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【答案】应助回帖
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fangzx025: 金币+100, ★★★★★最佳答案 2015-03-03 18:06:25
通过自由基捕获和同位素标记技术以及现代谱学手段，结合催化剂的表征和反应实验结果，研究苯基丙烯酸与含N（P）化合物在Cu-ETS-10-M和NiAg-ETS-10-M催化剂上的反应机理；研究沸石催化剂的骨架结构特性、表面化学性质、孔道结构对脱羧偶联反应的高效催化促进作用本质。
We studied the mechanism of decaroxylative coupling reaction of phenylacrylic acids with nitrogen or phosphorus-containing compounds in the presence of Cu-ETS-10-M and NiAg-ETS-10-M catalysts, by using radical trapping, isotope labelling, and (more detailed description of) spectroscopic methods; We also studied the characteristics of the structure of framework, the surface chemical properties and the structure of porous channel of the zeolite with regard to the nature of its high efficient catalytic activity for decaroxylative coupling reactions. |
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