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珊瑚贝贝

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The Preparation and Analysis of Chlorinated Ethylene Vinyl Acetate Copolymer as Coating Film in Gas-Solid Phase,
Journal of applied polymer science, 2014,131(22) DOI: 10.1002/app.41093
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珊瑚贝贝: 金币+10, ★★★★★最佳答案, 谢谢啦 2014-11-12 08:23:10
oven1986: LS-EPI+1, 感谢应助! 2014-11-12 15:27:43
The Preparation and Analysis of Chlorinated Ethylene Vinyl Acetate Copolymer as Coating Film in Gas-Solid Phase


作者:Jing, Z (Jing, Zhao)[ 1 ] ; Liu, LJ (Liu, Lijuan)[ 1 ] ; Zhang, SK (Zhang, Shukai)[ 1 ] ; Zhao, JR (Zhao, Jiruo)[ 1 ] ; Feng, Y (Feng, Ying)[ 1 ]




JOURNAL OF APPLIED POLYMER SCIENCE



卷: 131

期: 22

文献号: 41093

DOI: 10.1002/APP.41093

出版年: NOV 15 2014

查看期刊信息






























摘要

In this article, the feasibility of preparing chlorinated ethylene vinyl acetate copolymer (CEVA) in gas-solid phase is investigated. Furthermore, the structure of the chlorination product and its performance as a coating material are also analyzed. Both the molecular structure and crystallinity of the product are well studied with various characterization methods, including H-1-NMR, Fourier transform infrared, gel permeation chromatography, differential scanning calorimeter, and so forth. The results show that the chlorination of EVA in gas-solid phase is feasible and the chlorine content of CEVA can be made over 60%. It is also found that when the chlorine content is low, chlorination can easily occur in ethylene section but rarely happens in vinyl acetate section. Nevertheless, when the chlorine content of CEVA rises over 35%, -CH in the vinyl acetate section is also found chlorinated. The removal of hydrogen chloride is induced during chlorination, producing double bonds in the main chain. Besides, the trace of -CCl2 structure can also be found in the chain of CEVA. After chlorination, the crystallization will change and is negatively correlated with chlorine content. As the film forming material for coating, CEVA has its best performance with 50% chlorine content. (C) 2014 Wiley Periodicals, Inc.


关键词

作者关键词:addition polymerization; applications; coatings

KeyWords Plus:CARBON NANOTUBE NANOCOMPOSITES; FLAME-RETARDANT BEHAVIOR


作者信息

通讯作者地址: Zhao, JR (通讯作者)





Qingdao Univ Sci & Technol, Shandong Prov Key Lab Rubber Plast, Minist Educ, Key Lab Rubber Plast, Qingdao, Peoples R China.





地址:





[ 1 ] Qingdao Univ Sci & Technol, Shandong Prov Key Lab Rubber Plast, Minist Educ, Key Lab Rubber Plast, Qingdao, Peoples R China





电子邮件地址:jiruozhao@qust.edu.cn


基金资助致谢



基金资助机构

授权号



National Natural Science Foundation of China


51173090

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出版商

WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN 07030-5774, NJ USA


类别 / 分类

研究方向olymer Science

Web of Science 类别olymer Science


文献信息

文献类型:Article

语种:English

入藏号: WOS:000341179900049

ISSN: 0021-8995

电子 ISSN: 1097-4628


期刊信息


Impact Factor (影响因子): Journal Citation Reports®


其他信息

IDS 号: AO2TW

Web of Science 核心合集中的 "引用的参考文献": 10

Web of Science 核心合集中的 "被引频次": 0
4楼2014-11-11 16:29:15
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珊瑚贝贝

金虫 (初入文坛)

如果可以发个word版本的就更好了,万分感谢
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2楼2014-11-11 16:25:14
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感谢参与,应助指数 +1
3楼2014-11-11 16:28:58
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入藏号: WOS:000341179900049
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