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【奖励】本帖被评价84次，作者海天天意增加金币 66.8 个

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海天天意

铁杆木虫 (正式写手)

应助: 1 (幼儿园)
金币: 8265.5
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在线: 230.2小时
虫号: 1350494

[资源] Chem Soc Rev11.19新鲜在线中科大谢毅院士课题组无机二维纳米材料

Surface chemical-modification for engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials
Yuqiao Guo, Kun Xu, Changzheng Wu,* Jiyin Zhao and Yi Xie

2k.jpg
Two-dimensional (2D) nanomaterials, especially the inorganic ultrathin nanosheets with single or fewatomic
layers, have been extensively studied due to their special structures and rich physical properties
coming from the quantum confinement of electrons. With atomic-scale thickness, 2D nanomaterials
have an extremely high specific surface area enabling their surface phase to be as important as bulk
counterparts, and therefore provide an alternative way of modifying the surface phase for engineering the
intrinsic physical properties of inorganic 2D nanomaterials. In this review, we focus on recent research
concerning surface chemical modification strategies to effectively engineer the intrinsic physical properties of
inorganic 2D nanomaterials. We highlight the newly developed regulation strategies of surface incorporation,
defect engineering, and structure modulation of inorganic 2D nanomaterials, which respectively
influence the intrinsic conductivity, band structure, and magnetism while maintaining the primary 2D
freestanding structures that are vital for 2D based ultrasensitive electronic response, enhanced catalytic
and magnetocaloric capabilities.

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