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雷焕银虫 (小有名气)
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[求助]
可能是什么物质？ 已有1人参与
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由于接触波谱较少，解谱迷茫，先求助各大神能给予帮助，这些可能是哪些物质？非常感谢 4号 13C NMR (101 MHz, MeOD) δ 170.89 (s, 7H), 153.34 (s, 14H), 144.41 (s, 9H), 128.43 (s, 15H), 112.50 (s, 8H), 105.09 (s, 1H), 100.96 (s, 3H), 100.12 (s, 16H), 98.16 (s, 15H), 78.02 (s, 13H), 77.99 – 77.35 (m, 22H), 75.09 – 74.42 (m, 20H), 73.25 (s, 6H), 71.67 – 71.08 (m, 20H), 62.46 (d, J = 8.7 Hz, 21H), 61.27 (s, 16H), 57.33 (s, 1H), 55.49 (s, 3H), 49.87 (s, 1H), 49.74 (d, J = 20.6 Hz, 12H), 49.32 (d, J = 21.5 Hz, 43H), 49.03 (s, 7H), 49.03 (s, 19H), 49.07 – 48.52 (m, 94H), 48.57 (s, 14H), 48.47 (d, J = 21.5 Hz, 23H), 46.78 (s, 16H), 39.52 (s, 15H), 36.37 (s, 15H). 5号 13C NMR (101 MHz, MeOD) δ 150.78 (s, 2H), 148.91 (d, J = 26.6 Hz, 3H), 147.32 (t, J = 13.6 Hz, 3H), 137.35 (d, J = 9.5 Hz, 2H), 133.67 (s, 2H), 131.26 (s, 1H), 120.46 – 119.60 (m, 6H), 119.35 (s, 1H), 117.83 (s, 3H), 116.09 (s, 5H), 111.54 (d, J = 5.9 Hz, 3H), 110.97 (s, 3H), 110.53 (s, 1H), 102.68 (s, 3H), 88.92 (s, 1H), 87.36 (s, 3H), 86.98 (s, 2H), 83.43 (s, 1H), 78.04 (s, 4H), 77.69 (s, 5H), 74.80 (s, 5H), 72.60 (d, J = 4.8 Hz, 6H), 71.97 (s, 2H), 71.23 (s, 4H), 70.64 (s, 2H), 62.42 (s, 4H), 56.74 (s, 5H), 56.44 (s, 7H), 55.58 (s, 2H), 55.27 (d, J = 17.6 Hz, 5H), 51.12 (s, 1H), 49.64 (s, 5H), 49.47 (s, 2H), 49.32 (d, J = 21.5 Hz, 41H), 49.00 (s, 32H), 48.83 (s, 4H), 48.68 (d, J = 21.4 Hz, 38H), 48.36 (s, 5H). 6号 13C NMR (101 MHz, MeOD) δ 78.04 (s, 2H), 77.72 (s, 2H), 77.39 (s, 2H), 48.59 (s, 1H), 48.37 (s, 3H), 48.16 (s, 5H), 47.95 (s, 6H), 47.74 (s, 5H), 47.52 (s, 3H), 47.31 (s, 1H). 7号 13C NMR (101 MHz, MeOD) δ 105.51 (s, 1H), 104.56 (s, 2H), 101.22 (s, 3H), 99.68 (d, J = 5.4 Hz, 3H), 77.86 (s, 8H), 76.10 (s, 2H), 75.00 (s, 10H), 73.39 (d, J = 16.8 Hz, 14H), 71.80 (s, 5H), 71.46 (s, 9H), 69.79 (s, 1H), 67.28 (s, 2H), 62.40 (s, 10H), 57.63 (d, J = 9.2 Hz, 1H), 55.80 (s, 2H), 49.53 (d, J = 21.4 Hz, 15H), 49.42 – 49.40 (m, 4H), 49.12 (d, J = 17.4 Hz, 40H), 49.04 (s, 4H), 48.89 (d, J = 21.5 Hz, 63H), 48.61 (s, 3H), 48.47 (d, J = 21.4 Hz, 18H). 8号 13C NMR (101 MHz, MeOD) δ 196.26 (s, 1H), 156.30 (s, 1H), 126.69 (s, 1H), 125.16 (s, 2H), 116.66 (s, 2H), 112.18 (s, 1H), 56.50 (s, 1H), 49.64 (s, 9H), 49.42 (s, 31H), 49.21 (s, 32H), 49.00 (s, 51H), 48.79 (s, 33H), 48.57 (s, 18H), 48.36 (s, 7H). 再次感谢！ |
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seuseasoar
至尊木虫 (知名作家)
- 应助: 2238 (讲师)
- 金币: 48419.9
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- 专业: 食品科学基础
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
雷焕: 金币+20, ★★★很有帮助, 非常感谢！ 2015-03-28 16:41:50
感谢参与，应助指数 +1
雷焕: 金币+20, ★★★很有帮助, 非常感谢！ 2015-03-28 16:41:50
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44 1 . genameside C C23H34O15 相似度:57.1% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . 10,6'-di-O-(1-methoxy-1-methylethyl)-geniposide C25H40O12 相似度:57.1% Journal of Natural Products 1999 62 1646-1654 Stereoselective Hydrogenation and Ozonolysis of Iridoids. Conversion into Carbocyclic Nucleoside Analogues Henrik Franzyk, and Frank R. Stermitz Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . Genipin 1-O-β-D-isomaltoside C23H34O15 相似度:57.1% Phytochemistry 2009 70 779-784 Iridoid glycosides from Gardeniae Fructus for treatment of ankle sprain Quan Cheng Chen, Wei Yun Zhang, UiJoung Youn, HongJin Kim, IkSoo Lee, Hyun-Ju Jung, MinKyun Na, Byung-Sun Min, KiHwan Bae Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . genipin-gentiobioside 相似度:57.1% Journal of Chinese Medicinal Materials 2012 35 1950-1952 Study on the Chemical Constituents of Fructus Gardeniae HUANG Tao, MU Shu-zhen, HAO Xiao-jiang Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . genipin-gentiobioside 相似度:57.1% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . genameside C 相似度:57.1% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . 6''-O-trans-Sinapoylgenipin gentiobioside C34H44O19 相似度:57.1% Chemical & Pharmaceutical Bulletin 2011 59 803-833 Naturally Occurring Iridoids and Secoiridoids. An Updated Review, Part 4 Biswanath DINDA, Sudhan DEBNATH, and Rajarshi BANIK Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . scyphiphorins B C26H38O12 相似度:53.5% Helvetica Chimica Acta 2007 Vol. 90 1718 Scyphiphorins A and B, Two New Iridoid Glycosides from the Stem Bark of a Chinese Mangrove Scyphiphora hydrophyllacea Shu-Hong Tao, Jun Wu, Shu-Hua Qi, Si Zhang, Min-Yi Li, and Qing-Xin Li Structure 13C NMR Structure & 13C NMR 碳谱模拟图 55 1 . Mananthoside K C36H44O15 相似度:57.8% Journal of Asian Natural Products Research 2008 10 228-232 Three new lignan glycosides from Mananthes patentiflora Jun-Mian Tian, Hong-Ping He, Ying-Tong Di, Xian-Wen Yang, Zhu-Lin Gao and Xiao-Jiang Hao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . zanthpodocarpin E C41H40O15 相似度:56.0% Bioorganic & Medicinal Chemistry Letters 2014 24 4667-4671 Characterization and biological evaluation of six new dimeric lignans with an unusual α,β-unsaturated ketone motif from Zanthoxylum simulans Jun-Feng Wang, Yi-Hui Deng, Sheng-Hui Yang, Yan-Qun Liu, Yue-Hu Wang, Wei-Wei Pan, Xiao-Jiang Zhou Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . pinoresinol O-[6-O-(E)-caffeoyl]-β-D-glucopyranoside C35H38O14 相似度:55.2% Chemical & Pharmaceutical Bulletin 2002 50(5) 583-589 Studies on the Constituents from the Aerial Part of Baccharis dracunculifolia DC. II Yoshimi NAGATANI, Tsutomu WARASHINA, and Tadataka NORO Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . (+)-pinoresinol 4'-O-β-D-glucopyranosyl(1→2)-O-[β-D-glucopyranosyl(1→6)]-β-D-glucopyranoside 相似度:55.2% Heterocycles 1993 36 933-936 Structure of Novel Antioxidative Lignan Triglucoside Isolated from Sesame Seed Hirotaka Katsuzaki, Shunro Kawakishi, and Toshihiko Osawa Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . samsesquinoside C37H46O16 相似度:55.2% Fitoterapia 2014 94 29-35 New lignans from the bioactive fraction of Sambucus williamsii Hance and proliferation activities on osteoblastic-like UMR106 cells Hui-hui Xiao, Yi Dai, Man-sau Wong, Xin-sheng Yao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . compound 1 C36H40O14 相似度:55.2% Journal of Agricultural and Food Chemistry 2007 55 6460-6465 Inhibitory Activity against Tobacco Mosaic Virus (TMV) Replication of Pinoresinol and Syringaresinol Lignans and Their Glycosides from the Root of Rhus javanica var. roxburghiana Ming-An Ouyang, Yung-Shung Wein, Zhen-Kun Zhang, and Yueh-Hsiung Kuo Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . dracunculifoside R C36H44O15 相似度:52.6% Chemical & Pharmaceutical Bulletin 2002 50(5) 583-589 Studies on the Constituents from the Aerial Part of Baccharis dracunculifolia DC. II Yoshimi NAGATANI, Tsutomu WARASHINA, and Tadataka NORO Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . incanoside D C37H50O20 相似度:52.6% Chemical & Pharmaceutical Bulletin 2000 48(7) 1075-1078 Three New Phenylethanoid Glycosides from Caryopteris incana and Their Antioxidative Activity JianJun GAO,Kiharu IGARASHI,and Manabu NUKINA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . chionoside B C36H48O20 相似度:52.6% Chemical & Pharmaceutical Bulletin 2010 58 703-711 Phenylethanoid and Iridoid Glycosides in the New Zealand Snow Hebes (Veronica, Plantaginaceae) Rilka M. Taskova, Tetsuo Kokubun, Ken G. Ryan, Phil John Garnock-Jones and Soren Rosendal Jensen Structure 13C NMR Structure & 13C NMR 碳谱模拟图 |
2楼2015-03-28 12:19:52
seuseasoar
至尊木虫 (知名作家)
- 应助: 2238 (讲师)
- 金币: 48419.9
- 红花: 52
- 帖子: 6747
- 在线: 546.4小时
- 虫号: 2400995
- 注册: 2013-04-01
- 性别: MM
- 专业: 食品科学基础
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
雷焕: 金币+30, ★★★很有帮助, 非常感谢！ 2015-03-28 16:42:08
雷焕: 金币+30, ★★★很有帮助, 非常感谢！ 2015-03-28 16:42:08
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66 1 . compound 5 C6H13N2O2PS 相似度:50% Tetrahedron Letters 2000 41 3073-3076 Alkylthiylation of triquinphosphoranes by disulfides: an entry to chiral thiatriquinphosphoranes Caroline Marchi, Gérard Buono Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . (3R,4S,5R)-5-amino-1-(tert-butoxycarbonyl)-3,4-dihydroxypiperidine C10H20O4N2 相似度:50% European Journal of Organic Chemistry 2011 2230-2234 Concise Route to (–)- and (+)-Aphanorphine Mohamed Medjahdi, José C. González-Gómez, Francisco Foubelo and Miguel Yus Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . compound 39 相似度:50% European Journal of Organic Chemistry 2010 5263-5273 An Anomeric Effect Drives the Regiospecific Ring-Opening of 1,3-Oxazolidines under Acetylating Conditions R. Fernando Martínez, Martín ávalos, Reyes Babiano, Pedro Cintas, José L. Jiménez, Mark E. Light, Juan C. Palacios and Esther M. S. Pérez Structure 13C NMR Structure & 13C NMR 碳谱模拟图 77 1 . compound 5 相似度:59.0% Magnetic Resonance in Chemistry 1993 31 599-605 1H and 13C NMR data for 2-O-, 3-O-and 2,3-di-O-glycosylated methyl α-and β-D-galactopyranosides Alexander S. Shashkov, Nikolay E. Nifant'ev, Vera Yu. Amochaeva and Nikolay K. Kochetkov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . 2,6-dimethoxy-4[(1E)-prop-1-enyl]phenyl O-α-L-rhamnopyranosyl-(1→6)-β-D-glucopyranoside C23H34O12 相似度:54.5% Helvetica Chimica Acta 2006 Vol. 89 884 Study on the Chemical Constituents of Daphniphyllum angustifolium Haiyun Bai and Lihong Hu Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . rhyncoside D C21H32O13 相似度:54.5% Chemical & Pharmaceutical Bulletin 2007 55(8) 1175-1180 Rhyncosides A—F, Phenolic Constituents from the Chinese Mangrove Plant Bruguiera sexangula var. rhynchopetala Shuyun BAO,Yi DING,Zhiwei DENG,Peter PROKSCH,d an Wenhan LIN Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . methyl gentiobioside 相似度:54.5% Chemical & Pharmaceutical Bulletin 1989 37 2727-2730 Two New Triterpenoid Glycosides from the Leaves of Schefflera octophylla Junichi KITAJIMA and Yasuko TANAKA Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . 6'-O-β-D-Glucopyranosyltheviridoside C23H34O16 相似度:54.5% Phytochemistry 1995 38 793-794 Minor iridoids from Thevetia peruviana Fumiko Abe, Tatsuo Yamauchi, Shoji Yahara, Toshihiro Nohara Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . 5-O-Allosylantirrinoside 相似度:54.5% Phytochemistry 1993 32 1068-1070 5-O-Allosylantirrinoside from Linaria species Emilia Ilieva, Nedjalka Handjieva, Stefan Spassov, Simeon Popov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . 3-O-[β-D-glucopyranosyl (1→3)-α-L-rhamnopyranosyl (1→4)-β-D-xylopyranosyl] hederagenin 相似度:54.5% Turkish Journal of Chemistry 2002 26 947-954 New Triterpenic Saponins from Cephalaria transsylvanica SüHEYLA KIRMIZIGüL, HüSEYİN ANIL Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . compound 2 相似度:54.5% Canadian Journal of Chemistry 1990 68 1238-1250 NMR and conformational study of branched oligosaccharides containing 2,3-disubstituted residues of α-L-rhamnose Grigory M. Lipkind, Nikolay E. Nifant'ev, Alexander S. Shashkov, Nikolay K. Kochetkov Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . 8-methoxycarbonyloctyl O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1→2)-O-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→2)-3,4-di-O-benzyl-α-L-rhamnopyranoside C58H77NO16 相似度:54.5% Canadian Journal of Chemistry 1979 57 3073-3079 Artificial carbohydrate antigens: the synthesis of the tetrasaccharide repeating unit of Shigella flexneri O antigen Staffan Josephson, David R. Bundle Structure 13C NMR Structure & 13C NMR 碳谱模拟图 88 1 . ferulaldehyde C10H10O3 相似度:50% Chemistry of Natural Compounds 2009 45 234-236 MONO-AROMATIC CONSTITUENTSOF Dendrobium longicornu Jiang-Tao Li, Ben-Lin Yin, Ying Liu, Li-Qin Wang, and Ye-Gao Chen Structure 13C NMR Structure & 13C NMR 碳谱模拟图 2 . Coniferaldehyde 相似度:50% Korean Journal of Pharmacognosy 2009 40(4) 326-333 Phytochemical Studies on Lonicera Caulis (2) - Aliphatic and Phenolic Compounds Kim, Ju-Sun; Yean, Min-Hye; Seo, Hyun-Kyu; Lee, Je-Hyun; Kang, Sam-Sik Structure 13C NMR Structure & 13C NMR 碳谱模拟图 3 . acetovanillone 相似度:50% Chinese Traditional and Herbal Drugs 2005 36 1604-1607 Effect of phenolic acids isolated from Sambucus williamsii on proliferation and differentiation of rat osteoblastic UMR106 cells YANG Xu-juan; WONG Man-sau; WANG Nai-li; CHAN Sun-chi; YAO Xin-sheng Structure 13C NMR Structure & 13C NMR 碳谱模拟图 4 . coniferyl aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2011 42 437-439 Chemical constituents of Opuntia milpa (I) LUO Chuan, ZHANG Wan-nian Structure 13C NMR Structure & 13C NMR 碳谱模拟图 5 . coniferyl aldehyde C11H11O3 相似度:50% Natural Product Research and Development 2014 26 1780-1784 Chemical Constituents from the Fruits of Capparis masaikai LIAO Jin-hua, HU Xu-jia*, YUAN Chun-mao, HE Hong-ping, DI Ying-tong Structure 13C NMR Structure & 13C NMR 碳谱模拟图 6 . 4-Phenylphenol 相似度:50% Molecules 2012 17 12121-12139 Suzuki-Miyaura Reactions Catalyzed by C2-Symmetric Pd-Multi-Dentate N-Heterocyclic Carbene Complexes Lan Jiang, Fengjun Shan, Zhengning Li and Defeng Zhao Structure 13C NMR Structure & 13C NMR 碳谱模拟图 7 . coniferyl aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2012 43 2346-2350 Chemical constituents from fruits of Vitex negundo ZHAO Xiang-xiang; ZHENG Cheng-jian; QIN Lu-ping Structure 13C NMR Structure & 13C NMR 碳谱模拟图 8 . 2-羟基-5-甲氧基-苯丙烯醛 相似度:50% China Journal of Chinese Materia Medica 2012 37 2092-2099 Non-anthraquinones constituents from the roots of Knoxia valerianoides ZHAO Feng; WANG Sujuan; WU Xiuli; YU Yang; YUE Zhenggang; LIU Bo; LIN Sheng; ZHU Chenggen; YANG Yongchun; SHI Jiangong Structure 13C NMR Structure & 13C NMR 碳谱模拟图 9 . coniferaldehyde 相似度:50% Journal of the Korean Society for Applied Biological Chemistry 2012 55 433-437 Cytotoxic Compounds from the Fruits of Vitex rotundifolia against Human Cancer Cell Lines Haejin Kim, Jin-Mu Yi, No Soo Kim, You Jin Lee, Jinhee Kim, Dal-Seok Oh, Se-Mi Oh, Ok-Sun Bang, Jun Lee Structure 13C NMR Structure & 13C NMR 碳谱模拟图 10 . aldehyde 相似度:50% Chinese Traditional and Herbal Drugs 2014 45 1373-1377 Chemical constituents from Gnaphlium affine LI Sheng-hua Structure 13C NMR Structure & 13C NMR 碳谱模拟图 |
3楼2015-03-28 12:27:44
