28 (s, 2H), 62.40 (s, 10H), 57.63 (d, J = 9.2 Hz, 1H), 55.80 (s, 2H), 49.53 (d, J = 21.4 Hz, 15H), 49.42 – 49.40 (m, 4H), 49.12 (d, J = 17.4 Hz, 40H), 49.04 (s, 4H), 48.89 (d, J = 21.5 Hz, 63H), 48.61 (s, 3H), 48.47 (d, J = 21.4 Hz, 18H). 8号 13C NMR (101 MHz, MeOD) δ 196.26 (s, 1H), 156.30 (s, 1H), 126.69 (s, 1H), 125.16 (s, 2H), 116.66 (s, 2H), 112.18 (s, 1H), 56.50 (s, 1H), 49.64 (s, 9H), 49.42 (s, 31H), 49.21 (s, 32H), 49.00 (s, 51H), 48.79 (s, 33H), 48.57 (s, 18H), 48.36 (s, 7H). 再次感谢！ |
回复此楼» 猜你喜欢
269求调剂
已经有6人回复
-
297求调剂
已经有20人回复
-
297求调剂
已经有28人回复
-
267求调剂
已经有5人回复
-
考研调剂
已经有6人回复
-
314求调剂
已经有9人回复
-
285求调剂
已经有7人回复
-
一志愿矿大，材料工程专硕314分，0856可调都可以
已经有10人回复
-
还有化工二轮调剂的学校吗
已经有31人回复
-
一志愿211 0703化学 346分求调剂
已经有15人回复
» 本主题相关价值贴推荐，对您同样有帮助:
- 什么物质可以吸收反应溶剂中生成的甲醇
已经有15人回复
- 谁能告诉我热重分析700度左右这个失重是什么物质
已经有18人回复
- 这个物质在沸水中会发生水解吗？水解生成物会是什么？
已经有4人回复
- 哪里可以查询物质的基本理化性质？
已经有3人回复
- 加入什么物质能降低烷烃的沸点
已经有7人回复
- 有没有各个HPLC检测器能用来检测什么物质的详细介绍的资料
已经有4人回复
- XRD无法检测出物质的原因是什么？
已经有21人回复
- 同一个物质GC标准品和HPLC标准品的区别是什么？是否能通用？
已经有5人回复
- 百合花中醇提出来的物质在350nm左右有吸收峰，这是什么物质？
已经有11人回复
- GC-MS的图谱可以看出相对含量么？可以确定大概是什么物质吧？？？
已经有15人回复
- 什么物质可以使钾离子或钠离子显示呀？
已经有6人回复
- 什么样的两种物质或者是多种物质能形成共沸混合物？形成共沸混合物的条件是什么？
已经有9人回复
- 分子量相差113或44是哪一类物质？
已经有18人回复
- 红外光谱能测量混合物（液体）中各物质的含量吗？
已经有11人回复
- 用钯碳还原后有三种物质 求解可能是什么
已经有8人回复
- 有什么物质从水中结晶出来反而不能溶于水？
已经有20人回复
- 二甲苯能与什么物质常温下反应
已经有8人回复
- 有颜色的物质在紫外会有吸收峰吗
已经有10人回复
- 能量究竟是一种什么物质？
已经有87人回复
- 【求助】药物合成实验室，这可能是什么物质的味道？
已经有19人回复
- 【求助】紫外扫描360nm处出峰的可能是什么物质
已经有4人回复
- 【求助】紫外灯下呈橘红色荧光的是什么物质
已经有13人回复
seuseasoar
至尊木虫 (知名作家)
- 应助: 2238 (讲师)
- 金币: 48419.9
- 红花: 52
- 帖子: 6747
- 在线: 546.4小时
- 虫号: 2400995
- 注册: 2013-04-01
- 性别: MM
- 专业: 食品科学基础
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
雷焕: 金币+20, ★★★很有帮助, 非常感谢！ 2015-03-28 16:41:50
感谢参与，应助指数 +1
雷焕: 金币+20, ★★★很有帮助, 非常感谢！ 2015-03-28 16:41:50
|
44 1 . genameside C C23H34O15 相似度:57.1% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . 10,6'-di-O-(1-methoxy-1-methylethyl)-geniposide C25H40O12 相似度:57.1% Journal of Natural Products 1999 62 1646-1654 Stereoselective Hydrogenation and Ozonolysis of Iridoids. Conversion into Carbocyclic Nucleoside Analogues Henrik Franzyk, and Frank R. Stermitz Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . Genipin 1-O-β-D-isomaltoside C23H34O15 相似度:57.1% Phytochemistry 2009 70 779-784 Iridoid glycosides from Gardeniae Fructus for treatment of ankle sprain Quan Cheng Chen, Wei Yun Zhang, UiJoung Youn, HongJin Kim, IkSoo Lee, Hyun-Ju Jung, MinKyun Na, Byung-Sun Min, KiHwan Bae Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . genipin-gentiobioside 相似度:57.1% Journal of Chinese Medicinal Materials 2012 35 1950-1952 Study on the Chemical Constituents of Fructus Gardeniae HUANG Tao, MU Shu-zhen, HAO Xiao-jiang Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . genipin-gentiobioside 相似度:57.1% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . genameside C 相似度:57.1% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . 6''-O-trans-Sinapoylgenipin gentiobioside C34H44O19 相似度:57.1% Chemical & Pharmaceutical Bulletin 2011 59 803-833 Naturally Occurring Iridoids and Secoiridoids. An Updated Review, Part 4 Biswanath DINDA, Sudhan DEBNATH, and Rajarshi BANIK Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . scyphiphorins B C26H38O12 相似度:53.5% Helvetica Chimica Acta 2007 Vol. 90 1718 Scyphiphorins A and B, Two New Iridoid Glycosides from the Stem Bark of a Chinese Mangrove Scyphiphora hydrophyllacea Shu-Hong Tao, Jun Wu, Shu-Hua Qi, Si Zhang, Min-Yi Li, and Qing-Xin Li Structure 13C NMR Structure & 13C NMR 碳谱模拟图 55 1 . Mananthoside K C36H44O15 相似度:57.8% Journal of Asian Natural Products Research 2008 10 228-232 Three new lignan glycosides from Mananthes patentiflora Jun-Mian Tian, Hong-Ping He, Ying-Tong Di, Xian-Wen Yang, Zhu-Lin Gao and Xiao-Jiang Hao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . zanthpodocarpin E C41H40O15 相似度:56.0% Bioorganic & Medicinal Chemistry Letters 2014 24 4667-4671 Characterization and biological evaluation of six new dimeric lignans with an unusual α,β-unsaturated ketone motif from Zanthoxylum simulans Jun-Feng Wang, Yi-Hui Deng, Sheng-Hui Yang, Yan-Qun Liu, Yue-Hu Wang, Wei-Wei Pan, Xiao-Jiang Zhou Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . pinoresinol O-[6-O-(E)-caffeoyl]-β-D-glucopyranoside C35H38O14 相似度:55.2% Chemical & Pharmaceutical Bulletin 2002 50(5) 583-589 Studies on the Constituents from the Aerial Part of Baccharis dracunculifolia DC. II Yoshimi NAGATANI, Tsutomu WARASHINA, and Tadataka NORO Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . (+)-pinoresinol 4'-O-β-D-glucopyranosyl(1→2)-O-[β-D-glucopyranosyl(1→6)]-β-D-glucopyranoside 相似度:55.2% Heterocycles 1993 36 933-936 Structure of Novel Antioxidative Lignan Triglucoside Isolated from Sesame Seed Hirotaka Katsuzaki, Shunro Kawakishi, and Toshihiko Osawa Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . samsesquinoside C37H46O16 相似度:55.2% Fitoterapia 2014 94 29-35 New lignans from the bioactive fraction of Sambucus williamsii Hance and proliferation activities on osteoblastic-like UMR106 cells Hui-hui Xiao, Yi Dai, Man-sau Wong, Xin-sheng Yao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . compound 1 C36H40O14 相似度:55.2% Journal of Agricultural and Food Chemistry 2007 55 6460-6465 Inhibitory Activity against Tobacco Mosaic Virus (TMV) Replication of Pinoresinol and Syringaresinol Lignans and Their Glycosides from the Root of Rhus javanica var. roxburghiana Ming-An Ouyang, Yung-Shung Wein, Zhen-Kun Zhang, and Yueh-Hsiung Kuo Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . dracunculifoside R C36H44O15 相似度:52.6% Chemical & Pharmaceutical Bulletin 2002 50(5) 583-589 Studies on the Constituents from the Aerial Part of Baccharis dracunculifolia DC. II Yoshimi NAGATANI, Tsutomu WARASHINA, and Tadataka NORO Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . incanoside D C37H50O20 相似度:52.6% Chemical & Pharmaceutical Bulletin 2000 48(7) 1075-1078 Three New Phenylethanoid Glycosides from Caryopteris incana and Their Antioxidative Activity JianJun GAO,Kiharu IGARASHI,and Manabu NUKINA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . chionoside B C36H48O20 相似度:52.6% Chemical & Pharmaceutical Bulletin 2010 58 703-711 Phenylethanoid and Iridoid Glycosides in the New Zealand Snow Hebes (Veronica, Plantaginaceae) Rilka M. Taskova, Tetsuo Kokubun, Ken G. Ryan, Phil John Garnock-Jones and Soren Rosendal Jensen Structure 13C NMR Structure & 13C NMR 碳谱模拟图 |
2楼2015-03-28 12:19:52
seuseasoar
至尊木虫 (知名作家)
- 应助: 2238 (讲师)
- 金币: 48419.9
- 红花: 52
- 帖子: 6747
- 在线: 546.4小时
- 虫号: 2400995
- 注册: 2013-04-01
- 性别: MM
- 专业: 食品科学基础
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
雷焕: 金币+30, ★★★很有帮助, 非常感谢！ 2015-03-28 16:42:08
雷焕: 金币+30, ★★★很有帮助, 非常感谢！ 2015-03-28 16:42:08
|
66 1 . compound 5 C6H13N2O2PS 相似度:50% Tetrahedron Letters 2000 41 3073-3076 Alkylthiylation of triquinphosphoranes by disulfides: an entry to chiral thiatriquinphosphoranes Caroline Marchi, Gérard Buono Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . (3R,4S,5R)-5-amino-1-(tert-butoxycarbonyl)-3,4-dihydroxypiperidine C10H20O4N2 相似度:50% European Journal of Organic Chemistry 2011 2230-2234 Concise Route to (–)- and (+)-Aphanorphine Mohamed Medjahdi, José C. González-Gómez, Francisco Foubelo and Miguel Yus Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . compound 39 相似度:50% European Journal of Organic Chemistry 2010 5263-5273 An Anomeric Effect Drives the Regiospecific Ring-Opening of 1,3-Oxazolidines under Acetylating Conditions R. Fernando Martínez, Martín ávalos, Reyes Babiano, Pedro Cintas, José L. Jiménez, Mark E. Light, Juan C. Palacios and Esther M. S. Pérez Structure 13C NMR Structure & 13C NMR 碳谱模拟图 77 1 . compound 5 相似度:59.0% Magnetic Resonance in Chemistry 1993 31 599-605 1H and 13C NMR data for 2-O-, 3-O-and 2,3-di-O-glycosylated methyl α-and β-D-galactopyranosides Alexander S. Shashkov, Nikolay E. Nifant'ev, Vera Yu. Amochaeva and Nikolay K. Kochetkov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . 2,6-dimethoxy-4[(1E)-prop-1-enyl]phenyl O-α-L-rhamnopyranosyl-(1→6)-β-D-glucopyranoside C23H34O12 相似度:54.5% Helvetica Chimica Acta 2006 Vol. 89 884 Study on the Chemical Constituents of Daphniphyllum angustifolium Haiyun Bai and Lihong Hu Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . rhyncoside D C21H32O13 相似度:54.5% Chemical & Pharmaceutical Bulletin 2007 55(8) 1175-1180 Rhyncosides A—F, Phenolic Constituents from the Chinese Mangrove Plant Bruguiera sexangula var. rhynchopetala Shuyun BAO,Yi DING,Zhiwei DENG,Peter PROKSCH,d an Wenhan LIN Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . methyl gentiobioside 相似度:54.5% Chemical & Pharmaceutical Bulletin 1989 37 2727-2730 Two New Triterpenoid Glycosides from the Leaves of Schefflera octophylla Junichi KITAJIMA and Yasuko TANAKA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . 6'-O-β-D-Glucopyranosyltheviridoside C23H34O16 相似度:54.5% Phytochemistry 1995 38 793-794 Minor iridoids from Thevetia peruviana Fumiko Abe, Tatsuo Yamauchi, Shoji Yahara, Toshihiro Nohara Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . 5-O-Allosylantirrinoside 相似度:54.5% Phytochemistry 1993 32 1068-1070 5-O-Allosylantirrinoside from Linaria species Emilia Ilieva, Nedjalka Handjieva, Stefan Spassov, Simeon Popov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . 3-O-[β-D-glucopyranosyl (1→3)-α-L-rhamnopyranosyl (1→4)-β-D-xylopyranosyl] hederagenin 相似度:54.5% Turkish Journal of Chemistry 2002 26 947-954 New Triterpenic Saponins from Cephalaria transsylvanica SüHEYLA KIRMIZIGüL, HüSEYİN ANIL Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . compound 2 相似度:54.5% Canadian Journal of Chemistry 1990 68 1238-1250 NMR and conformational study of branched oligosaccharides containing 2,3-disubstituted residues of α-L-rhamnose Grigory M. Lipkind, Nikolay E. Nifant'ev, Alexander S. Shashkov, Nikolay K. Kochetkov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . 8-methoxycarbonyloctyl O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1→2)-O-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→2)-3,4-di-O-benzyl-α-L-rhamnopyranoside C58H77NO16 相似度:54.5% Canadian Journal of Chemistry 1979 57 3073-3079 Artificial carbohydrate antigens: the synthesis of the tetrasaccharide repeating unit of Shigella flexneri O antigen Staffan Josephson, David R. Bundle Structure 13C NMR Structure & 13C NMR 碳谱模拟图 88 1 . ferulaldehyde C10H10O3 相似度:50% Chemistry of Natural Compounds 2009 45 234-236 MONO-AROMATIC CONSTITUENTSOF Dendrobium longicornu Jiang-Tao Li, Ben-Lin Yin, Ying Liu, Li-Qin Wang, and Ye-Gao Chen Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . Coniferaldehyde 相似度:50% Korean Journal of Pharmacognosy 2009 40(4) 326-333 Phytochemical Studies on Lonicera Caulis (2) - Aliphatic and Phenolic Compounds Kim, Ju-Sun; Yean, Min-Hye; Seo, Hyun-Kyu; Lee, Je-Hyun; Kang, Sam-Sik Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . acetovanillone 相似度:50% Chinese Traditional and Herbal Drugs 2005 36 1604-1607 Effect of phenolic acids isolated from Sambucus williamsii on proliferation and differentiation of rat osteoblastic UMR106 cells YANG Xu-juan; WONG Man-sau; WANG Nai-li; CHAN Sun-chi; YAO Xin-sheng Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . coniferyl aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2011 42 437-439 Chemical constituents of Opuntia milpa (I) LUO Chuan, ZHANG Wan-nian Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . coniferyl aldehyde C11H11O3 相似度:50% Natural Product Research and Development 2014 26 1780-1784 Chemical Constituents from the Fruits of Capparis masaikai LIAO Jin-hua, HU Xu-jia*, YUAN Chun-mao, HE Hong-ping, DI Ying-tong Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . 4-Phenylphenol 相似度:50% Molecules 2012 17 12121-12139 Suzuki-Miyaura Reactions Catalyzed by C2-Symmetric Pd-Multi-Dentate N-Heterocyclic Carbene Complexes Lan Jiang, Fengjun Shan, Zhengning Li and Defeng Zhao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . coniferyl aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2012 43 2346-2350 Chemical constituents from fruits of Vitex negundo ZHAO Xiang-xiang; ZHENG Cheng-jian; QIN Lu-ping Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . 2-羟基-5-甲氧基-苯丙烯醛 相似度:50% China Journal of Chinese Materia Medica 2012 37 2092-2099 Non-anthraquinones constituents from the roots of Knoxia valerianoides ZHAO Feng; WANG Sujuan; WU Xiuli; YU Yang; YUE Zhenggang; LIU Bo; LIN Sheng; ZHU Chenggen; YANG Yongchun; SHI Jiangong Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . coniferaldehyde 相似度:50% Journal of the Korean Society for Applied Biological Chemistry 2012 55 433-437 Cytotoxic Compounds from the Fruits of Vitex rotundifolia against Human Cancer Cell Lines Haejin Kim, Jin-Mu Yi, No Soo Kim, You Jin Lee, Jinhee Kim, Dal-Seok Oh, Se-Mi Oh, Ok-Sun Bang, Jun Lee Structure 13C NMR Structure & 13C NMR 碳谱模拟图 10 . aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2014 45 1373-1377 Chemical constituents from Gnaphlium affine LI Sheng-hua Structure 13C NMR Structure & 13C NMR 碳谱模拟图 |
3楼2015-03-28 12:27:44
